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Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)

Byron J Truscott, Fady Nahra UGent, Alexandra MZ Slawin, David B Cordes and Steven Nolan UGent (2015) CHEMICAL COMMUNICATIONS. 51(1). p.62-65
abstract
Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir-bifluoride and Ir(I)-NHC and Rh(I)-NHC trifluoromethyl complexes are revealed.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
HETEROCYCLIC CARBENE COMPLEXES, TRANSITION-METAL CATALYSIS, C-F ACTIVATION, BOND ACTIVATION, X-RAY, NUCLEOPHILIC FLUORINATION, WILKINSONS CATALYST, CRYSTAL-STRUCTURES, HYDRIDE COMPLEXES, REACTIVITY
journal title
CHEMICAL COMMUNICATIONS
Chem. Commun.
volume
51
issue
1
pages
62 - 65
Web of Science type
Article
Web of Science id
000345909400007
JCR category
CHEMISTRY, MULTIDISCIPLINARY
JCR impact factor
6.567 (2015)
JCR rank
21/163 (2015)
JCR quartile
1 (2015)
ISSN
1359-7345
DOI
10.1039/c4cc07772e
language
English
UGent publication?
no
classification
A1
id
8168410
handle
http://hdl.handle.net/1854/LU-8168410
date created
2016-11-24 15:50:52
date last changed
2018-01-29 12:12:58
@article{8168410,
  abstract     = {Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir-bifluoride and Ir(I)-NHC and Rh(I)-NHC trifluoromethyl complexes are revealed.},
  author       = {Truscott, Byron J and Nahra, Fady and Slawin, Alexandra MZ and Cordes, David B and Nolan, Steven},
  issn         = {1359-7345},
  journal      = {CHEMICAL COMMUNICATIONS},
  keyword      = {HETEROCYCLIC CARBENE COMPLEXES,TRANSITION-METAL CATALYSIS,C-F ACTIVATION,BOND ACTIVATION,X-RAY,NUCLEOPHILIC FLUORINATION,WILKINSONS CATALYST,CRYSTAL-STRUCTURES,HYDRIDE COMPLEXES,REACTIVITY},
  language     = {eng},
  number       = {1},
  pages        = {62--65},
  title        = {Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)},
  url          = {http://dx.doi.org/10.1039/c4cc07772e},
  volume       = {51},
  year         = {2015},
}

Chicago
Truscott, Byron J, Fady Nahra, Alexandra MZ Slawin, David B Cordes, and Steven Nolan. 2015. “Fluoride, Bifluoride and Trifluoromethyl Complexes of iridium(I) and rhodium(I).” Chemical Communications 51 (1): 62–65.
APA
Truscott, B. J., Nahra, F., Slawin, A. M., Cordes, D. B., & Nolan, S. (2015). Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I). CHEMICAL COMMUNICATIONS, 51(1), 62–65.
Vancouver
1.
Truscott BJ, Nahra F, Slawin AM, Cordes DB, Nolan S. Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I). CHEMICAL COMMUNICATIONS. 2015;51(1):62–5.
MLA
Truscott, Byron J, Fady Nahra, Alexandra MZ Slawin, et al. “Fluoride, Bifluoride and Trifluoromethyl Complexes of iridium(I) and rhodium(I).” CHEMICAL COMMUNICATIONS 51.1 (2015): 62–65. Print.