
The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold
- Author
- Stephanie Dupuy, Luke Crawford, Michael Buehl, Alexandra MZ Slawin and Steven Nolan (UGent)
- Organization
- Abstract
- In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.
- Keywords
- arylboronic acids, gold hydroxide complexes, gold-aryl complexes, N-heterocyclic carbenes, transmetalation, CROSS-COUPLING REACTION, BOND FORMATION, STRUCTURAL-CHARACTERIZATION, ORGANOBORON COMPOUNDS, ORGANOGOLD COMPOUNDS, CRYSTAL-STRUCTURES, ORGANIC-REACTIONS, PALLADIUM, CATALYSIS, RELEVANCE
Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-8168870
- MLA
- Dupuy, Stephanie, et al. “The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction : The Case of Gold.” ADVANCED SYNTHESIS & CATALYSIS, vol. 354, no. 13, 2012, pp. 2380–86.
- APA
- Dupuy, S., Crawford, L., Buehl, M., Slawin, A. M., & Nolan, S. (2012). The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold. ADVANCED SYNTHESIS & CATALYSIS, 354(13), 2380–2386.
- Chicago author-date
- Dupuy, Stephanie, Luke Crawford, Michael Buehl, Alexandra MZ Slawin, and Steven Nolan. 2012. “The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction : The Case of Gold.” ADVANCED SYNTHESIS & CATALYSIS 354 (13): 2380–86.
- Chicago author-date (all authors)
- Dupuy, Stephanie, Luke Crawford, Michael Buehl, Alexandra MZ Slawin, and Steven Nolan. 2012. “The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction : The Case of Gold.” ADVANCED SYNTHESIS & CATALYSIS 354 (13): 2380–2386.
- Vancouver
- 1.Dupuy S, Crawford L, Buehl M, Slawin AM, Nolan S. The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold. ADVANCED SYNTHESIS & CATALYSIS. 2012;354(13):2380–6.
- IEEE
- [1]S. Dupuy, L. Crawford, M. Buehl, A. M. Slawin, and S. Nolan, “The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold,” ADVANCED SYNTHESIS & CATALYSIS, vol. 354, no. 13, pp. 2380–2386, 2012.
@article{8168870, abstract = {In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.}, author = {Dupuy, Stephanie and Crawford, Luke and Buehl, Michael and Slawin, Alexandra MZ and Nolan, Steven}, issn = {1615-4150}, journal = {ADVANCED SYNTHESIS & CATALYSIS}, keywords = {arylboronic acids,gold hydroxide complexes,gold-aryl complexes,N-heterocyclic carbenes,transmetalation,CROSS-COUPLING REACTION,BOND FORMATION,STRUCTURAL-CHARACTERIZATION,ORGANOBORON COMPOUNDS,ORGANOGOLD COMPOUNDS,CRYSTAL-STRUCTURES,ORGANIC-REACTIONS,PALLADIUM,CATALYSIS,RELEVANCE}, language = {eng}, number = {13}, pages = {2380--2386}, title = {The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold}, url = {http://dx.doi.org/10.1002/adsc.201200233}, volume = {354}, year = {2012}, }
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