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A switchable gold catalyst by encapsulation in a self-assembled cage

(2016) CHEMISTRY-A EUROPEAN JOURNAL. 22(42). p.14836-14839
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Abstract
Dinuclear gold complexes have the ability to interact with one or more substrates in a dual-activation mode, leading to different reactivity and selectivity than their mononuclear relatives. In this contribution, this difference was used to control the catalytic properties of a gold-based catalytic system by site-isolation of mononuclear gold complexes by selective encapsulation. The typical dual-activation mode is prohibited by this catalyst encapsulation, leading to typical behavior as a result of mononuclear activation. This strategy can be used as a switch (on/off) for a catalytic reaction and also permits reversible control over the product distribution during the course of a reaction.
Keywords
catalyst encapsulation, catalytic switch, dual catalysis, gold catalysis, supramolecular chemistry, TRANSITION-METAL CATALYSTS, REVERSIBLE ENCAPSULATION, ALKYNES, LIGAND, COMPLEXES, HYDROPHENOXYLATION, HYDROFORMYLATION, WATER, ACTIVATION, MECHANISM

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Citation

Please use this url to cite or link to this publication:

MLA
Jans, Anne CH, et al. “A Switchable Gold Catalyst by Encapsulation in a Self-Assembled Cage.” CHEMISTRY-A EUROPEAN JOURNAL, vol. 22, no. 42, 2016, pp. 14836–39.
APA
Jans, A. C., Gomez-Suarez, A., Nolan, S., & Reek, J. N. (2016). A switchable gold catalyst by encapsulation in a self-assembled cage. CHEMISTRY-A EUROPEAN JOURNAL, 22(42), 14836–14839.
Chicago author-date
Jans, Anne CH, Adrian Gomez-Suarez, Steven Nolan, and Joost NH Reek. 2016. “A Switchable Gold Catalyst by Encapsulation in a Self-Assembled Cage.” CHEMISTRY-A EUROPEAN JOURNAL 22 (42): 14836–39.
Chicago author-date (all authors)
Jans, Anne CH, Adrian Gomez-Suarez, Steven Nolan, and Joost NH Reek. 2016. “A Switchable Gold Catalyst by Encapsulation in a Self-Assembled Cage.” CHEMISTRY-A EUROPEAN JOURNAL 22 (42): 14836–14839.
Vancouver
1.
Jans AC, Gomez-Suarez A, Nolan S, Reek JN. A switchable gold catalyst by encapsulation in a self-assembled cage. CHEMISTRY-A EUROPEAN JOURNAL. 2016;22(42):14836–9.
IEEE
[1]
A. C. Jans, A. Gomez-Suarez, S. Nolan, and J. N. Reek, “A switchable gold catalyst by encapsulation in a self-assembled cage,” CHEMISTRY-A EUROPEAN JOURNAL, vol. 22, no. 42, pp. 14836–14839, 2016.
@article{8168143,
  abstract     = {Dinuclear gold complexes have the ability to interact with one or more substrates in a dual-activation mode, leading to different reactivity and selectivity than their mononuclear relatives. In this contribution, this difference was used to control the catalytic properties of a gold-based catalytic system by site-isolation of mononuclear gold complexes by selective encapsulation. The typical dual-activation mode is prohibited by this catalyst encapsulation, leading to typical behavior as a result of mononuclear activation. This strategy can be used as a switch (on/off) for a catalytic reaction and also permits reversible control over the product distribution during the course of a reaction.},
  author       = {Jans, Anne CH and Gomez-Suarez, Adrian and Nolan, Steven and Reek, Joost NH},
  issn         = {0947-6539},
  journal      = {CHEMISTRY-A EUROPEAN JOURNAL},
  keywords     = {catalyst encapsulation,catalytic switch,dual catalysis,gold catalysis,supramolecular chemistry,TRANSITION-METAL CATALYSTS,REVERSIBLE ENCAPSULATION,ALKYNES,LIGAND,COMPLEXES,HYDROPHENOXYLATION,HYDROFORMYLATION,WATER,ACTIVATION,MECHANISM},
  language     = {eng},
  number       = {42},
  pages        = {14836--14839},
  title        = {A switchable gold catalyst by encapsulation in a self-assembled cage},
  url          = {http://dx.doi.org/10.1002/chem.201603162},
  volume       = {22},
  year         = {2016},
}

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