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Well-defined NHC-rhodium hydroxide complexes as alkene hydrosilylation and dehydrogenative silylation catalysts

Byron J Truscott, Alexandra MZ Slawin and Steven Nolan (UGent)
(2013) DALTON TRANSACTIONS. 42(1). p.270-276
Author
Organization
Abstract
Alkene hydrosilylation and dehydrogenative silylation reactions, mediated by [Rh(cod)(NHC)(OH)] complexes (cod = 1,5-cyclooctadiene; NHC = N-heterocyclic carbene) are described. The study details a comparison of the catalytic activity and steric characteristics of four rhodium complexes bearing different NHC ligands. The novel [Rh(cod)(Ii-PrMe)(OH)] complex (Ii-PrMe = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidine) was designed to improve the reactivity of Rh(I)-hydroxides and proved to be a successful promoter of hydrosilylation and dehydrogenative silylation, displaying good stereo- and regiocontrol.
Keywords
N-HETEROCYCLIC CARBENE, PLATINUM(0)-CARBENE COMPLEXES, MECHANISM, EFFICIENT, SYSTEM

Citation

Please use this url to cite or link to this publication:

MLA
Truscott, Byron J., et al. “Well-Defined NHC-Rhodium Hydroxide Complexes as Alkene Hydrosilylation and Dehydrogenative Silylation Catalysts.” DALTON TRANSACTIONS, vol. 42, no. 1, 2013, pp. 270–76.
APA
Truscott, B. J., Slawin, A. M., & Nolan, S. (2013). Well-defined NHC-rhodium hydroxide complexes as alkene hydrosilylation and dehydrogenative silylation catalysts. DALTON TRANSACTIONS, 42(1), 270–276.
Chicago author-date
Truscott, Byron J, Alexandra MZ Slawin, and Steven Nolan. 2013. “Well-Defined NHC-Rhodium Hydroxide Complexes as Alkene Hydrosilylation and Dehydrogenative Silylation Catalysts.” DALTON TRANSACTIONS 42 (1): 270–76.
Chicago author-date (all authors)
Truscott, Byron J, Alexandra MZ Slawin, and Steven Nolan. 2013. “Well-Defined NHC-Rhodium Hydroxide Complexes as Alkene Hydrosilylation and Dehydrogenative Silylation Catalysts.” DALTON TRANSACTIONS 42 (1): 270–276.
Vancouver
1.
Truscott BJ, Slawin AM, Nolan S. Well-defined NHC-rhodium hydroxide complexes as alkene hydrosilylation and dehydrogenative silylation catalysts. DALTON TRANSACTIONS. 2013;42(1):270–6.
IEEE
[1]
B. J. Truscott, A. M. Slawin, and S. Nolan, “Well-defined NHC-rhodium hydroxide complexes as alkene hydrosilylation and dehydrogenative silylation catalysts,” DALTON TRANSACTIONS, vol. 42, no. 1, pp. 270–276, 2013.
@article{8168836,
  abstract     = {Alkene hydrosilylation and dehydrogenative silylation reactions, mediated by [Rh(cod)(NHC)(OH)] complexes (cod = 1,5-cyclooctadiene; NHC = N-heterocyclic carbene) are described. The study details a comparison of the catalytic activity and steric characteristics of four rhodium complexes bearing different NHC ligands. The novel [Rh(cod)(Ii-PrMe)(OH)] complex (Ii-PrMe = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidine) was designed to improve the reactivity of Rh(I)-hydroxides and proved to be a successful promoter of hydrosilylation and dehydrogenative silylation, displaying good stereo- and regiocontrol.},
  author       = {Truscott, Byron J and Slawin, Alexandra MZ and Nolan, Steven},
  issn         = {1477-9226},
  journal      = {DALTON TRANSACTIONS},
  keywords     = {N-HETEROCYCLIC CARBENE,PLATINUM(0)-CARBENE COMPLEXES,MECHANISM,EFFICIENT,SYSTEM},
  language     = {eng},
  number       = {1},
  pages        = {270--276},
  title        = {Well-defined NHC-rhodium hydroxide complexes as alkene hydrosilylation and dehydrogenative silylation catalysts},
  url          = {http://dx.doi.org/10.1039/c2dt31339a},
  volume       = {42},
  year         = {2013},
}
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