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Chain transfer in degenerative RAFT polymerization revisited: a comparative study of literature models

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Abstract
Under the validity of the degenerative transfer mechanism, the activation/deactivation process in reversible addition-fragmentation chain transfer (RAFT) polymerization can be formally quantified by transfer coefficients, depending on the chemical structure of the participating radicals and dormant species. In the present work, the different literature methods to experimentally determine these RAFT transfer coefficients are reviewed and theoretically re-evaluated. The accuracy of each method is mapped for a broad range of reaction conditions and RAFT transfer reactivities. General guidelines on when which method should be applied are formulated.
Keywords
PERMEATION CHROMATOGRAPHIC DETERMINATION, FREE-RADICAL POLYMERIZATION, EXHIBITING SLOW EQUILIBRIA, ACTIVATION RATE CONSTANTS, DIRECT ACTIVITY EXCHANGE, METHYL-METHACRYLATE, TERMINATION RATE COEFFICIENTS, LIVING POLYMERIZATION, KINETIC-ANALYSIS, AB-INITIO, kinetics (polym, ), modeling, radical polymerization, reversible addition fragmentation chain transfer (RAFT)

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Chicago
Derboven, Pieter, Paul Van Steenberge, Marie-Françoise Reyniers, C Barner-Kowollik, Dagmar D’hooge, and Guy Marin. 2016. “Chain Transfer in Degenerative RAFT Polymerization Revisited: a Comparative Study of Literature Models.” Macromolecular Theory and Simulations 25 (2): 104–115.
APA
Derboven, P., Van Steenberge, P., Reyniers, M.-F., Barner-Kowollik, C., D’hooge, D., & Marin, G. (2016). Chain transfer in degenerative RAFT polymerization revisited: a comparative study of literature models. MACROMOLECULAR THEORY AND SIMULATIONS, 25(2), 104–115.
Vancouver
1.
Derboven P, Van Steenberge P, Reyniers M-F, Barner-Kowollik C, D’hooge D, Marin G. Chain transfer in degenerative RAFT polymerization revisited: a comparative study of literature models. MACROMOLECULAR THEORY AND SIMULATIONS. 2016;25(2):104–15.
MLA
Derboven, Pieter, Paul Van Steenberge, Marie-Françoise Reyniers, et al. “Chain Transfer in Degenerative RAFT Polymerization Revisited: a Comparative Study of Literature Models.” MACROMOLECULAR THEORY AND SIMULATIONS 25.2 (2016): 104–115. Print.
@article{8054297,
  abstract     = {Under the validity of the degenerative transfer mechanism, the activation/deactivation process in reversible addition-fragmentation chain transfer (RAFT) polymerization can be formally quantified by transfer coefficients, depending on the chemical structure of the participating radicals and dormant species. In the present work, the different literature methods to experimentally determine these RAFT transfer coefficients are reviewed and theoretically re-evaluated. The accuracy of each method is mapped for a broad range of reaction conditions and RAFT transfer reactivities. General guidelines on when which method should be applied are formulated.},
  author       = {Derboven, Pieter and Van Steenberge, Paul and Reyniers, Marie-Fran\c{c}oise and Barner-Kowollik, C and D'hooge, Dagmar and Marin, Guy},
  issn         = {1022-1344},
  journal      = {MACROMOLECULAR THEORY AND SIMULATIONS},
  keyword      = {PERMEATION CHROMATOGRAPHIC DETERMINATION,FREE-RADICAL POLYMERIZATION,EXHIBITING SLOW EQUILIBRIA,ACTIVATION RATE CONSTANTS,DIRECT ACTIVITY EXCHANGE,METHYL-METHACRYLATE,TERMINATION RATE COEFFICIENTS,LIVING POLYMERIZATION,KINETIC-ANALYSIS,AB-INITIO,kinetics (polym,),modeling,radical polymerization,reversible addition fragmentation chain transfer (RAFT)},
  language     = {eng},
  number       = {2},
  pages        = {104--115},
  title        = {Chain transfer in degenerative RAFT polymerization revisited: a comparative study of literature models},
  url          = {http://dx.doi.org/10.1002/mats.201500076},
  volume       = {25},
  year         = {2016},
}

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