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A homochiral vanadium-salen based cadmium bpdc MOF with permanent porosity as an asymmetric catalyst in solvent-free cyanosilylation

(2016) CHEMICAL COMMUNICATIONS. 52(7). p.1401-1404
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UGent GOA grant number 01G00710.
Abstract
A homochiral vanadium-salen based MOF with the pcu topology is constructed via in situ synthesis under solvothermal conditions. The synthesized MOF exhibits BET surface areas of 574 m(2) g(-1), showing the highest H-2 adsorption capacity (1.05 wt% at 77 K, 1 bar) and the highest CO2 uptake (51 cm(3) g(-1) at 273 K, 1 bar) for currently known salen-based MOFs. This framework shows excellent performance as an asymmetric catalyst in solvent-free cyanosilylation.
Keywords
METAL-ORGANIC FRAMEWORKS, CARBON-DIOXIDE, SURFACE-AREA, EPOXIDATION, MICROPORES, COMPLEXES, HIGHLY SELECTIVE SEPARATION

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Citation

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MLA
Bhunia, Asamanjoy, et al. “A Homochiral Vanadium-Salen Based Cadmium Bpdc MOF with Permanent Porosity as an Asymmetric Catalyst in Solvent-Free Cyanosilylation.” CHEMICAL COMMUNICATIONS, vol. 52, no. 7, 2016, pp. 1401–04.
APA
Bhunia, A., Dey, S., Moreno, J. M., Diaz, U., Concepcion, P., Van Hecke, K., … Van Der Voort, P. (2016). A homochiral vanadium-salen based cadmium bpdc MOF with permanent porosity as an asymmetric catalyst in solvent-free cyanosilylation. CHEMICAL COMMUNICATIONS, 52(7), 1401–1404.
Chicago author-date
Bhunia, Asamanjoy, Subarna Dey, Jose Maria Moreno, Urbano Diaz, Patricia Concepcion, Kristof Van Hecke, Christoph Janiak, and Pascal Van Der Voort. 2016. “A Homochiral Vanadium-Salen Based Cadmium Bpdc MOF with Permanent Porosity as an Asymmetric Catalyst in Solvent-Free Cyanosilylation.” CHEMICAL COMMUNICATIONS 52 (7): 1401–4.
Chicago author-date (all authors)
Bhunia, Asamanjoy, Subarna Dey, Jose Maria Moreno, Urbano Diaz, Patricia Concepcion, Kristof Van Hecke, Christoph Janiak, and Pascal Van Der Voort. 2016. “A Homochiral Vanadium-Salen Based Cadmium Bpdc MOF with Permanent Porosity as an Asymmetric Catalyst in Solvent-Free Cyanosilylation.” CHEMICAL COMMUNICATIONS 52 (7): 1401–1404.
Vancouver
1.
Bhunia A, Dey S, Moreno JM, Diaz U, Concepcion P, Van Hecke K, et al. A homochiral vanadium-salen based cadmium bpdc MOF with permanent porosity as an asymmetric catalyst in solvent-free cyanosilylation. CHEMICAL COMMUNICATIONS. 2016;52(7):1401–4.
IEEE
[1]
A. Bhunia et al., “A homochiral vanadium-salen based cadmium bpdc MOF with permanent porosity as an asymmetric catalyst in solvent-free cyanosilylation,” CHEMICAL COMMUNICATIONS, vol. 52, no. 7, pp. 1401–1404, 2016.
@article{7082343,
  abstract     = {A homochiral vanadium-salen based MOF with the pcu topology is constructed via in situ synthesis under solvothermal conditions. The synthesized MOF exhibits BET surface areas of 574 m(2) g(-1), showing the highest H-2 adsorption capacity (1.05 wt% at 77 K, 1 bar) and the highest CO2 uptake (51 cm(3) g(-1) at 273 K, 1 bar) for currently known salen-based MOFs. This framework shows excellent performance as an asymmetric catalyst in solvent-free cyanosilylation.},
  author       = {Bhunia, Asamanjoy and Dey, Subarna and Moreno, Jose Maria and Diaz, Urbano and Concepcion, Patricia and Van Hecke, Kristof and Janiak, Christoph and Van Der Voort, Pascal},
  issn         = {1359-7345},
  journal      = {CHEMICAL COMMUNICATIONS},
  keywords     = {METAL-ORGANIC FRAMEWORKS,CARBON-DIOXIDE,SURFACE-AREA,EPOXIDATION,MICROPORES,COMPLEXES,HIGHLY SELECTIVE SEPARATION},
  language     = {eng},
  number       = {7},
  pages        = {1401--1404},
  title        = {A homochiral vanadium-salen based cadmium bpdc MOF with permanent porosity as an asymmetric catalyst in solvent-free cyanosilylation},
  url          = {http://dx.doi.org/10.1039/c5cc09459c},
  volume       = {52},
  year         = {2016},
}

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