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Gold(I)-catalyzed synthesis of furans and pyrroles via alkyne hydration

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Abstract
Furans and pyrroles were prepared via the gold(I)-catalyzed alkyne hydration of diynes. The use of [Au(IPr)OH] as precatalyst in a silver-free protocol permits low catalyst loadings and in situ generation of the active cationic gold species. A detailed computational study confirmed the experimental results and supports the proposed mechanism.
Keywords
N-HETEROCYCLIC CARBENES, POLYSUBSTITUTED FURANS, TERMINAL ALKYNES, GOLD, CATALYSIS, REARRANGEMENT, COMPLEXES, HYDROAMINATION, DERIVATIVES, 1, 3-DIYNES

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Chicago
Nun, Pierrick, Stephanie Dupuy, Sylvain Gaillard, Albert Poater, Luigi Cavallo, and Steven Nolan. 2011. “Gold(I)-catalyzed Synthesis of Furans and Pyrroles via Alkyne Hydration.” Catalysis Science & Technology 1 (1): 58–61.
APA
Nun, P., Dupuy, S., Gaillard, S., Poater, A., Cavallo, L., & Nolan, S. (2011). Gold(I)-catalyzed synthesis of furans and pyrroles via alkyne hydration. CATALYSIS SCIENCE & TECHNOLOGY, 1(1), 58–61.
Vancouver
1.
Nun P, Dupuy S, Gaillard S, Poater A, Cavallo L, Nolan S. Gold(I)-catalyzed synthesis of furans and pyrroles via alkyne hydration. CATALYSIS SCIENCE & TECHNOLOGY. 2011;1(1):58–61.
MLA
Nun, Pierrick et al. “Gold(I)-catalyzed Synthesis of Furans and Pyrroles via Alkyne Hydration.” CATALYSIS SCIENCE & TECHNOLOGY 1.1 (2011): 58–61. Print.
@article{8169121,
  abstract     = {Furans and pyrroles were prepared via the gold(I)-catalyzed alkyne hydration of diynes. The use of [Au(IPr)OH] as precatalyst in a silver-free protocol permits low catalyst loadings and in situ generation of the active cationic gold species. A detailed computational study confirmed the experimental results and supports the proposed mechanism.},
  author       = {Nun, Pierrick and Dupuy, Stephanie and Gaillard, Sylvain and Poater, Albert and Cavallo, Luigi and Nolan, Steven},
  issn         = {2044-4753},
  journal      = {CATALYSIS SCIENCE & TECHNOLOGY},
  keywords     = {N-HETEROCYCLIC CARBENES,POLYSUBSTITUTED FURANS,TERMINAL ALKYNES,GOLD,CATALYSIS,REARRANGEMENT,COMPLEXES,HYDROAMINATION,DERIVATIVES,1,3-DIYNES},
  language     = {eng},
  number       = {1},
  pages        = {58--61},
  title        = {Gold(I)-catalyzed synthesis of furans and pyrroles via alkyne hydration},
  url          = {http://dx.doi.org/10.1039/c0cy00055h},
  volume       = {1},
  year         = {2011},
}

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