Macromolecular coupling in seconds of triazolinedione end-functionalized polymers prepared by RAFT polymerization
- Author
- Stef Vandewalle, Stijn Billiet (UGent) , Frank Driessen (UGent) and Filip Du Prez (UGent)
- Organization
- Abstract
- The ultrafast and additive-free triazolinedione-click reaction with electron rich (di)enes is a powerful method for the ultrafast ligation of polymer segments. A versatile method is described for the introduction of dickable TAD end groups in various polymer segments, using reversible addition-fragmentation chain transfer polymerization. These triazolinedione-functionalized prepolymers were subsequently used for macromolecular functionalization with a low molecular weight diene and block copolymer synthesis of different types within seconds, at ambient conditions, through the coupling with diene-functionalized polymers such as poly(ethylene glycol) and poly(isobornyl acrylate).
- Keywords
- CLICK-CHEMISTRY, BLOCK-COPOLYMERS, FRAGMENTATION CHAIN TRANSFER, ELECTROPHILIC AROMATIC-SUBSTITUTION, HYPERBRANCHED POLYMERS, THIOLACTONE CHEMISTRY, TERMINAL ALKYNES, SCIENCE, TOOL, METHACRYLATE)
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-8067803
- MLA
- Vandewalle, Stef, et al. “Macromolecular Coupling in Seconds of Triazolinedione End-Functionalized Polymers Prepared by RAFT Polymerization.” ACS MACRO LETTERS, vol. 5, no. 6, 2016, pp. 766–71, doi:10.1021/acsmacrolett.6b00342.
- APA
- Vandewalle, S., Billiet, S., Driessen, F., & Du Prez, F. (2016). Macromolecular coupling in seconds of triazolinedione end-functionalized polymers prepared by RAFT polymerization. ACS MACRO LETTERS, 5(6), 766–771. https://doi.org/10.1021/acsmacrolett.6b00342
- Chicago author-date
- Vandewalle, Stef, Stijn Billiet, Frank Driessen, and Filip Du Prez. 2016. “Macromolecular Coupling in Seconds of Triazolinedione End-Functionalized Polymers Prepared by RAFT Polymerization.” ACS MACRO LETTERS 5 (6): 766–71. https://doi.org/10.1021/acsmacrolett.6b00342.
- Chicago author-date (all authors)
- Vandewalle, Stef, Stijn Billiet, Frank Driessen, and Filip Du Prez. 2016. “Macromolecular Coupling in Seconds of Triazolinedione End-Functionalized Polymers Prepared by RAFT Polymerization.” ACS MACRO LETTERS 5 (6): 766–771. doi:10.1021/acsmacrolett.6b00342.
- Vancouver
- 1.Vandewalle S, Billiet S, Driessen F, Du Prez F. Macromolecular coupling in seconds of triazolinedione end-functionalized polymers prepared by RAFT polymerization. ACS MACRO LETTERS. 2016;5(6):766–71.
- IEEE
- [1]S. Vandewalle, S. Billiet, F. Driessen, and F. Du Prez, “Macromolecular coupling in seconds of triazolinedione end-functionalized polymers prepared by RAFT polymerization,” ACS MACRO LETTERS, vol. 5, no. 6, pp. 766–771, 2016.
@article{8067803, abstract = {{The ultrafast and additive-free triazolinedione-click reaction with electron rich (di)enes is a powerful method for the ultrafast ligation of polymer segments. A versatile method is described for the introduction of dickable TAD end groups in various polymer segments, using reversible addition-fragmentation chain transfer polymerization. These triazolinedione-functionalized prepolymers were subsequently used for macromolecular functionalization with a low molecular weight diene and block copolymer synthesis of different types within seconds, at ambient conditions, through the coupling with diene-functionalized polymers such as poly(ethylene glycol) and poly(isobornyl acrylate).}}, author = {{Vandewalle, Stef and Billiet, Stijn and Driessen, Frank and Du Prez, Filip}}, issn = {{2161-1653}}, journal = {{ACS MACRO LETTERS}}, keywords = {{CLICK-CHEMISTRY,BLOCK-COPOLYMERS,FRAGMENTATION CHAIN TRANSFER,ELECTROPHILIC AROMATIC-SUBSTITUTION,HYPERBRANCHED POLYMERS,THIOLACTONE CHEMISTRY,TERMINAL ALKYNES,SCIENCE,TOOL,METHACRYLATE)}}, language = {{eng}}, number = {{6}}, pages = {{766--771}}, title = {{Macromolecular coupling in seconds of triazolinedione end-functionalized polymers prepared by RAFT polymerization}}, url = {{http://doi.org/10.1021/acsmacrolett.6b00342}}, volume = {{5}}, year = {{2016}}, }
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