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Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)

(2015) CHEMICAL COMMUNICATIONS. 51(1). p.62-65
Author
Organization
Abstract
Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir-bifluoride and Ir(I)-NHC and Rh(I)-NHC trifluoromethyl complexes are revealed.
Keywords
HETEROCYCLIC CARBENE COMPLEXES, TRANSITION-METAL CATALYSIS, C-F ACTIVATION, BOND ACTIVATION, X-RAY, NUCLEOPHILIC FLUORINATION, WILKINSONS CATALYST, CRYSTAL-STRUCTURES, HYDRIDE COMPLEXES, REACTIVITY

Citation

Please use this url to cite or link to this publication:

MLA
Truscott, Byron J., et al. “Fluoride, Bifluoride and Trifluoromethyl Complexes of Iridium(I) and Rhodium(I).” CHEMICAL COMMUNICATIONS, vol. 51, no. 1, 2015, pp. 62–65.
APA
Truscott, B. J., Nahra, F., Slawin, A. M., Cordes, D. B., & Nolan, S. (2015). Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I). CHEMICAL COMMUNICATIONS, 51(1), 62–65.
Chicago author-date
Truscott, Byron J, Fady Nahra, Alexandra MZ Slawin, David B Cordes, and Steven Nolan. 2015. “Fluoride, Bifluoride and Trifluoromethyl Complexes of Iridium(I) and Rhodium(I).” CHEMICAL COMMUNICATIONS 51 (1): 62–65.
Chicago author-date (all authors)
Truscott, Byron J, Fady Nahra, Alexandra MZ Slawin, David B Cordes, and Steven Nolan. 2015. “Fluoride, Bifluoride and Trifluoromethyl Complexes of Iridium(I) and Rhodium(I).” CHEMICAL COMMUNICATIONS 51 (1): 62–65.
Vancouver
1.
Truscott BJ, Nahra F, Slawin AM, Cordes DB, Nolan S. Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I). CHEMICAL COMMUNICATIONS. 2015;51(1):62–5.
IEEE
[1]
B. J. Truscott, F. Nahra, A. M. Slawin, D. B. Cordes, and S. Nolan, “Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I),” CHEMICAL COMMUNICATIONS, vol. 51, no. 1, pp. 62–65, 2015.
@article{8168410,
  abstract     = {Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir-bifluoride and Ir(I)-NHC and Rh(I)-NHC trifluoromethyl complexes are revealed.},
  author       = {Truscott, Byron J and Nahra, Fady and Slawin, Alexandra MZ and Cordes, David B and Nolan, Steven},
  issn         = {1359-7345},
  journal      = {CHEMICAL COMMUNICATIONS},
  keywords     = {HETEROCYCLIC CARBENE COMPLEXES,TRANSITION-METAL CATALYSIS,C-F ACTIVATION,BOND ACTIVATION,X-RAY,NUCLEOPHILIC FLUORINATION,WILKINSONS CATALYST,CRYSTAL-STRUCTURES,HYDRIDE COMPLEXES,REACTIVITY},
  language     = {eng},
  number       = {1},
  pages        = {62--65},
  title        = {Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)},
  url          = {http://dx.doi.org/10.1039/c4cc07772e},
  volume       = {51},
  year         = {2015},
}

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