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Aminocarbonyl group containing Hoveyda-Grubbs-type complexes : synthesis and activity in olefin metathesis transformations

(2008) JOURNAL OF ORGANIC CHEMISTRY. 73(11). p.4225-4228
Author
Organization
Abstract
Three novel "boomerang" precatalysts bearing different aminocarbonyl functions are reported. Comparative kinetic studies show that this functional group allows for a control of the catalytic activity in metathesis transformations. The scope of the more active catalyst is investigated and shows a good tolerance to various substrates in ring-closing metathesis, enyne metathesis, and cross metathesis. ICP-MS analyses illustrate the good affinity of this catalyst for silica gel, as levels of Ru contamination lower than 6 ppm are detected in the final products.
Keywords
N-HETEROCYCLIC CARBENE, TAGGED RUTHENIUM COMPLEXES, RING-CLOSING METATHESIS, IONIC LIQUIDS, CATALYSTS, EFFICIENT, LIGANDS, ACTIVATION, DESIGN

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Chicago
Rix, Diane, Frederic Caijo, Isabelle Laurent, Fabien Boeda, Herve Clavier, Steven Nolan, and Marc Mauduit. 2008. “Aminocarbonyl Group Containing Hoveyda-Grubbs-type Complexes : Synthesis and Activity in Olefin Metathesis Transformations.” Journal of Organic Chemistry 73 (11): 4225–4228.
APA
Rix, D., Caijo, F., Laurent, I., Boeda, F., Clavier, H., Nolan, S., & Mauduit, M. (2008). Aminocarbonyl group containing Hoveyda-Grubbs-type complexes : synthesis and activity in olefin metathesis transformations. JOURNAL OF ORGANIC CHEMISTRY, 73(11), 4225–4228.
Vancouver
1.
Rix D, Caijo F, Laurent I, Boeda F, Clavier H, Nolan S, et al. Aminocarbonyl group containing Hoveyda-Grubbs-type complexes : synthesis and activity in olefin metathesis transformations. JOURNAL OF ORGANIC CHEMISTRY. 2008;73(11):4225–8.
MLA
Rix, Diane, Frederic Caijo, Isabelle Laurent, et al. “Aminocarbonyl Group Containing Hoveyda-Grubbs-type Complexes : Synthesis and Activity in Olefin Metathesis Transformations.” JOURNAL OF ORGANIC CHEMISTRY 73.11 (2008): 4225–4228. Print.
@article{8169626,
  abstract     = {Three novel {\textacutedbl}boomerang{\textacutedbl} precatalysts bearing different aminocarbonyl functions are reported. Comparative kinetic studies show that this functional group allows for a control of the catalytic activity in metathesis transformations. The scope of the more active catalyst is investigated and shows a good tolerance to various substrates in ring-closing metathesis, enyne metathesis, and cross metathesis. ICP-MS analyses illustrate the good affinity of this catalyst for silica gel, as levels of Ru contamination lower than 6 ppm are detected in the final products.},
  author       = {Rix, Diane and Caijo, Frederic and Laurent, Isabelle and Boeda, Fabien and Clavier, Herve and Nolan, Steven and Mauduit, Marc},
  issn         = {0022-3263},
  journal      = {JOURNAL OF ORGANIC CHEMISTRY},
  language     = {eng},
  number       = {11},
  pages        = {4225--4228},
  title        = {Aminocarbonyl group containing Hoveyda-Grubbs-type complexes : synthesis and activity in olefin metathesis transformations},
  url          = {http://dx.doi.org/10.1021/jo800203d},
  volume       = {73},
  year         = {2008},
}

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