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A breathing zirconium metal-organic framework with reversible loss of crystallinity by correlated nanodomain formation

(2016) CHEMISTRY-A EUROPEAN JOURNAL. 22(10). p.3264-3267
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Abstract
The isoreticular analogue of the metal-organic framework UiO-66(Zr), synthesized with the flexible trans-1,4-cyclohexanedicarboxylic acid as linker, shows a peculiar breathing behavior by reversibly losing long-range crystalline order upon evacuation. The underlying flexibility is attributed to a concerted conformational contraction of up to two thirds of the linkers, which breaks the local lattice symmetry. X-ray scattering data are described well by a nanodomain model in which differently oriented tetragonal-type distortions propagate over about 7-10 unit cells.
Keywords
STABILITY, CLUSTERS, MOFS, dynamic porosity, metal-organic frameworks, phase transitions, structure elucidation, zirconium

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Citation

Please use this url to cite or link to this publication:

Chicago
Bueken, Bart, Frederik Vermoortele, Matthew J Cliffe, Michael T Wharmby, Damien Foucher, Jelle Wieme, Louis Vanduyfhuys, et al. 2016. “A Breathing Zirconium Metal-organic Framework with Reversible Loss of Crystallinity by Correlated Nanodomain Formation.” Chemistry-a European Journal 22 (10): 3264–3267.
APA
Bueken, Bart, Vermoortele, F., Cliffe, M. J., Wharmby, M. T., Foucher, D., Wieme, J., Vanduyfhuys, L., et al. (2016). A breathing zirconium metal-organic framework with reversible loss of crystallinity by correlated nanodomain formation. CHEMISTRY-A EUROPEAN JOURNAL, 22(10), 3264–3267.
Vancouver
1.
Bueken B, Vermoortele F, Cliffe MJ, Wharmby MT, Foucher D, Wieme J, et al. A breathing zirconium metal-organic framework with reversible loss of crystallinity by correlated nanodomain formation. CHEMISTRY-A EUROPEAN JOURNAL. 2016;22(10):3264–7.
MLA
Bueken, Bart, Frederik Vermoortele, Matthew J Cliffe, et al. “A Breathing Zirconium Metal-organic Framework with Reversible Loss of Crystallinity by Correlated Nanodomain Formation.” CHEMISTRY-A EUROPEAN JOURNAL 22.10 (2016): 3264–3267. Print.
@article{7167933,
  abstract     = {The isoreticular analogue of the metal-organic framework UiO-66(Zr), synthesized with the flexible trans-1,4-cyclohexanedicarboxylic acid as linker, shows a peculiar breathing behavior by reversibly losing long-range crystalline order upon evacuation. The underlying flexibility is attributed to a concerted conformational contraction of up to two thirds of the linkers, which breaks the local lattice symmetry. X-ray scattering data are described well by a nanodomain model in which differently oriented tetragonal-type distortions propagate over about 7-10 unit cells.},
  author       = {Bueken, Bart and Vermoortele, Frederik and Cliffe, Matthew J and Wharmby, Michael T and Foucher, Damien and Wieme, Jelle and Vanduyfhuys, Louis and Martineau, Charlotte  and Stock, Norbert and Taulelle, Francis and Van Speybroeck, Veronique and Goodwin, Andrew L and De Vos, Dirk},
  issn         = {0947-6539},
  journal      = {CHEMISTRY-A EUROPEAN JOURNAL},
  language     = {eng},
  number       = {10},
  pages        = {3264--3267},
  title        = {A breathing zirconium metal-organic framework with reversible loss of crystallinity by correlated nanodomain formation},
  url          = {http://dx.doi.org/10.1002/chem.201600330},
  volume       = {22},
  year         = {2016},
}

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