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Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis

Author
Organization
Abstract
Three new Au(I) complexes of the formula [Au(NHC)(NTf2)] (NHC = N-heterocyclic carbene) bearing bulky and flexible ligands have been synthesised. The ligands studied are IPent, IHept and INon which belong to the 'ITent' ('Tent' for 'tentacular') family of NHC derivatives. The effect of these ligands in gold-promoted transformations has been investigated.
Keywords
catalysis, flexible and bulky ligands, gold, ligand design, N-heterocyclic carbenes, ORTHO-SUBSTITUTED BIARYLS, CROSS-COUPLING REACTIONS, PD-PEPPSI-IPENT, ROOM-TEMPERATURE, HIGHLY EFFICIENT, ORGANIC TRANSFORMATIONS, RESTRICTED FLEXIBILITY, NHC COMPLEXES, PRE-CATALYST, PALLADIUM

Citation

Please use this url to cite or link to this publication:

MLA
Collado, Alba et al. “Influence of Bulky yet Flexible N-heterocyclic Carbene Ligands in Gold Catalysis.” BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 11 (2015): n. pag. Print.
APA
Collado, A., Patrick, S. R., Gasperini, D., Meiries, S., & Nolan, S. (2015). Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 11.
Chicago author-date
Collado, Alba, Scott R Patrick, Danila Gasperini, Sebastien Meiries, and Steven Nolan. 2015. “Influence of Bulky yet Flexible N-heterocyclic Carbene Ligands in Gold Catalysis.” Beilstein Journal of Organic Chemistry 11.
Chicago author-date (all authors)
Collado, Alba, Scott R Patrick, Danila Gasperini, Sebastien Meiries, and Steven Nolan. 2015. “Influence of Bulky yet Flexible N-heterocyclic Carbene Ligands in Gold Catalysis.” Beilstein Journal of Organic Chemistry 11.
Vancouver
1.
Collado A, Patrick SR, Gasperini D, Meiries S, Nolan S. Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY. 2015;11.
IEEE
[1]
A. Collado, S. R. Patrick, D. Gasperini, S. Meiries, and S. Nolan, “Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis,” BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, vol. 11, 2015.
@article{8168274,
  abstract     = {Three new Au(I) complexes of the formula [Au(NHC)(NTf2)] (NHC = N-heterocyclic carbene) bearing bulky and flexible ligands have been synthesised. The ligands studied are IPent, IHept and INon which belong to the 'ITent' ('Tent' for 'tentacular') family of NHC derivatives. The effect of these ligands in gold-promoted transformations has been investigated.},
  author       = {Collado, Alba and Patrick, Scott R and Gasperini, Danila and Meiries, Sebastien and Nolan, Steven},
  issn         = {1860-5397},
  journal      = {BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY},
  keywords     = {catalysis,flexible and bulky ligands,gold,ligand design,N-heterocyclic carbenes,ORTHO-SUBSTITUTED BIARYLS,CROSS-COUPLING REACTIONS,PD-PEPPSI-IPENT,ROOM-TEMPERATURE,HIGHLY EFFICIENT,ORGANIC TRANSFORMATIONS,RESTRICTED FLEXIBILITY,NHC COMPLEXES,PRE-CATALYST,PALLADIUM},
  language     = {eng},
  pages        = {6},
  title        = {Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis},
  url          = {http://dx.doi.org/10.3762/bjoc.11.196},
  volume       = {11},
  year         = {2015},
}

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