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New [Au(NHC)(OH)] complexes for silver-free protocols

(2014) ORGANOMETALLICS. 33(1). p.421-424
Author
Organization
Abstract
Novel (NHC)gold(I) hydroxides are reported. Their differing tolerances to air and moisture are rationalized by the varying abilities of the NHC ligands to sterically protect the reactive metal center. A number of gold hydroxides were used in the silver-free preparation of Gagosz-type catalysts. This general procedure led to analytically pure products while avoiding the use of expensive silver reagents.
Keywords
N-HETEROCYCLIC CARBENE, ABNORMAL NHC-GOLD(I) COMPLEXES, GOLD(I) COMPLEXES, CATALYSIS, PHOSPHINE, NHC, REACTIVITY, HYDROXIDES, ADDITIVES, EFFICIENT

Citation

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Chicago
Patrick, Scott R, Adrian Gomez-Suarez, Alexandra MZ Slawin, and Steven Nolan. 2014. “New [Au(NHC)(OH)] Complexes for Silver-free Protocols.” Organometallics 33 (1): 421–424.
APA
Patrick, S. R., Gomez-Suarez, A., Slawin, A. M., & Nolan, S. (2014). New [Au(NHC)(OH)] complexes for silver-free protocols. ORGANOMETALLICS, 33(1), 421–424.
Vancouver
1.
Patrick SR, Gomez-Suarez A, Slawin AM, Nolan S. New [Au(NHC)(OH)] complexes for silver-free protocols. ORGANOMETALLICS. 2014;33(1):421–4.
MLA
Patrick, Scott R, Adrian Gomez-Suarez, Alexandra MZ Slawin, et al. “New [Au(NHC)(OH)] Complexes for Silver-free Protocols.” ORGANOMETALLICS 33.1 (2014): 421–424. Print.
@article{8168527,
  abstract     = {Novel (NHC)gold(I) hydroxides are reported. Their differing tolerances to air and moisture are rationalized by the varying abilities of the NHC ligands to sterically protect the reactive metal center. A number of gold hydroxides were used in the silver-free preparation of Gagosz-type catalysts. This general procedure led to analytically pure products while avoiding the use of expensive silver reagents.},
  author       = {Patrick, Scott R and Gomez-Suarez, Adrian and Slawin, Alexandra MZ and Nolan, Steven},
  issn         = {0276-7333},
  journal      = {ORGANOMETALLICS},
  keyword      = {N-HETEROCYCLIC CARBENE,ABNORMAL NHC-GOLD(I) COMPLEXES,GOLD(I) COMPLEXES,CATALYSIS,PHOSPHINE,NHC,REACTIVITY,HYDROXIDES,ADDITIVES,EFFICIENT},
  language     = {eng},
  number       = {1},
  pages        = {421--424},
  title        = {New [Au(NHC)(OH)] complexes for silver-free protocols},
  url          = {http://dx.doi.org/10.1021/om4010065},
  volume       = {33},
  year         = {2014},
}

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