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Ruthenium catalysed C-H bond borylation

Jose A Fernandez-Salas, Simone Manzini, Lorenzo Piola, Alexandra MZ Slawin and Steven Nolan (UGent)
(2014) CHEMICAL COMMUNICATIONS. 50(51). p.6782-6784
Author
Organization
Abstract
An easily prepared series of phenylindenyldihydridosilyl ruthenium complexes (2a-2d) was obtained by reaction of tertiary silanes with the commercially-available [RuCl(3-phenylindenyl)(PPh3)(2)] (1). The [RuH2(3-phenylindenyl)(SiEt3)] (2a) complex was shown to be highly efficient (1.5mol%) in the ortho-selective borylation of pyridyl substrates, with yields of up to 90%. A novel ruthenium(IV)-catalysed C-H activation borylation/functionalization reaction using a remarkably low catalyst loadings is described.
Keywords
ROOM-TEMPERATURE REACTIONS, DIRECTED ORTHO BORYLATION, FUNCTIONALIZED ARENES, SILYLENE COMPLEXES, ACTIVATION, REACTIVITY, MECHANISM, SILANES, CONSTRUCTION, HETEROCYCLES

Citation

Please use this url to cite or link to this publication:

Chicago
Fernandez-Salas, Jose A, Simone Manzini, Lorenzo Piola, Alexandra MZ Slawin, and Steven Nolan. 2014. “Ruthenium Catalysed C-H Bond Borylation.” Chemical Communications 50 (51): 6782–6784.
APA
Fernandez-Salas, J. A., Manzini, S., Piola, L., Slawin, A. M., & Nolan, S. (2014). Ruthenium catalysed C-H bond borylation. CHEMICAL COMMUNICATIONS, 50(51), 6782–6784.
Vancouver
1.
Fernandez-Salas JA, Manzini S, Piola L, Slawin AM, Nolan S. Ruthenium catalysed C-H bond borylation. CHEMICAL COMMUNICATIONS. 2014;50(51):6782–4.
MLA
Fernandez-Salas, Jose A, Simone Manzini, Lorenzo Piola, et al. “Ruthenium Catalysed C-H Bond Borylation.” CHEMICAL COMMUNICATIONS 50.51 (2014): 6782–6784. Print.
@article{8168572,
  abstract     = {An easily prepared series of phenylindenyldihydridosilyl ruthenium complexes (2a-2d) was obtained by reaction of tertiary silanes with the commercially-available [RuCl(3-phenylindenyl)(PPh3)(2)] (1). The [RuH2(3-phenylindenyl)(SiEt3)] (2a) complex was shown to be highly efficient (1.5mol\%) in the ortho-selective borylation of pyridyl substrates, with yields of up to 90\%. A novel ruthenium(IV)-catalysed C-H activation borylation/functionalization reaction using a remarkably low catalyst loadings is described.},
  author       = {Fernandez-Salas, Jose A and Manzini, Simone and Piola, Lorenzo and Slawin, Alexandra MZ and Nolan, Steven},
  issn         = {1359-7345},
  journal      = {CHEMICAL COMMUNICATIONS},
  keyword      = {ROOM-TEMPERATURE REACTIONS,DIRECTED ORTHO BORYLATION,FUNCTIONALIZED ARENES,SILYLENE COMPLEXES,ACTIVATION,REACTIVITY,MECHANISM,SILANES,CONSTRUCTION,HETEROCYCLES},
  language     = {eng},
  number       = {51},
  pages        = {6782--6784},
  title        = {Ruthenium catalysed C-H bond borylation},
  url          = {http://dx.doi.org/10.1039/c4cc02096k},
  volume       = {50},
  year         = {2014},
}
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