Advanced search
Add to list

Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : direct arylation of heterocycles

Author
Organization
Abstract
The use of [Pd(NHC)(cinnamyl)Cl] precatalysts in the direct arylation of heterocycles has been investigated. Among four different precatalysts, [Pd(SIPr)(cinnamyl)Cl] proved to be the most efficient promoter of the reaction. The C-H functionalization of sulfur- or nitrogen-containing heterocycles has been achieved at low catalyst loadings. These catalyst charges range from 0.1 to 0.01 mol % palladium.
Keywords
C-H functionalization, direct arylation, heterocycles, N-heterocyclic carbenes, palladium, CATALYZED DIRECT ARYLATION, C-H BONDS, PALLADIUM COMPLEXES, CARBENE COMPLEXES, SUZUKI-MIYAURA, ELECTRONIC-PROPERTIES, BUCHWALD-HARTWIG, ARYL BROMIDES, PRE-CATALYST, NHC

Citation

Please use this url to cite or link to this publication:

MLA
Martin, Anthony R., et al. “Extending the Utility of [Pd(NHC)(Cinnamyl)Cl] Precatalysts : Direct Arylation of Heterocycles.” BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, vol. 8, 2012, pp. 1637–43, doi:10.3762/bjoc.8.187.
APA
Martin, A. R., Chartoire, A., Slawin, A. M., & Nolan, S. (2012). Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : direct arylation of heterocycles. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 8, 1637–1643. https://doi.org/10.3762/bjoc.8.187
Chicago author-date
Martin, Anthony R, Anthony Chartoire, Alexandra MZ Slawin, and Steven Nolan. 2012. “Extending the Utility of [Pd(NHC)(Cinnamyl)Cl] Precatalysts : Direct Arylation of Heterocycles.” BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 8: 1637–43. https://doi.org/10.3762/bjoc.8.187.
Chicago author-date (all authors)
Martin, Anthony R, Anthony Chartoire, Alexandra MZ Slawin, and Steven Nolan. 2012. “Extending the Utility of [Pd(NHC)(Cinnamyl)Cl] Precatalysts : Direct Arylation of Heterocycles.” BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 8: 1637–1643. doi:10.3762/bjoc.8.187.
Vancouver
1.
Martin AR, Chartoire A, Slawin AM, Nolan S. Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : direct arylation of heterocycles. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY. 2012;8:1637–43.
IEEE
[1]
A. R. Martin, A. Chartoire, A. M. Slawin, and S. Nolan, “Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : direct arylation of heterocycles,” BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, vol. 8, pp. 1637–1643, 2012.
@article{8168858,
  abstract     = {{The use of [Pd(NHC)(cinnamyl)Cl] precatalysts in the direct arylation of heterocycles has been investigated. Among four different precatalysts, [Pd(SIPr)(cinnamyl)Cl] proved to be the most efficient promoter of the reaction. The C-H functionalization of sulfur- or nitrogen-containing heterocycles has been achieved at low catalyst loadings. These catalyst charges range from 0.1 to 0.01 mol % palladium.}},
  author       = {{Martin, Anthony R and Chartoire, Anthony and Slawin, Alexandra MZ and Nolan, Steven}},
  issn         = {{1860-5397}},
  journal      = {{BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY}},
  keywords     = {{C-H functionalization,direct arylation,heterocycles,N-heterocyclic carbenes,palladium,CATALYZED DIRECT ARYLATION,C-H BONDS,PALLADIUM COMPLEXES,CARBENE COMPLEXES,SUZUKI-MIYAURA,ELECTRONIC-PROPERTIES,BUCHWALD-HARTWIG,ARYL BROMIDES,PRE-CATALYST,NHC}},
  language     = {{eng}},
  pages        = {{1637--1643}},
  title        = {{Extending the utility of [Pd(NHC)(cinnamyl)Cl] precatalysts : direct arylation of heterocycles}},
  url          = {{http://dx.doi.org/10.3762/bjoc.8.187}},
  volume       = {{8}},
  year         = {{2012}},
}

Altmetric
View in Altmetric
Web of Science
Times cited: