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Chiral imidate-ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

Katrien Bert (UGent) , Timothy Noël (UGent) , Wim Kimpe (UGent) , Jan Goeman (UGent) and Johan Van der Eycken (UGent)
(2012) ORGANIC & BIOMOLECULAR CHEMISTRY. 10(42). p.8539-8550
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Organization
Abstract
A small library of chiral imidate-ferrocenylphosphane ligands was efficiently synthesized (8 examples) and evaluated in the iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. These catalysts perform very well in a range of examples (yields and ee's up to 100%).
Keywords
CATALYZED ENANTIOSELECTIVE HYDROGENATION, ASYMMETRIC HYDROGENATION, TRISUBSTITUTED OLEFINS, EFFICIENT LIGANDS, IRIDIUM CATALYSTS, ALKENES, SUBSTITUENTS, COMPLEXES, SCALE

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MLA
Bert, Katrien et al. “Chiral Imidate-ferrocenylphosphanes: Synthesis and Application as P,N-ligands in iridium(I)-catalyzed Hydrogenation of Unfunctionalized and Poorly Functionalized Olefins.” ORGANIC & BIOMOLECULAR CHEMISTRY 10.42 (2012): 8539–8550. Print.
APA
Bert, K., Noël, T., Kimpe, W., Goeman, J., & Van der Eycken, J. (2012). Chiral imidate-ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. ORGANIC & BIOMOLECULAR CHEMISTRY, 10(42), 8539–8550.
Chicago author-date
Bert, Katrien, Timothy Noël, Wim Kimpe, Jan Goeman, and Johan Van der Eycken. 2012. “Chiral Imidate-ferrocenylphosphanes: Synthesis and Application as P,N-ligands in iridium(I)-catalyzed Hydrogenation of Unfunctionalized and Poorly Functionalized Olefins.” Organic & Biomolecular Chemistry 10 (42): 8539–8550.
Chicago author-date (all authors)
Bert, Katrien, Timothy Noël, Wim Kimpe, Jan Goeman, and Johan Van der Eycken. 2012. “Chiral Imidate-ferrocenylphosphanes: Synthesis and Application as P,N-ligands in iridium(I)-catalyzed Hydrogenation of Unfunctionalized and Poorly Functionalized Olefins.” Organic & Biomolecular Chemistry 10 (42): 8539–8550.
Vancouver
1.
Bert K, Noël T, Kimpe W, Goeman J, Van der Eycken J. Chiral imidate-ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. ORGANIC & BIOMOLECULAR CHEMISTRY. 2012;10(42):8539–50.
IEEE
[1]
K. Bert, T. Noël, W. Kimpe, J. Goeman, and J. Van der Eycken, “Chiral imidate-ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins,” ORGANIC & BIOMOLECULAR CHEMISTRY, vol. 10, no. 42, pp. 8539–8550, 2012.
@article{8067706,
  abstract     = {A small library of chiral imidate-ferrocenylphosphane ligands was efficiently synthesized (8 examples) and evaluated in the iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. These catalysts perform very well in a range of examples (yields and ee's up to 100%).},
  author       = {Bert, Katrien and Noël, Timothy and Kimpe, Wim and Goeman, Jan and Van der Eycken, Johan},
  issn         = {1477-0520},
  journal      = {ORGANIC & BIOMOLECULAR CHEMISTRY},
  keywords     = {CATALYZED ENANTIOSELECTIVE HYDROGENATION,ASYMMETRIC HYDROGENATION,TRISUBSTITUTED OLEFINS,EFFICIENT LIGANDS,IRIDIUM CATALYSTS,ALKENES,SUBSTITUENTS,COMPLEXES,SCALE},
  language     = {eng},
  number       = {42},
  pages        = {8539--8550},
  title        = {Chiral imidate-ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins},
  url          = {http://dx.doi.org/10.1039/c2ob25871d},
  volume       = {10},
  year         = {2012},
}

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