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CO2 fixation employing an iridium(I)-hydroxide complex

(2014) CHEMICAL COMMUNICATIONS. 50(3). p.286-288
Author
Organization
Abstract
The reactivity of a number of Ir-I complexes towards CO2 is explored using [Ir(NHC)(OH)] as a key synthon. CO2 insertion into Ir-O and Ir-N bonds proved facile, yielding a number of Ir-I-carbonates and -carbamates. Most importantly, reaction between CO2 and Ir-I-OH led to isolation of the novel [{Ir-I}(2)-(mu-kappa(1):kappa(2)-CO3)] complex.
Keywords
DIOXIDE COORDINATION CHEMISTRY, TRANSITION-METAL-COMPLEXES, CARBON-DIOXIDE, REDUCTIVE ELIMINATION, MOLECULAR-STRUCTURE, REACTIVITY, INSERTION, ACTIVATION, RHODIUM, BOND

Citation

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Chicago
Truscott, Byron J, David J Nelson, Alexandra MZ Slawin, and Steven Nolan. 2014. “CO2 Fixation Employing an iridium(I)-hydroxide Complex.” Chemical Communications 50 (3): 286–288.
APA
Truscott, B. J., Nelson, D. J., Slawin, A. M., & Nolan, S. (2014). CO2 fixation employing an iridium(I)-hydroxide complex. CHEMICAL COMMUNICATIONS, 50(3), 286–288.
Vancouver
1.
Truscott BJ, Nelson DJ, Slawin AM, Nolan S. CO2 fixation employing an iridium(I)-hydroxide complex. CHEMICAL COMMUNICATIONS. 2014;50(3):286–8.
MLA
Truscott, Byron J, David J Nelson, Alexandra MZ Slawin, et al. “CO2 Fixation Employing an iridium(I)-hydroxide Complex.” CHEMICAL COMMUNICATIONS 50.3 (2014): 286–288. Print.
@article{8168588,
  abstract     = {The reactivity of a number of Ir-I complexes towards CO2 is explored using [Ir(NHC)(OH)] as a key synthon. CO2 insertion into Ir-O and Ir-N bonds proved facile, yielding a number of Ir-I-carbonates and -carbamates. Most importantly, reaction between CO2 and Ir-I-OH led to isolation of the novel [\{Ir-I\}(2)-(mu-kappa(1):kappa(2)-CO3)] complex.},
  author       = {Truscott, Byron J and Nelson, David J and Slawin, Alexandra MZ and Nolan, Steven},
  issn         = {1359-7345},
  journal      = {CHEMICAL COMMUNICATIONS},
  keyword      = {DIOXIDE COORDINATION CHEMISTRY,TRANSITION-METAL-COMPLEXES,CARBON-DIOXIDE,REDUCTIVE ELIMINATION,MOLECULAR-STRUCTURE,REACTIVITY,INSERTION,ACTIVATION,RHODIUM,BOND},
  language     = {eng},
  number       = {3},
  pages        = {286--288},
  title        = {CO2 fixation employing an iridium(I)-hydroxide complex},
  url          = {http://dx.doi.org/10.1039/c3cc46922k},
  volume       = {50},
  year         = {2014},
}

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