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Exploring the limits of catalytic ammonia-borane dehydrogenation using a bis(N-heterocyclic carbene) iridium(III) complex

David J Nelson, Byron J Truscott, Jonathan D Egbert and Steven Nolan (UGent)
(2013) ORGANOMETALLICS. 32(13). p.3769-3772
Author
Organization
Abstract
Ammonia borane dehydrogenation can be catalyzed by a number of organometallic species. [Ir(kappa(2)-(IBu)-Bu-t)(2)][PF6] ((IBu)-Bu-t = 1,3-bis(tert-butyl)imidazol-2-ylidene) is the most active catalyst for this process that has been reported to date. We explore herein the absolute limits of the use of this and related complexes, including [Ir(kappa(2)-(IBu)-Bu-t)(2)][BAr4F], [Ir(H)(2)((IBu)-Bu-t)(2)]-[BAr4F], and [Ir(kappa(2)-(IBu)-Bu-t)(2)(NH3)][BAr4F] (BAr4F = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate).
Keywords
CHEMICAL HYDROGEN STORAGE, C-H ACTIVATION, SOLVOLYSIS, CHEMISTRY, FUTURE

Citation

Please use this url to cite or link to this publication:

MLA
Nelson, David J., et al. “Exploring the Limits of Catalytic Ammonia-Borane Dehydrogenation Using a Bis(N-Heterocyclic Carbene) Iridium(III) Complex.” ORGANOMETALLICS, vol. 32, no. 13, 2013, pp. 3769–72.
APA
Nelson, D. J., Truscott, B. J., Egbert, J. D., & Nolan, S. (2013). Exploring the limits of catalytic ammonia-borane dehydrogenation using a bis(N-heterocyclic carbene) iridium(III) complex. ORGANOMETALLICS, 32(13), 3769–3772.
Chicago author-date
Nelson, David J, Byron J Truscott, Jonathan D Egbert, and Steven Nolan. 2013. “Exploring the Limits of Catalytic Ammonia-Borane Dehydrogenation Using a Bis(N-Heterocyclic Carbene) Iridium(III) Complex.” ORGANOMETALLICS 32 (13): 3769–72.
Chicago author-date (all authors)
Nelson, David J, Byron J Truscott, Jonathan D Egbert, and Steven Nolan. 2013. “Exploring the Limits of Catalytic Ammonia-Borane Dehydrogenation Using a Bis(N-Heterocyclic Carbene) Iridium(III) Complex.” ORGANOMETALLICS 32 (13): 3769–3772.
Vancouver
1.
Nelson DJ, Truscott BJ, Egbert JD, Nolan S. Exploring the limits of catalytic ammonia-borane dehydrogenation using a bis(N-heterocyclic carbene) iridium(III) complex. ORGANOMETALLICS. 2013;32(13):3769–72.
IEEE
[1]
D. J. Nelson, B. J. Truscott, J. D. Egbert, and S. Nolan, “Exploring the limits of catalytic ammonia-borane dehydrogenation using a bis(N-heterocyclic carbene) iridium(III) complex,” ORGANOMETALLICS, vol. 32, no. 13, pp. 3769–3772, 2013.
@article{8168693,
  abstract     = {Ammonia borane dehydrogenation can be catalyzed by a number of organometallic species. [Ir(kappa(2)-(IBu)-Bu-t)(2)][PF6] ((IBu)-Bu-t = 1,3-bis(tert-butyl)imidazol-2-ylidene) is the most active catalyst for this process that has been reported to date. We explore herein the absolute limits of the use of this and related complexes, including [Ir(kappa(2)-(IBu)-Bu-t)(2)][BAr4F], [Ir(H)(2)((IBu)-Bu-t)(2)]-[BAr4F], and [Ir(kappa(2)-(IBu)-Bu-t)(2)(NH3)][BAr4F] (BAr4F = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate).},
  author       = {Nelson, David J and Truscott, Byron J and Egbert, Jonathan D and Nolan, Steven},
  issn         = {0276-7333},
  journal      = {ORGANOMETALLICS},
  keywords     = {CHEMICAL HYDROGEN STORAGE,C-H ACTIVATION,SOLVOLYSIS,CHEMISTRY,FUTURE},
  language     = {eng},
  number       = {13},
  pages        = {3769--3772},
  title        = {Exploring the limits of catalytic ammonia-borane dehydrogenation using a bis(N-heterocyclic carbene) iridium(III) complex},
  url          = {http://dx.doi.org/10.1021/om400402r},
  volume       = {32},
  year         = {2013},
}
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