Advanced search

Synthesis and activity in ring-closing metathesis of phosphine and NHC-containing ruthenium-indenylidene (bis)pyridine complexes

Author
Organization
Abstract
The reactions of Cl-2-Ru-(3-phenylindenylidene) complexes with excess pyridine lead to new ruthenium (Ru)-based bis(pyridine) adducts in good yield. These thermally robust catalysts have been tested in ring-closing metathesis (RCM). In spite of promising initiation rates, only moderate to good activities have been observed in kinetic studies on several substrates.
Keywords
homogenous catalysis, metathesis, ruthenium, NHC, indenylidene, HETEROCYCLIC CARBENE COMPLEXES, OLEFIN-METATHESIS, ALKYLIDENE COMPLEXES, CROSS-METATHESIS, CATALYSTS, LIGANDS, BEARING

Citation

Please use this url to cite or link to this publication:

Chicago
Clavier, Herve, and Steven Nolan. 2007. “Synthesis and Activity in Ring-closing Metathesis of Phosphine and NHC-containing Ruthenium-indenylidene (bis)pyridine Complexes.” In NATO Science Series II-Mathematics Physics and Chemistry, ed. Y Imamoglu and V Dragutan, 243:29–37. Dordrecht, The Netherlands: Springer.
APA
Clavier, H., & Nolan, S. (2007). Synthesis and activity in ring-closing metathesis of phosphine and NHC-containing ruthenium-indenylidene (bis)pyridine complexes. In Y. Imamoglu & V. Dragutan (Eds.), NATO Science Series II-Mathematics Physics and Chemistry (Vol. 243, pp. 29–37). Presented at the Conference of the NATO Advanced Study Institute on New Frontiers in Metathesis Chemistry, Dordrecht, The Netherlands: Springer.
Vancouver
1.
Clavier H, Nolan S. Synthesis and activity in ring-closing metathesis of phosphine and NHC-containing ruthenium-indenylidene (bis)pyridine complexes. In: Imamoglu Y, Dragutan V, editors. NATO Science Series II-Mathematics Physics and Chemistry. Dordrecht, The Netherlands: Springer; 2007. p. 29–37.
MLA
Clavier, Herve, and Steven Nolan. “Synthesis and Activity in Ring-closing Metathesis of Phosphine and NHC-containing Ruthenium-indenylidene (bis)pyridine Complexes.” NATO Science Series II-Mathematics Physics and Chemistry. Ed. Y Imamoglu & V Dragutan. Vol. 243. Dordrecht, The Netherlands: Springer, 2007. 29–37. Print.
@inproceedings{8169873,
  abstract     = {The reactions of Cl-2-Ru-(3-phenylindenylidene) complexes with excess pyridine lead to new ruthenium (Ru)-based bis(pyridine) adducts in good yield. These thermally robust catalysts have been tested in ring-closing metathesis (RCM). In spite of promising initiation rates, only moderate to good activities have been observed in kinetic studies on several substrates.},
  author       = {Clavier, Herve and Nolan, Steven},
  booktitle    = {NATO Science Series II-Mathematics Physics and Chemistry},
  editor       = {Imamoglu, Y and Dragutan, V},
  isbn         = {9781402060908 },
  issn         = {1568-2609},
  keyword      = {homogenous catalysis,metathesis,ruthenium,NHC,indenylidene,HETEROCYCLIC CARBENE COMPLEXES,OLEFIN-METATHESIS,ALKYLIDENE COMPLEXES,CROSS-METATHESIS,CATALYSTS,LIGANDS,BEARING},
  language     = {eng},
  location     = {Antalya, Turkey},
  pages        = {29--37},
  publisher    = {Springer},
  title        = {Synthesis and activity in ring-closing metathesis of phosphine and NHC-containing ruthenium-indenylidene (bis)pyridine complexes},
  url          = {http://dx.doi.org/10.1007/978-1-4020-6091-5\_2},
  volume       = {243},
  year         = {2007},
}

Altmetric
View in Altmetric
Web of Science
Times cited: