[(IPr)Pd(0)] species : a versatile, well-defined catalyst precursor for cross coupling reactions
- Author
- NM Scott, O Navarro, O Briel and Steven Nolan (UGent)
- Organization
- Abstract
- The catalytic application of the newly commercial available complex (IPr)Pd(allyl)Cl (IPr = N,N '-bis(2,6-diisopropyl)imidazol-2-ylidene) is described. This complex is an lent source in generating the active 12-electron [(IPr)Pd(0)] palladium species under mild catalytic conditions. As a result it performs a number of organic transformations very effectively and allows for the use of the inexpensive aryl chlorides as coupling partners in cross-coupling chemistry. These non-phosphine palladium systems also permit simple workup procedures. Processes incorporating these catalysts seem feasable as several well defined Pd NHC complexes are availiable at industrial scale.
- Keywords
- N-HETEROCYCLIC CARBENE, OLEFIN METATHESIS CATALYSTS, ACTIVE PALLADIUM CATALYSTS, ARYL CHLORIDES, ARYLBORONIC ACIDS, ALPHA-ARYLATION, BOND FORMATION, COMPLEXES BEARING, C-N, BROMIDES
Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-8170072
- MLA
- Scott, NM, et al. “[(IPr)Pd(0)] Species : A Versatile, Well-Defined Catalyst Precursor for Cross Coupling Reactions.” CHIMICA OGGI-CHEMISTRY TODAY, vol. 23, no. 4, 2005, pp. 10–14.
- APA
- Scott, N., Navarro, O., Briel, O., & Nolan, S. (2005). [(IPr)Pd(0)] species : a versatile, well-defined catalyst precursor for cross coupling reactions. CHIMICA OGGI-CHEMISTRY TODAY, 23(4), 10–14.
- Chicago author-date
- Scott, NM, O Navarro, O Briel, and Steven Nolan. 2005. “[(IPr)Pd(0)] Species : A Versatile, Well-Defined Catalyst Precursor for Cross Coupling Reactions.” CHIMICA OGGI-CHEMISTRY TODAY 23 (4): 10–14.
- Chicago author-date (all authors)
- Scott, NM, O Navarro, O Briel, and Steven Nolan. 2005. “[(IPr)Pd(0)] Species : A Versatile, Well-Defined Catalyst Precursor for Cross Coupling Reactions.” CHIMICA OGGI-CHEMISTRY TODAY 23 (4): 10–14.
- Vancouver
- 1.Scott N, Navarro O, Briel O, Nolan S. [(IPr)Pd(0)] species : a versatile, well-defined catalyst precursor for cross coupling reactions. CHIMICA OGGI-CHEMISTRY TODAY. 2005;23(4):10–4.
- IEEE
- [1]N. Scott, O. Navarro, O. Briel, and S. Nolan, “[(IPr)Pd(0)] species : a versatile, well-defined catalyst precursor for cross coupling reactions,” CHIMICA OGGI-CHEMISTRY TODAY, vol. 23, no. 4, pp. 10–14, 2005.
@article{8170072,
abstract = {The catalytic application of the newly commercial available complex (IPr)Pd(allyl)Cl (IPr = N,N '-bis(2,6-diisopropyl)imidazol-2-ylidene) is described. This complex is an lent source in generating the active 12-electron [(IPr)Pd(0)] palladium species under mild catalytic conditions. As a result it performs a number of organic transformations very effectively and allows for the use of the inexpensive aryl chlorides as coupling partners in cross-coupling chemistry. These non-phosphine palladium systems also permit simple workup procedures. Processes incorporating these catalysts seem feasable as several well defined Pd NHC complexes are availiable at industrial scale.},
author = {Scott, NM and Navarro, O and Briel, O and Nolan, Steven},
issn = {0392-839X},
journal = {CHIMICA OGGI-CHEMISTRY TODAY},
keywords = {N-HETEROCYCLIC CARBENE,OLEFIN METATHESIS CATALYSTS,ACTIVE PALLADIUM CATALYSTS,ARYL CHLORIDES,ARYLBORONIC ACIDS,ALPHA-ARYLATION,BOND FORMATION,COMPLEXES BEARING,C-N,BROMIDES},
language = {eng},
number = {4},
pages = {10--14},
title = {[(IPr)Pd(0)] species : a versatile, well-defined catalyst precursor for cross coupling reactions},
volume = {23},
year = {2005},
}