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Gold-acetonyl complexes : from side-products to valuable synthons

(2015) CHEMISTRY-A EUROPEAN JOURNAL. 21(14). p.5403-5412
Author
Organization
Abstract
A new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH3)]. The approach capitalizes on the formation of a decomposition product observed in the course of the synthesis of [Au(IPr)(CI)]. A library of gold acetonyl complexes containing the most common N-heterocyclic carbene (NHC) ligands has been synthesized. These acetonyl complexes are good synthons for the preparation of numerous organogold complexes. Moreover, they have proven to be precatalysts in common gold(I)-catalyzed reactions.
Keywords
acetonyl, carbenes, gold, homogeneous, catalysis, organogolci, N-HETEROCYCLIC CARBENE, C-H ACTIVATION, STRUCTURAL-CHARACTERIZATION, PLATINUM(II) COMPLEXES, MOLECULAR-STRUCTURE, BOND ACTIVATION, ALPHA-ARYLATION, 2-PHENYLAZOPHENYLGOLD(III) COMPLEXES, KETONYLGOLD(III) COMPLEXES, ORGANIC TRANSFORMATIONS

Citation

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MLA
Gasperini, Danila, et al. “Gold-Acetonyl Complexes : From Side-Products to Valuable Synthons.” CHEMISTRY-A EUROPEAN JOURNAL, vol. 21, no. 14, 2015, pp. 5403–12.
APA
Gasperini, D., Collado, A., Gomez-Suarez, A., Cordes, D. B., Slawin, A. M., & Nolan, S. (2015). Gold-acetonyl complexes : from side-products to valuable synthons. CHEMISTRY-A EUROPEAN JOURNAL, 21(14), 5403–5412.
Chicago author-date
Gasperini, Danila, Alba Collado, Adrian Gomez-Suarez, David B Cordes, Alexandra MZ Slawin, and Steven Nolan. 2015. “Gold-Acetonyl Complexes : From Side-Products to Valuable Synthons.” CHEMISTRY-A EUROPEAN JOURNAL 21 (14): 5403–12.
Chicago author-date (all authors)
Gasperini, Danila, Alba Collado, Adrian Gomez-Suarez, David B Cordes, Alexandra MZ Slawin, and Steven Nolan. 2015. “Gold-Acetonyl Complexes : From Side-Products to Valuable Synthons.” CHEMISTRY-A EUROPEAN JOURNAL 21 (14): 5403–5412.
Vancouver
1.
Gasperini D, Collado A, Gomez-Suarez A, Cordes DB, Slawin AM, Nolan S. Gold-acetonyl complexes : from side-products to valuable synthons. CHEMISTRY-A EUROPEAN JOURNAL. 2015;21(14):5403–12.
IEEE
[1]
D. Gasperini, A. Collado, A. Gomez-Suarez, D. B. Cordes, A. M. Slawin, and S. Nolan, “Gold-acetonyl complexes : from side-products to valuable synthons,” CHEMISTRY-A EUROPEAN JOURNAL, vol. 21, no. 14, pp. 5403–5412, 2015.
@article{8168319,
  abstract     = {A new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH3)]. The approach capitalizes on the formation of a decomposition product observed in the course of the synthesis of [Au(IPr)(CI)]. A library of gold acetonyl complexes containing the most common N-heterocyclic carbene (NHC) ligands has been synthesized. These acetonyl complexes are good synthons for the preparation of numerous organogold complexes. Moreover, they have proven to be precatalysts in common gold(I)-catalyzed reactions.},
  author       = {Gasperini, Danila and Collado, Alba and Gomez-Suarez, Adrian and Cordes, David B and Slawin, Alexandra MZ and Nolan, Steven},
  issn         = {0947-6539},
  journal      = {CHEMISTRY-A EUROPEAN JOURNAL},
  keywords     = {acetonyl,carbenes,gold,homogeneous,catalysis,organogolci,N-HETEROCYCLIC CARBENE,C-H ACTIVATION,STRUCTURAL-CHARACTERIZATION,PLATINUM(II) COMPLEXES,MOLECULAR-STRUCTURE,BOND ACTIVATION,ALPHA-ARYLATION,2-PHENYLAZOPHENYLGOLD(III) COMPLEXES,KETONYLGOLD(III) COMPLEXES,ORGANIC TRANSFORMATIONS},
  language     = {eng},
  number       = {14},
  pages        = {5403--5412},
  title        = {Gold-acetonyl complexes : from side-products to valuable synthons},
  url          = {http://dx.doi.org/10.1002/chem.201406543},
  volume       = {21},
  year         = {2015},
}

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