Percent buried volume for phosphine and N-heterocyclic carbene ligands : steric properties in organometallic chemistry
- Author
- Herve Clavier and Steven Nolan (UGent)
- Organization
- Abstract
- Electronic and steric ligand effects both play major roles in organometallic chemistry and consequently in metal-mediated catalysis. Quantifying such parameters is of interest to better understand not only the parameters governing catalyst performance but also reaction mechanisms. Nowadays, ligand molecular architectures are becoming significantly more elaborate and existing models describing ligand sterics prove lacking. This review presents the development of a more general method to determine the steric parameter of organometallic ligands. Two case studies are presented: the tertiary phosphines and the N-heterocyclic carbenes.
- Keywords
- TRANSITION-METAL-COMPLEXES, X-RAY STRUCTURES, CROSS-COUPLING REACTIONS, OLEFIN METATHESIS CATALYSTS, NHC PALLADIUM COMPLEXES, LEWIS-BASE ADDUCTS, RUCL CP-ASTERISK, GOLD(I) COMPLEXES, CRYSTAL-STRUCTURES, MOLECULAR-STRUCTURE
Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-8169327
- MLA
- Clavier, Herve, and Steven Nolan. “Percent Buried Volume for Phosphine and N-heterocyclic Carbene Ligands : Steric Properties in Organometallic Chemistry.” CHEMICAL COMMUNICATIONS 46.6 (2010): 841–861. Print.
- APA
- Clavier, H., & Nolan, S. (2010). Percent buried volume for phosphine and N-heterocyclic carbene ligands : steric properties in organometallic chemistry. CHEMICAL COMMUNICATIONS, 46(6), 841–861.
- Chicago author-date
- Clavier, Herve, and Steven Nolan. 2010. “Percent Buried Volume for Phosphine and N-heterocyclic Carbene Ligands : Steric Properties in Organometallic Chemistry.” Chemical Communications 46 (6): 841–861.
- Chicago author-date (all authors)
- Clavier, Herve, and Steven Nolan. 2010. “Percent Buried Volume for Phosphine and N-heterocyclic Carbene Ligands : Steric Properties in Organometallic Chemistry.” Chemical Communications 46 (6): 841–861.
- Vancouver
- 1.Clavier H, Nolan S. Percent buried volume for phosphine and N-heterocyclic carbene ligands : steric properties in organometallic chemistry. CHEMICAL COMMUNICATIONS. 2010;46(6):841–61.
- IEEE
- [1]H. Clavier and S. Nolan, “Percent buried volume for phosphine and N-heterocyclic carbene ligands : steric properties in organometallic chemistry,” CHEMICAL COMMUNICATIONS, vol. 46, no. 6, pp. 841–861, 2010.
@article{8169327,
abstract = {Electronic and steric ligand effects both play major roles in organometallic chemistry and consequently in metal-mediated catalysis. Quantifying such parameters is of interest to better understand not only the parameters governing catalyst performance but also reaction mechanisms. Nowadays, ligand molecular architectures are becoming significantly more elaborate and existing models describing ligand sterics prove lacking. This review presents the development of a more general method to determine the steric parameter of organometallic ligands. Two case studies are presented: the tertiary phosphines and the N-heterocyclic carbenes.},
author = {Clavier, Herve and Nolan, Steven},
issn = {1359-7345},
journal = {CHEMICAL COMMUNICATIONS},
keywords = {TRANSITION-METAL-COMPLEXES,X-RAY STRUCTURES,CROSS-COUPLING REACTIONS,OLEFIN METATHESIS CATALYSTS,NHC PALLADIUM COMPLEXES,LEWIS-BASE ADDUCTS,RUCL CP-ASTERISK,GOLD(I) COMPLEXES,CRYSTAL-STRUCTURES,MOLECULAR-STRUCTURE},
language = {eng},
number = {6},
pages = {841--861},
title = {Percent buried volume for phosphine and N-heterocyclic carbene ligands : steric properties in organometallic chemistry},
url = {http://dx.doi.org/10.1039/b922984a},
volume = {46},
year = {2010},
}
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