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Importance of radical transfer in precipitation polymerization: the case of vinyl chloride suspension polymerization

Joris Wieme UGent, Dagmar D'hooge UGent, Marie-Françoise Reyniers UGent and Guy Marin UGent (2009) MACROMOLECULAR REACTION ENGINEERING. 3(1). p.16-35
abstract
The importance of radical transfer between the reactive phases in precipitation polymerization processes is investigated with the vinyl chloride suspension polymerization as an example. A two-film model that accounts for a mass transfer resistance in both the monomer-rich and the polymer-rich phase is constructed and applied. Equilibrium is assumed at the interphase boundary. Based on model calculations using intrinsic rate coefficients obtained by regression to experimental data the effect of accounting for radical transfer between the reactive phases on the simulated monomer conversion and total moments of the molar mass distribution is demonstrated. It is found that the effect of radical transfer between the reactive phases is most pronounced at low polymerization temperatures.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
modeling, kinetics, poly(vinyl chloride) (PVC), precipitation polymerization, simulations, SUPERCRITICAL CARBON-DIOXIDE, BULK-POLYMERIZATION, HIGH-CONVERSION, DISPERSION POLYMERIZATION, INITIATOR EFFICIENCIES, CHAIN TRANSFER, KINETIC-MODEL, POLYVINYL-CHLORIDE), TERMINATION, SYSTEMS
journal title
MACROMOLECULAR REACTION ENGINEERING
Macromol. React. Eng.
volume
3
issue
1
pages
16 - 35
Web of Science type
Article
Web of Science id
000263622300003
JCR category
ENGINEERING, CHEMICAL
JCR impact factor
1.488 (2009)
JCR rank
42/123 (2009)
JCR quartile
2 (2009)
ISSN
1862-832X
DOI
10.1002/mren.200800028
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
786089
handle
http://hdl.handle.net/1854/LU-786089
date created
2009-11-20 14:18:00
date last changed
2009-12-15 16:36:51
@article{786089,
  abstract     = {The importance of radical transfer between the reactive phases in precipitation polymerization processes is investigated with the vinyl chloride suspension polymerization as an example. A two-film model that accounts for a mass transfer resistance in both the monomer-rich and the polymer-rich phase is constructed and applied. Equilibrium is assumed at the interphase boundary. Based on model calculations using intrinsic rate coefficients obtained by regression to experimental data the effect of accounting for radical transfer between the reactive phases on the simulated monomer conversion and total moments of the molar mass distribution is demonstrated. It is found that the effect of radical transfer between the reactive phases is most pronounced at low polymerization temperatures.},
  author       = {Wieme, Joris and D'hooge, Dagmar and Reyniers, Marie-Fran\c{c}oise and Marin, Guy},
  issn         = {1862-832X},
  journal      = {MACROMOLECULAR REACTION ENGINEERING},
  keyword      = {modeling,kinetics,poly(vinyl chloride) (PVC),precipitation polymerization,simulations,SUPERCRITICAL CARBON-DIOXIDE,BULK-POLYMERIZATION,HIGH-CONVERSION,DISPERSION POLYMERIZATION,INITIATOR EFFICIENCIES,CHAIN TRANSFER,KINETIC-MODEL,POLYVINYL-CHLORIDE),TERMINATION,SYSTEMS},
  language     = {eng},
  number       = {1},
  pages        = {16--35},
  title        = {Importance of radical transfer in precipitation polymerization: the case of vinyl chloride suspension polymerization},
  url          = {http://dx.doi.org/10.1002/mren.200800028},
  volume       = {3},
  year         = {2009},
}

Chicago
Wieme, Joris, Dagmar D’hooge, Marie-Françoise Reyniers, and Guy Marin. 2009. “Importance of Radical Transfer in Precipitation Polymerization: The Case of Vinyl Chloride Suspension Polymerization.” Macromolecular Reaction Engineering 3 (1): 16–35.
APA
Wieme, Joris, D’hooge, D., Reyniers, M.-F., & Marin, G. (2009). Importance of radical transfer in precipitation polymerization: the case of vinyl chloride suspension polymerization. MACROMOLECULAR REACTION ENGINEERING, 3(1), 16–35.
Vancouver
1.
Wieme J, D’hooge D, Reyniers M-F, Marin G. Importance of radical transfer in precipitation polymerization: the case of vinyl chloride suspension polymerization. MACROMOLECULAR REACTION ENGINEERING. 2009;3(1):16–35.
MLA
Wieme, Joris, Dagmar D’hooge, Marie-Françoise Reyniers, et al. “Importance of Radical Transfer in Precipitation Polymerization: The Case of Vinyl Chloride Suspension Polymerization.” MACROMOLECULAR REACTION ENGINEERING 3.1 (2009): 16–35. Print.