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The role of silver additives in gold-mediated C-H functionalisation

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Abstract
The role of silver additives is examined in the context of gold-mediated functionalisation of aromatic C-H bonds. Doubt is cast on the commonly cited route of halide abstraction from gold and evidence of substrate activation is given.
Keywords
C-H functionalisation, gold catalyst, halide abstraction, N-heterocyclic carbene, silver salt, substrate activation, N-HETEROCYCLIC CARBENES, BOND FORMATION, CATALYSIS, ARYLATION, COMPLEXES, ACID

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Chicago
Patrick, Scott R, Ine IF Boogaerts, Sylvain Gaillard, Alexandra MZ Slawin, and Steven Nolan. 2011. “The Role of Silver Additives in Gold-mediated C-H Functionalisation.” Beilstein Journal of Organic Chemistry 7: 892–896.
APA
Patrick, S. R., Boogaerts, I. I., Gaillard, S., Slawin, A. M., & Nolan, S. (2011). The role of silver additives in gold-mediated C-H functionalisation. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 7, 892–896.
Vancouver
1.
Patrick SR, Boogaerts II, Gaillard S, Slawin AM, Nolan S. The role of silver additives in gold-mediated C-H functionalisation. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY. 2011;7:892–6.
MLA
Patrick, Scott R et al. “The Role of Silver Additives in Gold-mediated C-H Functionalisation.” BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 7 (2011): 892–896. Print.
@article{8169029,
  abstract     = {The role of silver additives is examined in the context of gold-mediated functionalisation of aromatic C-H bonds. Doubt is cast on the commonly cited route of halide abstraction from gold and evidence of substrate activation is given.},
  author       = {Patrick, Scott R and Boogaerts, Ine IF and Gaillard, Sylvain and Slawin, Alexandra MZ and Nolan, Steven},
  issn         = {1860-5397},
  journal      = {BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY},
  keywords     = {C-H functionalisation,gold catalyst,halide abstraction,N-heterocyclic carbene,silver salt,substrate activation,N-HETEROCYCLIC CARBENES,BOND FORMATION,CATALYSIS,ARYLATION,COMPLEXES,ACID},
  language     = {eng},
  pages        = {892--896},
  title        = {The role of silver additives in gold-mediated C-H functionalisation},
  url          = {http://dx.doi.org/10.3762/bjoc.7.102},
  volume       = {7},
  year         = {2011},
}

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