Advanced search

Expeditious synthesis of [Au(NHC)(L)]+ (NHC = N-heterocyclic carbene; L = phosphine or NHC) complexes

(2010) ORGANOMETALLICS. 29(21). p.5402-5408
Author
Organization
Abstract
The use of the versatile N-heterocyclic carbene (NHC) gold(I) hydroxide [Au(OH)(IPr)] (IPr = N,N '-bis(2,6-diisopropylpheny)imidazol-2-ylidene) as precursor permits the expedient synthesis of a series of cationic heteroleptic [Au(NHC)(NHC')](+) and [Au(NHC)(PR3)](+) complexes by proton. lysis with the appropriate acid salts. Complete characterization by H-1 and C-13 NMR spectroscopy and by single-crystal X-ray diffraction was performed in order to discern electronic and structural differences between cationic heteroleptic [Au(NHC)(NHC')](+) and [Au(NHC)(PR3)](+) congeners.
Keywords
GOLD(I) COMPLEXES, ANTICANCER AGENT, METAL-COMPLEXES, PHASE-I, CYTOTOXICITY, DERIVATIVES, LIGANDS, BEARING

Citation

Please use this url to cite or link to this publication:

Chicago
Gaillard, Sylvain, Pierrick Nun, Alexandra MZ Slawin, and Steven Nolan. 2010. “Expeditious Synthesis of [Au(NHC)(L)]+ (NHC = N-heterocyclic Carbene; L = Phosphine or NHC) Complexes.” Organometallics 29 (21): 5402–5408.
APA
Gaillard, S., Nun, P., Slawin, A. M., & Nolan, S. (2010). Expeditious synthesis of [Au(NHC)(L)]+ (NHC = N-heterocyclic carbene; L = phosphine or NHC) complexes. ORGANOMETALLICS, 29(21), 5402–5408.
Vancouver
1.
Gaillard S, Nun P, Slawin AM, Nolan S. Expeditious synthesis of [Au(NHC)(L)]+ (NHC = N-heterocyclic carbene; L = phosphine or NHC) complexes. ORGANOMETALLICS. 2010;29(21):5402–8.
MLA
Gaillard, Sylvain et al. “Expeditious Synthesis of [Au(NHC)(L)]+ (NHC = N-heterocyclic Carbene; L = Phosphine or NHC) Complexes.” ORGANOMETALLICS 29.21 (2010): 5402–5408. Print.
@article{8169217,
  abstract     = {The use of the versatile N-heterocyclic carbene (NHC) gold(I) hydroxide [Au(OH)(IPr)] (IPr = N,N '-bis(2,6-diisopropylpheny)imidazol-2-ylidene) as precursor permits the expedient synthesis of a series of cationic heteroleptic [Au(NHC)(NHC')](+) and [Au(NHC)(PR3)](+) complexes by proton. lysis with the appropriate acid salts. Complete characterization by H-1 and C-13 NMR spectroscopy and by single-crystal X-ray diffraction was performed in order to discern electronic and structural differences between cationic heteroleptic [Au(NHC)(NHC')](+) and [Au(NHC)(PR3)](+) congeners.},
  author       = {Gaillard, Sylvain and Nun, Pierrick and Slawin, Alexandra MZ and Nolan, Steven},
  issn         = {0276-7333},
  journal      = {ORGANOMETALLICS},
  keywords     = {GOLD(I) COMPLEXES,ANTICANCER AGENT,METAL-COMPLEXES,PHASE-I,CYTOTOXICITY,DERIVATIVES,LIGANDS,BEARING},
  language     = {eng},
  number       = {21},
  pages        = {5402--5408},
  title        = {Expeditious synthesis of [Au(NHC)(L)]+ (NHC = N-heterocyclic carbene; L = phosphine or NHC) complexes},
  url          = {http://dx.doi.org/10.1021/om100456b},
  volume       = {29},
  year         = {2010},
}

Altmetric
View in Altmetric
Web of Science
Times cited: