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Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene

Author
Organization
Abstract
The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored.
Keywords
ADDUCTS, PHOSPHINE, TRANSFORMATIONS, NHC, MECHANISM, LIGANDS, BURIED VOLUME, RUTHENIUM-INDENYLIDENE COMPLEXES, ORGANOMETALLIC CHEMISTRY, CHEMICAL-SHIFTS, ring closing metathesis ruthenium heterocyclic carbene catalyst

Citation

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MLA
Manzini, Simone et al. “Evaluation of an Olefin Metathesis Pre-catalyst with a Bulky and Electron-rich N-heterocyclic Carbene.” JOURNAL OF ORGANOMETALLIC CHEMISTRY 780 (2015): 43–48. Print.
APA
Manzini, S., Urbina Blanco, C. A., Nelson, D. J., Poater, A., Lebl, T., Meiries, S., Slawin, A. M., et al. (2015). Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 780, 43–48.
Chicago author-date
Manzini, Simone, César Alejandro Urbina Blanco, David J Nelson, Albert Poater, Tomas Lebl, Sebastien Meiries, Alexandra MZ Slawin, Laura Falivene, Luigi Cavallo, and Steven Nolan. 2015. “Evaluation of an Olefin Metathesis Pre-catalyst with a Bulky and Electron-rich N-heterocyclic Carbene.” Journal of Organometallic Chemistry 780: 43–48.
Chicago author-date (all authors)
Manzini, Simone, César Alejandro Urbina Blanco, David J Nelson, Albert Poater, Tomas Lebl, Sebastien Meiries, Alexandra MZ Slawin, Laura Falivene, Luigi Cavallo, and Steven Nolan. 2015. “Evaluation of an Olefin Metathesis Pre-catalyst with a Bulky and Electron-rich N-heterocyclic Carbene.” Journal of Organometallic Chemistry 780: 43–48.
Vancouver
1.
Manzini S, Urbina Blanco CA, Nelson DJ, Poater A, Lebl T, Meiries S, et al. Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 2015;780:43–8.
IEEE
[1]
S. Manzini et al., “Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene,” JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 780, pp. 43–48, 2015.
@article{8166392,
  abstract     = {The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored.},
  author       = {Manzini, Simone and Urbina Blanco, César Alejandro and Nelson, David J and Poater, Albert and Lebl, Tomas and Meiries, Sebastien and Slawin, Alexandra MZ and Falivene, Laura and Cavallo, Luigi and Nolan, Steven},
  issn         = {0022-328X},
  journal      = {JOURNAL OF ORGANOMETALLIC CHEMISTRY},
  keywords     = {ADDUCTS,PHOSPHINE,TRANSFORMATIONS,NHC,MECHANISM,LIGANDS,BURIED VOLUME,RUTHENIUM-INDENYLIDENE COMPLEXES,ORGANOMETALLIC CHEMISTRY,CHEMICAL-SHIFTS,ring closing metathesis ruthenium heterocyclic carbene catalyst},
  language     = {eng},
  pages        = {43--48},
  title        = {Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene},
  url          = {http://dx.doi.org/10.1016/j.jorganchem.2014.12.040},
  volume       = {780},
  year         = {2015},
}

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