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[(IPr)Pd(0)] species : a versatile, well-defined catalyst precursor for cross coupling reactions

Author
Organization
Abstract
The catalytic application of the newly commercial available complex (IPr)Pd(allyl)Cl (IPr = N,N '-bis(2,6-diisopropyl)imidazol-2-ylidene) is described. This complex is an lent source in generating the active 12-electron [(IPr)Pd(0)] palladium species under mild catalytic conditions. As a result it performs a number of organic transformations very effectively and allows for the use of the inexpensive aryl chlorides as coupling partners in cross-coupling chemistry. These non-phosphine palladium systems also permit simple workup procedures. Processes incorporating these catalysts seem feasable as several well defined Pd NHC complexes are availiable at industrial scale.
Keywords
N-HETEROCYCLIC CARBENE, OLEFIN METATHESIS CATALYSTS, ACTIVE PALLADIUM CATALYSTS, ARYL CHLORIDES, ARYLBORONIC ACIDS, ALPHA-ARYLATION, BOND FORMATION, COMPLEXES BEARING, C-N, BROMIDES

Citation

Please use this url to cite or link to this publication:

MLA
Scott, NM, et al. “[(IPr)Pd(0)] Species : A Versatile, Well-Defined Catalyst Precursor for Cross Coupling Reactions.” CHIMICA OGGI-CHEMISTRY TODAY, vol. 23, no. 4, 2005, pp. 10–14.
APA
Scott, N., Navarro, O., Briel, O., & Nolan, S. (2005). [(IPr)Pd(0)] species : a versatile, well-defined catalyst precursor for cross coupling reactions. CHIMICA OGGI-CHEMISTRY TODAY, 23(4), 10–14.
Chicago author-date
Scott, NM, O Navarro, O Briel, and Steven Nolan. 2005. “[(IPr)Pd(0)] Species : A Versatile, Well-Defined Catalyst Precursor for Cross Coupling Reactions.” CHIMICA OGGI-CHEMISTRY TODAY 23 (4): 10–14.
Chicago author-date (all authors)
Scott, NM, O Navarro, O Briel, and Steven Nolan. 2005. “[(IPr)Pd(0)] Species : A Versatile, Well-Defined Catalyst Precursor for Cross Coupling Reactions.” CHIMICA OGGI-CHEMISTRY TODAY 23 (4): 10–14.
Vancouver
1.
Scott N, Navarro O, Briel O, Nolan S. [(IPr)Pd(0)] species : a versatile, well-defined catalyst precursor for cross coupling reactions. CHIMICA OGGI-CHEMISTRY TODAY. 2005;23(4):10–4.
IEEE
[1]
N. Scott, O. Navarro, O. Briel, and S. Nolan, “[(IPr)Pd(0)] species : a versatile, well-defined catalyst precursor for cross coupling reactions,” CHIMICA OGGI-CHEMISTRY TODAY, vol. 23, no. 4, pp. 10–14, 2005.
@article{8170072,
  abstract     = {The catalytic application of the newly commercial available complex (IPr)Pd(allyl)Cl (IPr = N,N '-bis(2,6-diisopropyl)imidazol-2-ylidene) is described. This complex is an lent source in generating the active 12-electron [(IPr)Pd(0)] palladium species under mild catalytic conditions. As a result it performs a number of organic transformations very effectively and allows for the use of the inexpensive aryl chlorides as coupling partners in cross-coupling chemistry. These non-phosphine palladium systems also permit simple workup procedures. Processes incorporating these catalysts seem feasable as several well defined Pd NHC complexes are availiable at industrial scale.},
  author       = {Scott, NM and Navarro, O and Briel, O and Nolan, Steven},
  issn         = {0392-839X},
  journal      = {CHIMICA OGGI-CHEMISTRY TODAY},
  keywords     = {N-HETEROCYCLIC CARBENE,OLEFIN METATHESIS CATALYSTS,ACTIVE PALLADIUM CATALYSTS,ARYL CHLORIDES,ARYLBORONIC ACIDS,ALPHA-ARYLATION,BOND FORMATION,COMPLEXES BEARING,C-N,BROMIDES},
  language     = {eng},
  number       = {4},
  pages        = {10--14},
  title        = {[(IPr)Pd(0)] species : a versatile, well-defined catalyst precursor for cross coupling reactions},
  volume       = {23},
  year         = {2005},
}

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