Advanced search
1 file | 538.32 KB Add to list

Dynamic capillary diffusion system for monoterpene and sesquiterpene calibration : quantitative measurement and determination of physical properties

Author
Organization
Abstract
This article describes a method for preparation of low concentration gas standard mixtures of biogenic volatile organic compounds (BVOCs) emitted primarily by plants. A set of 10 plant volatiles including -pinene, -pinene, 3-carene, linalool, methyl salicylate, -cedrene, -caryophyllene, -farnesene, aromadendrene and -humulene was used in the study. Gas standard mixture of these compounds was generated using a capillary diffusion system (CDS). Diffusion coefficient (D) and saturation vapour pressure (p(s)) data of these compounds were calculated from experimentally determined gas chromatographic retention indices (RI) and empirical relationships between D and p(s) versus RI. A comparison of the calculated and measured concentrations of investigated compounds has proved that designed CDS can be successfully used for the proper quantification of BVOCs.
Keywords
biogenic volatile organic compounds, capillary diffusion system, gas chromatographic retention index, diffusion coefficient, saturation vapour pressure, SOLID-PHASE MICROEXTRACTION, VOLATILE ORGANIC-COMPOUNDS, VAPOR-PRESSURES, BIOGENIC HYDROCARBONS, AIR, EMISSIONS, OXIDATION, MODEL

Downloads

  • (...).pdf
    • full text
    • |
    • UGent only
    • |
    • PDF
    • |
    • 538.32 KB

Citation

Please use this url to cite or link to this publication:

MLA
Kosina, Jiri, Jo Dewulf, Ivan Viden, et al. “Dynamic Capillary Diffusion System for Monoterpene and Sesquiterpene Calibration : Quantitative Measurement and Determination of Physical Properties.” INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY 93.6 (2013): 637–649. Print.
APA
Kosina, J., Dewulf, J., Viden, I., Pokorska, O., & Van Langenhove, H. (2013). Dynamic capillary diffusion system for monoterpene and sesquiterpene calibration : quantitative measurement and determination of physical properties. INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 93(6), 637–649.
Chicago author-date
Kosina, Jiri, Jo Dewulf, Ivan Viden, Olga Pokorska, and Herman Van Langenhove. 2013. “Dynamic Capillary Diffusion System for Monoterpene and Sesquiterpene Calibration : Quantitative Measurement and Determination of Physical Properties.” International Journal of Environmental Analytical Chemistry 93 (6): 637–649.
Chicago author-date (all authors)
Kosina, Jiri, Jo Dewulf, Ivan Viden, Olga Pokorska, and Herman Van Langenhove. 2013. “Dynamic Capillary Diffusion System for Monoterpene and Sesquiterpene Calibration : Quantitative Measurement and Determination of Physical Properties.” International Journal of Environmental Analytical Chemistry 93 (6): 637–649.
Vancouver
1.
Kosina J, Dewulf J, Viden I, Pokorska O, Van Langenhove H. Dynamic capillary diffusion system for monoterpene and sesquiterpene calibration : quantitative measurement and determination of physical properties. INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY. 2013;93(6):637–49.
IEEE
[1]
J. Kosina, J. Dewulf, I. Viden, O. Pokorska, and H. Van Langenhove, “Dynamic capillary diffusion system for monoterpene and sesquiterpene calibration : quantitative measurement and determination of physical properties,” INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, vol. 93, no. 6, pp. 637–649, 2013.
@article{8162153,
  abstract     = {This article describes a method for preparation of low concentration gas standard mixtures of biogenic volatile organic compounds (BVOCs) emitted primarily by plants. A set of 10 plant volatiles including -pinene, -pinene, 3-carene, linalool, methyl salicylate, -cedrene, -caryophyllene, -farnesene, aromadendrene and -humulene was used in the study. Gas standard mixture of these compounds was generated using a capillary diffusion system (CDS). Diffusion coefficient (D) and saturation vapour pressure (p(s)) data of these compounds were calculated from experimentally determined gas chromatographic retention indices (RI) and empirical relationships between D and p(s) versus RI. A comparison of the calculated and measured concentrations of investigated compounds has proved that designed CDS can be successfully used for the proper quantification of BVOCs.},
  author       = {Kosina, Jiri and Dewulf, Jo and Viden, Ivan and Pokorska, Olga and Van Langenhove, Herman},
  issn         = {0306-7319},
  journal      = {INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY},
  keywords     = {biogenic volatile organic compounds,capillary diffusion system,gas chromatographic retention index,diffusion coefficient,saturation vapour pressure,SOLID-PHASE MICROEXTRACTION,VOLATILE ORGANIC-COMPOUNDS,VAPOR-PRESSURES,BIOGENIC HYDROCARBONS,AIR,EMISSIONS,OXIDATION,MODEL},
  language     = {eng},
  number       = {6},
  pages        = {637--649},
  title        = {Dynamic capillary diffusion system for monoterpene and sesquiterpene calibration : quantitative measurement and determination of physical properties},
  url          = {http://dx.doi.org/10.1080/03067319.2012.656621},
  volume       = {93},
  year         = {2013},
}

Altmetric
View in Altmetric
Web of Science
Times cited: