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Olefin metathesis in air

Lorenzo Piola, Fady Nahra (UGent) and Steven Nolan (UGent)
Author
Organization
Abstract
Since the discovery and now widespread use of olefin metathesis, the evolution of metathesis catalysts towards air stability has become an area of significant interest. In this fascinating area of study, beginning with early systems making use of high oxidation state early transition metal centers that required strict exclusion of water and air, advances have been made to render catalysts more stable and yet more functional group tolerant. This review summarizes the major developments concerning catalytic systems directed towards water and air tolerance.
Keywords
air stability, catalysis, olefin metathesis, RCM, ROMP, ruthenium, RING-CLOSING METATHESIS, N-HETEROCYCLIC CARBENES, ENOL-ESTER SYNTHESIS, RUTHENIUM-INDENYLIDENE COMPLEXES, TRANSFER RADICAL-ADDITION, SCHIFF-BASE LIGANDS, CROSS-METATHESIS, VINYLIDENE COMPLEXES, ALKENE METATHESIS, IMIDAZOLIN-2-YLIDENE LIGANDS

Citation

Please use this url to cite or link to this publication:

Chicago
Piola, Lorenzo, Fady Nahra, and Steven Nolan. 2015. “Olefin Metathesis in Air.” Beilstein Journal of Organic Chemistry 11: 2038–2055.
APA
Piola, L., Nahra, F., & Nolan, S. (2015). Olefin metathesis in air. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 11, 2038–2055.
Vancouver
1.
Piola L, Nahra F, Nolan S. Olefin metathesis in air. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY. 2015;11:2038–55.
MLA
Piola, Lorenzo, Fady Nahra, and Steven Nolan. “Olefin Metathesis in Air.” BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 11 (2015): 2038–2055. Print.
@article{8168269,
  abstract     = {Since the discovery and now widespread use of olefin metathesis, the evolution of metathesis catalysts towards air stability has become an area of significant interest. In this fascinating area of study, beginning with early systems making use of high oxidation state early transition metal centers that required strict exclusion of water and air, advances have been made to render catalysts more stable and yet more functional group tolerant. This review summarizes the major developments concerning catalytic systems directed towards water and air tolerance.},
  author       = {Piola, Lorenzo and Nahra, Fady and Nolan, Steven},
  issn         = {1860-5397},
  journal      = {BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY},
  keyword      = {air stability,catalysis,olefin metathesis,RCM,ROMP,ruthenium,RING-CLOSING METATHESIS,N-HETEROCYCLIC CARBENES,ENOL-ESTER SYNTHESIS,RUTHENIUM-INDENYLIDENE COMPLEXES,TRANSFER RADICAL-ADDITION,SCHIFF-BASE LIGANDS,CROSS-METATHESIS,VINYLIDENE COMPLEXES,ALKENE METATHESIS,IMIDAZOLIN-2-YLIDENE LIGANDS},
  language     = {eng},
  pages        = {2038--2055},
  title        = {Olefin metathesis in air},
  url          = {http://dx.doi.org/10.3762/bjoc.11.221},
  volume       = {11},
  year         = {2015},
}

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