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Insights into the decomposition of olefin metathesis precatalysts

Simone Manzini, Albert Poater, David J. Nelson, Luigi Cavallo, Alexandra M. Z. Slawin and Steven Nolan UGent (2014) ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 53(34). p.8995-8999
abstract
The decomposition of a series of benzylidene, methylidene, and 3-phenylindenylidene complexes has been probed in alcohol solution in the presence of base. Tricyclohexylphosphane- containing precatalysts are shown to yield [RuCl(H)(H-2)(PCy3)(2)] in isopropyl alcohol solutions, while 3-phenylindenylidene complexes lead to eta(5)-(3-phenyl)indenyl products. The potential-energy surfaces for the formation of the latter species have been probed using density functional theory studies.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
density functional calculations, hydride ligands, metathesis, reaction mechanisms, ruthenium, RUTHENIUM PHENYLINDENYL COMPLEX, HETEROCYCLIC CARBENE LIGANDS, ORGANOMETALLIC CHEMISTRY, INDENYLIDENE COMPLEXES, ELECTRONIC-STRUCTURE, PRIMARY ALCOHOLS, BURIED VOLUME, CATALYST, ISOMERIZATION, DEGRADATION
journal title
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Angew. Chem.-Int. Edit.
volume
53
issue
34
pages
8995 - 8999
Web of Science type
Article
Web of Science id
000340526400029
JCR category
CHEMISTRY, MULTIDISCIPLINARY
JCR impact factor
11.261 (2014)
JCR rank
13/157 (2014)
JCR quartile
1 (2014)
ISSN
1433-7851
DOI
10.1002/anie.201403770
language
English
UGent publication?
no
classification
A1
id
8168454
handle
http://hdl.handle.net/1854/LU-8168454
date created
2016-11-24 15:53:08
date last changed
2018-01-29 12:12:10
@article{8168454,
  abstract     = {The decomposition of a series of benzylidene, methylidene, and 3-phenylindenylidene complexes has been probed in alcohol solution in the presence of base. Tricyclohexylphosphane- containing precatalysts are shown to yield [RuCl(H)(H-2)(PCy3)(2)] in isopropyl alcohol solutions, while 3-phenylindenylidene complexes lead to eta(5)-(3-phenyl)indenyl products. The potential-energy surfaces for the formation of the latter species have been probed using density functional theory studies.},
  author       = {Manzini, Simone and Poater, Albert and Nelson, David J. and Cavallo, Luigi and Slawin, Alexandra M. Z. and Nolan, Steven},
  issn         = {1433-7851},
  journal      = {ANGEWANDTE CHEMIE-INTERNATIONAL EDITION},
  keyword      = {density functional calculations,hydride ligands,metathesis,reaction mechanisms,ruthenium,RUTHENIUM PHENYLINDENYL COMPLEX,HETEROCYCLIC CARBENE LIGANDS,ORGANOMETALLIC CHEMISTRY,INDENYLIDENE COMPLEXES,ELECTRONIC-STRUCTURE,PRIMARY ALCOHOLS,BURIED VOLUME,CATALYST,ISOMERIZATION,DEGRADATION},
  language     = {eng},
  number       = {34},
  pages        = {8995--8999},
  title        = {Insights into the decomposition of olefin metathesis precatalysts},
  url          = {http://dx.doi.org/10.1002/anie.201403770},
  volume       = {53},
  year         = {2014},
}

Chicago
Manzini, Simone, Albert Poater, David J. Nelson, Luigi Cavallo, Alexandra M. Z. Slawin, and Steven Nolan. 2014. “Insights into the Decomposition of Olefin Metathesis Precatalysts.” Angewandte Chemie-international Edition 53 (34): 8995–8999.
APA
Manzini, S., Poater, A., Nelson, D. J., Cavallo, L., Slawin, A. M. Z., & Nolan, S. (2014). Insights into the decomposition of olefin metathesis precatalysts. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 53(34), 8995–8999.
Vancouver
1.
Manzini S, Poater A, Nelson DJ, Cavallo L, Slawin AMZ, Nolan S. Insights into the decomposition of olefin metathesis precatalysts. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2014;53(34):8995–9.
MLA
Manzini, Simone, Albert Poater, David J. Nelson, et al. “Insights into the Decomposition of Olefin Metathesis Precatalysts.” ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.34 (2014): 8995–8999. Print.