A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes
- Author
- Pierrick Nun, Sylvain Gaillard, Albert Poater, Luigi Cavallo and Steven Nolan (UGent)
- Organization
- Abstract
- Substituted indenes can be prepared after a sequence [1,3] O-acyl shift-hydroarylation-[1,3] O-acyl shift. Each step is catalyzed by a cationic NHC-Gold(I) species generated in situ after reaction between [(IPr) AuOH] and HBF4 center dot OEt2. This interesting silver-free way is fully supported by a computational study justifying the formation of each intermediate.
- Keywords
- N-HETEROCYCLIC CARBENES, GOLD CATALYSIS, PROPARGYLIC ACETATES, APPROXIMATION, PLATINUM, ENERGY, REARRANGEMENT, ACTIVATION, DIVERSITY, SOLVENT
Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-8169180
- MLA
- Nun, Pierrick, et al. “A Combined Mechanistic and Computational Study of the Gold(I)-Catalyzed Formation of Substituted Indenes.” ORGANIC & BIOMOLECULAR CHEMISTRY, vol. 9, no. 1, 2011, pp. 101–04, doi:10.1039/c0ob00758g.
- APA
- Nun, P., Gaillard, S., Poater, A., Cavallo, L., & Nolan, S. (2011). A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes. ORGANIC & BIOMOLECULAR CHEMISTRY, 9(1), 101–104. https://doi.org/10.1039/c0ob00758g
- Chicago author-date
- Nun, Pierrick, Sylvain Gaillard, Albert Poater, Luigi Cavallo, and Steven Nolan. 2011. “A Combined Mechanistic and Computational Study of the Gold(I)-Catalyzed Formation of Substituted Indenes.” ORGANIC & BIOMOLECULAR CHEMISTRY 9 (1): 101–4. https://doi.org/10.1039/c0ob00758g.
- Chicago author-date (all authors)
- Nun, Pierrick, Sylvain Gaillard, Albert Poater, Luigi Cavallo, and Steven Nolan. 2011. “A Combined Mechanistic and Computational Study of the Gold(I)-Catalyzed Formation of Substituted Indenes.” ORGANIC & BIOMOLECULAR CHEMISTRY 9 (1): 101–104. doi:10.1039/c0ob00758g.
- Vancouver
- 1.Nun P, Gaillard S, Poater A, Cavallo L, Nolan S. A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes. ORGANIC & BIOMOLECULAR CHEMISTRY. 2011;9(1):101–4.
- IEEE
- [1]P. Nun, S. Gaillard, A. Poater, L. Cavallo, and S. Nolan, “A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes,” ORGANIC & BIOMOLECULAR CHEMISTRY, vol. 9, no. 1, pp. 101–104, 2011.
@article{8169180,
abstract = {{Substituted indenes can be prepared after a sequence [1,3] O-acyl shift-hydroarylation-[1,3] O-acyl shift. Each step is catalyzed by a cationic NHC-Gold(I) species generated in situ after reaction between [(IPr) AuOH] and HBF4 center dot OEt2. This interesting silver-free way is fully supported by a computational study justifying the formation of each intermediate.}},
author = {{Nun, Pierrick and Gaillard, Sylvain and Poater, Albert and Cavallo, Luigi and Nolan, Steven}},
issn = {{1477-0520}},
journal = {{ORGANIC & BIOMOLECULAR CHEMISTRY}},
keywords = {{N-HETEROCYCLIC CARBENES,GOLD CATALYSIS,PROPARGYLIC ACETATES,APPROXIMATION,PLATINUM,ENERGY,REARRANGEMENT,ACTIVATION,DIVERSITY,SOLVENT}},
language = {{eng}},
number = {{1}},
pages = {{101--104}},
title = {{A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes}},
url = {{http://doi.org/10.1039/c0ob00758g}},
volume = {{9}},
year = {{2011}},
}
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