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Building indenylidene-ruthenium catalysts for metathesis transformations

Author
Organization
Abstract
Ruthenium-mediated olefin metathesis has emerged as an indispensable tool in organic synthesis for the formation carbon carbon double bonds, attested by the large number of applications for natural product synthesis. Among the numerous catalysts developed to mediate olefin metathesis transformations, ruthenium-indenylidene complexes are robust and powerful pre-catalysts. The discovery of this catalyst category was slightly muddled due to a first mis-assignment of the compound structure. This report provides an overview of the synthetic routes for the construction of the indenylidene pattern in ruthenium complexes. The parameters relating to the indenylidene moiety construction will be discussed as well as the mechanism of this formation.
Keywords
Olefin metathesis, Ruthenium catalysts, Indenylidene complexes, Allenylidene complexes, Fluorenylidene complexes, RING-CLOSING METATHESIS, TRANSFER RADICAL POLYMERIZATION, HIGHLY-ACTIVE CATALYSTS, OLEFIN METATHESIS, ALLENYLIDENE COMPLEXES, ALKENE METATHESIS, CROSS-METATHESIS, ARENE COMPLEXES, EFFICIENT, CARBENE

Citation

Please use this url to cite or link to this publication:

MLA
Clavier, Herve, and Steven Nolan. “Building Indenylidene-Ruthenium Catalysts for Metathesis Transformations.” NATO Science for Peace and Security, Series A : Chemistry and Biology, Springer, 2010, pp. 39–47.
APA
Clavier, H., & Nolan, S. (2010). Building indenylidene-ruthenium catalysts for metathesis transformations. In NATO Science for Peace and Security, series A : chemistry and biology (pp. 39–47). Dordrecht, The Netherlands: Springer.
Chicago author-date
Clavier, Herve, and Steven Nolan. 2010. “Building Indenylidene-Ruthenium Catalysts for Metathesis Transformations.” In NATO Science for Peace and Security, Series A : Chemistry and Biology, 39–47. Dordrecht, The Netherlands: Springer.
Chicago author-date (all authors)
Clavier, Herve, and Steven Nolan. 2010. “Building Indenylidene-Ruthenium Catalysts for Metathesis Transformations.” In NATO Science for Peace and Security, Series A : Chemistry and Biology, 39–47. Dordrecht, The Netherlands: Springer.
Vancouver
1.
Clavier H, Nolan S. Building indenylidene-ruthenium catalysts for metathesis transformations. In: NATO Science for Peace and Security, series A : chemistry and biology. Dordrecht, The Netherlands: Springer; 2010. p. 39–47.
IEEE
[1]
H. Clavier and S. Nolan, “Building indenylidene-ruthenium catalysts for metathesis transformations,” in NATO Science for Peace and Security, series A : chemistry and biology, Bucharest, Romania, 2010, pp. 39–47.
@inproceedings{8169390,
  abstract     = {Ruthenium-mediated olefin metathesis has emerged as an indispensable tool in organic synthesis for the formation carbon carbon double bonds, attested by the large number of applications for natural product synthesis. Among the numerous catalysts developed to mediate olefin metathesis transformations, ruthenium-indenylidene complexes are robust and powerful pre-catalysts. The discovery of this catalyst category was slightly muddled due to a first mis-assignment of the compound structure. This report provides an overview of the synthetic routes for the construction of the indenylidene pattern in ruthenium complexes. The parameters relating to the indenylidene moiety construction will be discussed as well as the mechanism of this formation.},
  author       = {Clavier, Herve and Nolan, Steven},
  booktitle    = {NATO Science for Peace and Security, series A : chemistry and biology},
  isbn         = {9789048134311},
  issn         = {1874-6489},
  keywords     = {Olefin metathesis,Ruthenium catalysts,Indenylidene complexes,Allenylidene complexes,Fluorenylidene complexes,RING-CLOSING METATHESIS,TRANSFER RADICAL POLYMERIZATION,HIGHLY-ACTIVE CATALYSTS,OLEFIN METATHESIS,ALLENYLIDENE COMPLEXES,ALKENE METATHESIS,CROSS-METATHESIS,ARENE COMPLEXES,EFFICIENT,CARBENE},
  language     = {eng},
  location     = {Bucharest, Romania},
  pages        = {39--47},
  publisher    = {Springer},
  title        = {Building indenylidene-ruthenium catalysts for metathesis transformations},
  url          = {http://dx.doi.org/10.1007/978-90-481-3433-5_4},
  year         = {2010},
}

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