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The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold

Stephanie Dupuy, Luke Crawford, Michael Buehl, Alexandra MZ Slawin and Steven Nolan (UGent)
(2012) ADVANCED SYNTHESIS & CATALYSIS. 354(13). p.2380-2386
Author
Organization
Abstract
In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.
Keywords
arylboronic acids, gold hydroxide complexes, gold-aryl complexes, N-heterocyclic carbenes, transmetalation, CROSS-COUPLING REACTION, BOND FORMATION, STRUCTURAL-CHARACTERIZATION, ORGANOBORON COMPOUNDS, ORGANOGOLD COMPOUNDS, CRYSTAL-STRUCTURES, ORGANIC-REACTIONS, PALLADIUM, CATALYSIS, RELEVANCE

Citation

Please use this url to cite or link to this publication:

MLA
Dupuy, Stephanie, et al. “The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction : The Case of Gold.” ADVANCED SYNTHESIS & CATALYSIS, vol. 354, no. 13, 2012, pp. 2380–86.
APA
Dupuy, S., Crawford, L., Buehl, M., Slawin, A. M., & Nolan, S. (2012). The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold. ADVANCED SYNTHESIS & CATALYSIS, 354(13), 2380–2386.
Chicago author-date
Dupuy, Stephanie, Luke Crawford, Michael Buehl, Alexandra MZ Slawin, and Steven Nolan. 2012. “The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction : The Case of Gold.” ADVANCED SYNTHESIS & CATALYSIS 354 (13): 2380–86.
Chicago author-date (all authors)
Dupuy, Stephanie, Luke Crawford, Michael Buehl, Alexandra MZ Slawin, and Steven Nolan. 2012. “The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction : The Case of Gold.” ADVANCED SYNTHESIS & CATALYSIS 354 (13): 2380–2386.
Vancouver
1.
Dupuy S, Crawford L, Buehl M, Slawin AM, Nolan S. The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold. ADVANCED SYNTHESIS & CATALYSIS. 2012;354(13):2380–6.
IEEE
[1]
S. Dupuy, L. Crawford, M. Buehl, A. M. Slawin, and S. Nolan, “The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold,” ADVANCED SYNTHESIS & CATALYSIS, vol. 354, no. 13, pp. 2380–2386, 2012.
@article{8168870,
  abstract     = {In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.},
  author       = {Dupuy, Stephanie and Crawford, Luke and Buehl, Michael and Slawin, Alexandra MZ and Nolan, Steven},
  issn         = {1615-4150},
  journal      = {ADVANCED SYNTHESIS & CATALYSIS},
  keywords     = {arylboronic acids,gold hydroxide complexes,gold-aryl complexes,N-heterocyclic carbenes,transmetalation,CROSS-COUPLING REACTION,BOND FORMATION,STRUCTURAL-CHARACTERIZATION,ORGANOBORON COMPOUNDS,ORGANOGOLD COMPOUNDS,CRYSTAL-STRUCTURES,ORGANIC-REACTIONS,PALLADIUM,CATALYSIS,RELEVANCE},
  language     = {eng},
  number       = {13},
  pages        = {2380--2386},
  title        = {The role of metal hydroxide complexes in late transition metal-mediated transmetalation reaction : the case of gold},
  url          = {http://dx.doi.org/10.1002/adsc.201200233},
  volume       = {354},
  year         = {2012},
}
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