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Chain transfer in degenerative RAFT polymerization revisited: a comparative study of literature models

Pieter Derboven, Paul Van Steenberge UGent, Marie-Françoise Reyniers UGent, C Barner-Kowollik, Dagmar D'hooge UGent and Guy Marin UGent (2016) MACROMOLECULAR THEORY AND SIMULATIONS. 25(2). p.104-115
abstract
Under the validity of the degenerative transfer mechanism, the activation/deactivation process in reversible addition-fragmentation chain transfer (RAFT) polymerization can be formally quantified by transfer coefficients, depending on the chemical structure of the participating radicals and dormant species. In the present work, the different literature methods to experimentally determine these RAFT transfer coefficients are reviewed and theoretically re-evaluated. The accuracy of each method is mapped for a broad range of reaction conditions and RAFT transfer reactivities. General guidelines on when which method should be applied are formulated.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
PERMEATION CHROMATOGRAPHIC DETERMINATION, FREE-RADICAL POLYMERIZATION, EXHIBITING SLOW EQUILIBRIA, ACTIVATION RATE CONSTANTS, DIRECT ACTIVITY EXCHANGE, METHYL-METHACRYLATE, TERMINATION RATE COEFFICIENTS, LIVING POLYMERIZATION, KINETIC-ANALYSIS, AB-INITIO, kinetics (polym, ), modeling, radical polymerization, reversible addition fragmentation chain transfer (RAFT)
journal title
MACROMOLECULAR THEORY AND SIMULATIONS
volume
25
issue
2
pages
104 - 115
Web of Science type
Article
Web of Science id
000373103600002
JCR category
POLYMER SCIENCE
JCR impact factor
1.724 (2016)
JCR rank
37/86 (2016)
JCR quartile
2 (2016)
ISSN
1022-1344
DOI
10.1002/mats.201500076
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
8054297
handle
http://hdl.handle.net/1854/LU-8054297
date created
2016-08-24 15:24:49
date last changed
2017-03-09 12:54:26
@article{8054297,
  abstract     = {Under the validity of the degenerative transfer mechanism, the activation/deactivation process in reversible addition-fragmentation chain transfer (RAFT) polymerization can be formally quantified by transfer coefficients, depending on the chemical structure of the participating radicals and dormant species. In the present work, the different literature methods to experimentally determine these RAFT transfer coefficients are reviewed and theoretically re-evaluated. The accuracy of each method is mapped for a broad range of reaction conditions and RAFT transfer reactivities. General guidelines on when which method should be applied are formulated.},
  author       = {Derboven, Pieter and Van Steenberge, Paul and Reyniers, Marie-Fran\c{c}oise and Barner-Kowollik, C and D'hooge, Dagmar and Marin, Guy},
  issn         = {1022-1344},
  journal      = {MACROMOLECULAR THEORY AND SIMULATIONS},
  keyword      = {PERMEATION CHROMATOGRAPHIC DETERMINATION,FREE-RADICAL POLYMERIZATION,EXHIBITING SLOW EQUILIBRIA,ACTIVATION RATE CONSTANTS,DIRECT ACTIVITY EXCHANGE,METHYL-METHACRYLATE,TERMINATION RATE COEFFICIENTS,LIVING POLYMERIZATION,KINETIC-ANALYSIS,AB-INITIO,kinetics (polym,),modeling,radical polymerization,reversible addition fragmentation chain transfer (RAFT)},
  language     = {eng},
  number       = {2},
  pages        = {104--115},
  title        = {Chain transfer in degenerative RAFT polymerization revisited: a comparative study of literature models},
  url          = {http://dx.doi.org/10.1002/mats.201500076},
  volume       = {25},
  year         = {2016},
}

Chicago
Derboven, Pieter, Paul Van Steenberge, Marie-Françoise Reyniers, C Barner-Kowollik, Dagmar D’hooge, and Guy Marin. 2016. “Chain Transfer in Degenerative RAFT Polymerization Revisited: a Comparative Study of Literature Models.” Macromolecular Theory and Simulations 25 (2): 104–115.
APA
Derboven, P., Van Steenberge, P., Reyniers, M.-F., Barner-Kowollik, C., D’hooge, D., & Marin, G. (2016). Chain transfer in degenerative RAFT polymerization revisited: a comparative study of literature models. MACROMOLECULAR THEORY AND SIMULATIONS, 25(2), 104–115.
Vancouver
1.
Derboven P, Van Steenberge P, Reyniers M-F, Barner-Kowollik C, D’hooge D, Marin G. Chain transfer in degenerative RAFT polymerization revisited: a comparative study of literature models. MACROMOLECULAR THEORY AND SIMULATIONS. 2016;25(2):104–15.
MLA
Derboven, Pieter, Paul Van Steenberge, Marie-Françoise Reyniers, et al. “Chain Transfer in Degenerative RAFT Polymerization Revisited: a Comparative Study of Literature Models.” MACROMOLECULAR THEORY AND SIMULATIONS 25.2 (2016): 104–115. Print.