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The influence of phosphane ligands on the versatility of ruthenium-indenylidene complexes in metathesis

(2010) CHEMISTRY-A EUROPEAN JOURNAL. 16(30). p.9215-9225
Author
Organization
Abstract
The aim of the present study is to develop readily available and stable pre-catalysts that could be easily prepared on large scale from simple starting materials. Based on the hypothesis that substitution of classical PCy3 with phosphanes of varying electron-donating properties could be a straightforward manner to improve catalytic activity, a methodical study dealing with the effect of phosphane fine-tuning in ruthenium-indenylidene catalysts was performed. Challenged to establish how the electronic properties of para-substituted phosphane ligands translate into catalyst activity, the versatile behaviour of these new ruthenium-indenylidene complexes was investigated for a number of metathesis reactions.
Keywords
N-HETEROCYCLIC CARBENE, phosphane ligand rutheniuindenylidene metathesis catalyst, RING-CLOSING METATHESIS, OLEFIN METATHESIS, CATALYSTS BEARING, CROSS-METATHESIS, REARRANGEMENT METATHESIS, THEORETICAL PERSPECTIVE, AROMATIC-COMPOUNDS, GRUBBS CATALYSTS, NHC LIGAND

Citation

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MLA
Broggi, Julie, et al. “The Influence of Phosphane Ligands on the Versatility of Ruthenium-Indenylidene Complexes in Metathesis.” CHEMISTRY-A EUROPEAN JOURNAL, vol. 16, no. 30, 2010, pp. 9215–25.
APA
Broggi, J., Urbina Blanco, C. A., Clavier, H., Leitgeb, A., Slugovc, C., Slawin, A. M., & Nolan, S. (2010). The influence of phosphane ligands on the versatility of ruthenium-indenylidene complexes in metathesis. CHEMISTRY-A EUROPEAN JOURNAL, 16(30), 9215–9225.
Chicago author-date
Broggi, Julie, César Alejandro Urbina Blanco, Herve Clavier, Anita Leitgeb, Christian Slugovc, Alexandra MZ Slawin, and Steven Nolan. 2010. “The Influence of Phosphane Ligands on the Versatility of Ruthenium-Indenylidene Complexes in Metathesis.” CHEMISTRY-A EUROPEAN JOURNAL 16 (30): 9215–25.
Chicago author-date (all authors)
Broggi, Julie, César Alejandro Urbina Blanco, Herve Clavier, Anita Leitgeb, Christian Slugovc, Alexandra MZ Slawin, and Steven Nolan. 2010. “The Influence of Phosphane Ligands on the Versatility of Ruthenium-Indenylidene Complexes in Metathesis.” CHEMISTRY-A EUROPEAN JOURNAL 16 (30): 9215–9225.
Vancouver
1.
Broggi J, Urbina Blanco CA, Clavier H, Leitgeb A, Slugovc C, Slawin AM, et al. The influence of phosphane ligands on the versatility of ruthenium-indenylidene complexes in metathesis. CHEMISTRY-A EUROPEAN JOURNAL. 2010;16(30):9215–25.
IEEE
[1]
J. Broggi et al., “The influence of phosphane ligands on the versatility of ruthenium-indenylidene complexes in metathesis,” CHEMISTRY-A EUROPEAN JOURNAL, vol. 16, no. 30, pp. 9215–9225, 2010.
@article{8166541,
  abstract     = {The aim of the present study is to develop readily available and stable pre-catalysts that could be easily prepared on large scale from simple starting materials. Based on the hypothesis that substitution of classical PCy3 with phosphanes of varying electron-donating properties could be a straightforward manner to improve catalytic activity, a methodical study dealing with the effect of phosphane fine-tuning in ruthenium-indenylidene catalysts was performed. Challenged to establish how the electronic properties of para-substituted phosphane ligands translate into catalyst activity, the versatile behaviour of these new ruthenium-indenylidene complexes was investigated for a number of metathesis reactions.},
  author       = {Broggi, Julie and Urbina Blanco, César Alejandro and Clavier, Herve and Leitgeb, Anita and Slugovc, Christian and Slawin, Alexandra MZ and Nolan, Steven},
  issn         = {0947-6539},
  journal      = {CHEMISTRY-A EUROPEAN JOURNAL},
  keywords     = {N-HETEROCYCLIC CARBENE,phosphane ligand rutheniuindenylidene metathesis catalyst,RING-CLOSING METATHESIS,OLEFIN METATHESIS,CATALYSTS BEARING,CROSS-METATHESIS,REARRANGEMENT METATHESIS,THEORETICAL PERSPECTIVE,AROMATIC-COMPOUNDS,GRUBBS CATALYSTS,NHC LIGAND},
  language     = {eng},
  number       = {30},
  pages        = {9215--9225},
  title        = {The influence of phosphane ligands on the versatility of ruthenium-indenylidene complexes in metathesis},
  url          = {http://dx.doi.org/10.1002/chem.201000659},
  volume       = {16},
  year         = {2010},
}

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