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Insertion of a N-heterocyclic carbene (NHC) into a platinum-olefin bond

(2007) ORGANOMETALLICS. 26(14). p.3286-3288
Author
Organization
Abstract
The insertion of a N-heterocyclic carbene (NHC) into a coordinated olefin moiety is observed for a Pt-based system. Important intermediates along the reaction pathway have been isolated and fully characterized. Computational work supports a proposed mechanistic pathway involving external attack at the olefin by a NHC ligand rather than an intramolecular migratory insertion route.
Keywords
C-H ACTIVATION, OXIDATIVE ADDITION, ROOM-TEMPERATURE, SUZUKI-MIYAURA, TRANSESTERIFICATION/ACYLATION REACTIONS, PLATINUM(0)-CARBENE COMPLEXES, METATHESIS CATALYSTS, MIGRATORY INSERTION, BUCHWALD-HARTWIG, RUTHENIUM

Citation

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Chicago
Fantasia, Serena, Heiko Jacobsen, Luigi Cavallo, and Steven Nolan. 2007. “Insertion of a N-heterocyclic Carbene (NHC) into a Platinum-olefin Bond.” Organometallics 26 (14): 3286–3288.
APA
Fantasia, S., Jacobsen, H., Cavallo, L., & Nolan, S. (2007). Insertion of a N-heterocyclic carbene (NHC) into a platinum-olefin bond. ORGANOMETALLICS, 26(14), 3286–3288.
Vancouver
1.
Fantasia S, Jacobsen H, Cavallo L, Nolan S. Insertion of a N-heterocyclic carbene (NHC) into a platinum-olefin bond. ORGANOMETALLICS. 2007;26(14):3286–8.
MLA
Fantasia, Serena, Heiko Jacobsen, Luigi Cavallo, et al. “Insertion of a N-heterocyclic Carbene (NHC) into a Platinum-olefin Bond.” ORGANOMETALLICS 26.14 (2007): 3286–3288. Print.
@article{8169812,
  abstract     = {The insertion of a N-heterocyclic carbene (NHC) into a coordinated olefin moiety is observed for a Pt-based system. Important intermediates along the reaction pathway have been isolated and fully characterized. Computational work supports a proposed mechanistic pathway involving external attack at the olefin by a NHC ligand rather than an intramolecular migratory insertion route.},
  author       = {Fantasia, Serena and Jacobsen, Heiko and Cavallo, Luigi and Nolan, Steven},
  issn         = {0276-7333},
  journal      = {ORGANOMETALLICS},
  keyword      = {C-H ACTIVATION,OXIDATIVE ADDITION,ROOM-TEMPERATURE,SUZUKI-MIYAURA,TRANSESTERIFICATION/ACYLATION REACTIONS,PLATINUM(0)-CARBENE COMPLEXES,METATHESIS CATALYSTS,MIGRATORY INSERTION,BUCHWALD-HARTWIG,RUTHENIUM},
  language     = {eng},
  number       = {14},
  pages        = {3286--3288},
  title        = {Insertion of a N-heterocyclic carbene (NHC) into a platinum-olefin bond},
  url          = {http://dx.doi.org/10.1021/om700447u},
  volume       = {26},
  year         = {2007},
}

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