Advanced search

Solution calorimetric study of ligand exchange reactions in the [Au(L)Cl] system (L = phosphine and phosphite)

(2010) ORGANOMETALLICS. 29(20). p.4579-4583
Author
Organization
Abstract
The relative L-Au bond dissociation enthalpies of [Au(L)Cl] (L = tetrahydrothiophene (tht), PCy(n)Ph((3-n)), [1,1'-bipheny1]-2-yldicyclohexylphosphine (Cy-JohnPhos), dicyclohexyl(2',6'-dimethoxy[1,1'-biphenyl]-2-yl)phosphine (SPhos), dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine (XPhos), P(OPh)(3), P(O-2,4-(t)Bu(2)Ph)(3), P(O(i)Pr)(3), and the two enantiomers of 1,1', 1 ''-[phosphinidynetris[oxy-(1-S/R)-[1,1'-binaphthalene]-2',2-diyl]] tricyclo[3.3113,7]decane-1-carboxylic acid ester) are examined, These enthalpic values are examined in terms of the intrinsic steric and electronic properties of the ancillary ligand. Estimates of the absolute BDE for the investigated ligands are presented.
Keywords
CATIONIC GOLD(I) COMPLEXES, ORGANOMETALLIC CHEMISTRY, CATALYSIS, ALKYNES, ENERGY, BOND, DENSITIES, MOIETY, ENYNES

Citation

Please use this url to cite or link to this publication:

Chicago
Fortman, George C, and Steven Nolan. 2010. “Solution Calorimetric Study of Ligand Exchange Reactions in the [Au(L)Cl] System (L = Phosphine and Phosphite).” Organometallics 29 (20): 4579–4583.
APA
Fortman, G. C., & Nolan, S. (2010). Solution calorimetric study of ligand exchange reactions in the [Au(L)Cl] system (L = phosphine and phosphite). ORGANOMETALLICS, 29(20), 4579–4583.
Vancouver
1.
Fortman GC, Nolan S. Solution calorimetric study of ligand exchange reactions in the [Au(L)Cl] system (L = phosphine and phosphite). ORGANOMETALLICS. 2010;29(20):4579–83.
MLA
Fortman, George C, and Steven Nolan. “Solution Calorimetric Study of Ligand Exchange Reactions in the [Au(L)Cl] System (L = Phosphine and Phosphite).” ORGANOMETALLICS 29.20 (2010): 4579–4583. Print.
@article{8169223,
  abstract     = {The relative L-Au bond dissociation enthalpies of [Au(L)Cl] (L = tetrahydrothiophene (tht), PCy(n)Ph((3-n)), [1,1'-bipheny1]-2-yldicyclohexylphosphine (Cy-JohnPhos), dicyclohexyl(2',6'-dimethoxy[1,1'-biphenyl]-2-yl)phosphine (SPhos), dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine (XPhos), P(OPh)(3), P(O-2,4-(t)Bu(2)Ph)(3), P(O(i)Pr)(3), and the two enantiomers of 1,1', 1 ''-[phosphinidynetris[oxy-(1-S/R)-[1,1'-binaphthalene]-2',2-diyl]] tricyclo[3.3113,7]decane-1-carboxylic acid ester) are examined, These enthalpic values are examined in terms of the intrinsic steric and electronic properties of the ancillary ligand. Estimates of the absolute BDE for the investigated ligands are presented.},
  author       = {Fortman, George C and Nolan, Steven},
  issn         = {0276-7333},
  journal      = {ORGANOMETALLICS},
  keywords     = {CATIONIC GOLD(I) COMPLEXES,ORGANOMETALLIC CHEMISTRY,CATALYSIS,ALKYNES,ENERGY,BOND,DENSITIES,MOIETY,ENYNES},
  language     = {eng},
  number       = {20},
  pages        = {4579--4583},
  title        = {Solution calorimetric study of ligand exchange reactions in the [Au(L)Cl] system (L = phosphine and phosphite)},
  url          = {http://dx.doi.org/10.1021/om1007049},
  volume       = {29},
  year         = {2010},
}

Altmetric
View in Altmetric
Web of Science
Times cited: