Advanced search

A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes

Author
Organization
Abstract
Substituted indenes can be prepared after a sequence [1,3] O-acyl shift-hydroarylation-[1,3] O-acyl shift. Each step is catalyzed by a cationic NHC-Gold(I) species generated in situ after reaction between [(IPr) AuOH] and HBF4 center dot OEt2. This interesting silver-free way is fully supported by a computational study justifying the formation of each intermediate.
Keywords
N-HETEROCYCLIC CARBENES, GOLD CATALYSIS, PROPARGYLIC ACETATES, APPROXIMATION, PLATINUM, ENERGY, REARRANGEMENT, ACTIVATION, DIVERSITY, SOLVENT

Citation

Please use this url to cite or link to this publication:

Chicago
Nun, Pierrick, Sylvain Gaillard, Albert Poater, Luigi Cavallo, and Steven Nolan. 2011. “A Combined Mechanistic and Computational Study of the gold(I)-catalyzed Formation of Substituted Indenes.” Organic & Biomolecular Chemistry 9 (1): 101–104.
APA
Nun, P., Gaillard, S., Poater, A., Cavallo, L., & Nolan, S. (2011). A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes. ORGANIC & BIOMOLECULAR CHEMISTRY, 9(1), 101–104.
Vancouver
1.
Nun P, Gaillard S, Poater A, Cavallo L, Nolan S. A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes. ORGANIC & BIOMOLECULAR CHEMISTRY. 2011;9(1):101–4.
MLA
Nun, Pierrick et al. “A Combined Mechanistic and Computational Study of the gold(I)-catalyzed Formation of Substituted Indenes.” ORGANIC & BIOMOLECULAR CHEMISTRY 9.1 (2011): 101–104. Print.
@article{8169180,
  abstract     = {Substituted indenes can be prepared after a sequence [1,3] O-acyl shift-hydroarylation-[1,3] O-acyl shift. Each step is catalyzed by a cationic NHC-Gold(I) species generated in situ after reaction between [(IPr) AuOH] and HBF4 center dot OEt2. This interesting silver-free way is fully supported by a computational study justifying the formation of each intermediate.},
  author       = {Nun, Pierrick and Gaillard, Sylvain and Poater, Albert and Cavallo, Luigi and Nolan, Steven},
  issn         = {1477-0520},
  journal      = {ORGANIC & BIOMOLECULAR CHEMISTRY},
  keywords     = {N-HETEROCYCLIC CARBENES,GOLD CATALYSIS,PROPARGYLIC ACETATES,APPROXIMATION,PLATINUM,ENERGY,REARRANGEMENT,ACTIVATION,DIVERSITY,SOLVENT},
  language     = {eng},
  number       = {1},
  pages        = {101--104},
  title        = {A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes},
  url          = {http://dx.doi.org/10.1039/c0ob00758g},
  volume       = {9},
  year         = {2011},
}

Altmetric
View in Altmetric
Web of Science
Times cited: