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Homogeneous gold-catalyzed cyclization reactions of alkynes with N- and S-nucleophiles

Wouter Debrouwer (UGent) , Thomas Heugebaert (UGent) , Bart Roman (UGent) and Christian Stevens (UGent)
(2015) ADVANCED SYNTHESIS & CATALYSIS. 357(14-15). p.2975-3006
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Abstract
This review covers the formation of N- and S-containing heterocycles, initiated by gold-catalyzed nucleophilic attack of N- or S-nucleophiles onto alkynes. These types of nucleophiles have been somewhat overlooked as compared to their C- or O-counterparts in other reviews. In this particular work, their intramolecular gold-mediated attack onto alkynes is reviewed in depth. It is structured in such a fashion that the reader will get a clear view of which substrates react in which cyclization mode.
Keywords
hydroamination, homogeneous catalysis, MILD CONDITIONS, TRANSITION-METAL CATALYSTS, DIPYRROLOBENZOQUINONE (+)-TERREUSINONE, CYCLOISOMERIZATION REACTIONS, ENANTIOSELECTIVE SYNTHESIS, TERMINAL ALKYNES, CASCADE REACTION, gold catalysis, amines, HIGHLY SUBSTITUTED PYRROLES, sulfides, GOLD(I)-CATALYZED INTRAMOLECULAR HYDROAMINATION, 6-MEMBERED MESOIONIC CARBENE

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Chicago
Debrouwer, Wouter, Thomas Heugebaert, Bart Roman, and Christian Stevens. 2015. “Homogeneous Gold-catalyzed Cyclization Reactions of Alkynes with N- and S-nucleophiles.” Advanced Synthesis & Catalysis 357 (14-15): 2975–3006.
APA
Debrouwer, W., Heugebaert, T., Roman, B., & Stevens, C. (2015). Homogeneous gold-catalyzed cyclization reactions of alkynes with N- and S-nucleophiles. ADVANCED SYNTHESIS & CATALYSIS, 357(14-15), 2975–3006.
Vancouver
1.
Debrouwer W, Heugebaert T, Roman B, Stevens C. Homogeneous gold-catalyzed cyclization reactions of alkynes with N- and S-nucleophiles. ADVANCED SYNTHESIS & CATALYSIS. 2015;357(14-15):2975–3006.
MLA
Debrouwer, Wouter, Thomas Heugebaert, Bart Roman, et al. “Homogeneous Gold-catalyzed Cyclization Reactions of Alkynes with N- and S-nucleophiles.” ADVANCED SYNTHESIS & CATALYSIS 357.14-15 (2015): 2975–3006. Print.
@article{7070953,
  abstract     = {This review covers the formation of N- and S-containing heterocycles, initiated by gold-catalyzed nucleophilic attack of N- or S-nucleophiles onto alkynes. These types of nucleophiles have been somewhat overlooked as compared to their C- or O-counterparts in other reviews. In this particular work, their intramolecular gold-mediated attack onto alkynes is reviewed in depth. It is structured in such a fashion that the reader will get a clear view of which substrates react in which cyclization mode.},
  author       = {Debrouwer, Wouter and Heugebaert, Thomas and Roman, Bart and Stevens, Christian},
  issn         = {1615-4150},
  journal      = {ADVANCED SYNTHESIS \& CATALYSIS},
  language     = {eng},
  number       = {14-15},
  pages        = {2975--3006},
  title        = {Homogeneous gold-catalyzed cyclization reactions of alkynes with N- and S-nucleophiles},
  url          = {http://dx.doi.org/10.1002/adsc.201500520},
  volume       = {357},
  year         = {2015},
}

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