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High-throughput synthesis of thermoresponsive poly(oligoethylene glycol acrylate) copolymers by RAFT polymerization

Lenny Voorhaar (UGent) , Kristof Van Hecke (UGent) , Gertjan Vancoillie (UGent) , Qilu Zhang (UGent) and Richard Hoogenboom (UGent)
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Abstract
Thermoresponsive polymers are an interesting class of stimuli-responsive polymers because of their potential in vivo applications resulting from the easily controllabe trigger. In this work, two series of statistical copolymers of di(ethylene glycol) ethyl ether acrylate with di(ethylene glycol) methyl ether acrylate and tri(ethylene glycol) methyl ether acrylate, respectively, were synthesized using high-throughput automated parallel RAFT polymerization to accurately tune the polymer phase transition temperature. Cloud point temperature determination for each copolymer was performed by parallel turbidimetry and revealed a linear relationship with copolymer composition. The crystal structure of the used chain transfer agent 2-(((butylsulfanyl)carbonothioyl) sulfanyl)propanoic acid is also reported.
Keywords
SHAPE-MEMORY POLYMERS, INITIO EMULSION POLYMERIZATION, 2-HYDROXYETHYL ACRYLATE, RADICAL POLYMERIZATION, RESPONSIVE POLYMERS, CHAIN, ACID, LCST, POLY(2-OXAZOLINE)S, TEMPERATURE

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MLA
Voorhaar, Lenny, et al. “High-Throughput Synthesis of Thermoresponsive Poly(Oligoethylene Glycol Acrylate) Copolymers by RAFT Polymerization.” ACS Symposium Series, edited by K Matyjaszewski et al., vol. 1188, American Chemical Society (ACS), 2015, pp. 63–77.
APA
Voorhaar, L., Van Hecke, K., Vancoillie, G., Zhang, Q., & Hoogenboom, R. (2015). High-throughput synthesis of thermoresponsive poly(oligoethylene glycol acrylate) copolymers by RAFT polymerization. In K. Matyjaszewski, B. Sumerlin, N. Tsarevsky, & J. Chiefari (Eds.), ACS Symposium Series (Vol. 1188, pp. 63–77). Washington, DC, USA: American Chemical Society (ACS).
Chicago author-date
Voorhaar, Lenny, Kristof Van Hecke, Gertjan Vancoillie, Qilu Zhang, and Richard Hoogenboom. 2015. “High-Throughput Synthesis of Thermoresponsive Poly(Oligoethylene Glycol Acrylate) Copolymers by RAFT Polymerization.” In ACS Symposium Series, edited by K Matyjaszewski, BS Sumerlin, NV Tsarevsky, and J Chiefari, 1188:63–77. Washington, DC, USA: American Chemical Society (ACS).
Chicago author-date (all authors)
Voorhaar, Lenny, Kristof Van Hecke, Gertjan Vancoillie, Qilu Zhang, and Richard Hoogenboom. 2015. “High-Throughput Synthesis of Thermoresponsive Poly(Oligoethylene Glycol Acrylate) Copolymers by RAFT Polymerization.” In ACS Symposium Series, ed by. K Matyjaszewski, BS Sumerlin, NV Tsarevsky, and J Chiefari, 1188:63–77. Washington, DC, USA: American Chemical Society (ACS).
Vancouver
1.
Voorhaar L, Van Hecke K, Vancoillie G, Zhang Q, Hoogenboom R. High-throughput synthesis of thermoresponsive poly(oligoethylene glycol acrylate) copolymers by RAFT polymerization. In: Matyjaszewski K, Sumerlin B, Tsarevsky N, Chiefari J, editors. ACS Symposium Series. Washington, DC, USA: American Chemical Society (ACS); 2015. p. 63–77.
IEEE
[1]
L. Voorhaar, K. Van Hecke, G. Vancoillie, Q. Zhang, and R. Hoogenboom, “High-throughput synthesis of thermoresponsive poly(oligoethylene glycol acrylate) copolymers by RAFT polymerization,” in ACS Symposium Series, San Francisco, CA, USA, 2015, vol. 1188, pp. 63–77.
@inproceedings{7022717,
  abstract     = {Thermoresponsive polymers are an interesting class of stimuli-responsive polymers because of their potential in vivo applications resulting from the easily controllabe trigger. In this work, two series of statistical copolymers of di(ethylene glycol) ethyl ether acrylate with di(ethylene glycol) methyl ether acrylate and tri(ethylene glycol) methyl ether acrylate, respectively, were synthesized using high-throughput automated parallel RAFT polymerization to accurately tune the polymer phase transition temperature. Cloud point temperature determination for each copolymer was performed by parallel turbidimetry and revealed a linear relationship with copolymer composition. The crystal structure of the used chain transfer agent 2-(((butylsulfanyl)carbonothioyl) sulfanyl)propanoic acid is also reported.},
  author       = {Voorhaar, Lenny and Van Hecke, Kristof and Vancoillie, Gertjan and Zhang, Qilu and Hoogenboom, Richard},
  booktitle    = {ACS Symposium Series},
  editor       = {Matyjaszewski, K and Sumerlin, BS and Tsarevsky, NV and Chiefari, J},
  isbn         = {9780841230507},
  issn         = {0097-6156},
  keywords     = {SHAPE-MEMORY POLYMERS,INITIO EMULSION POLYMERIZATION,2-HYDROXYETHYL ACRYLATE,RADICAL POLYMERIZATION,RESPONSIVE POLYMERS,CHAIN,ACID,LCST,POLY(2-OXAZOLINE)S,TEMPERATURE},
  language     = {eng},
  location     = {San Francisco, CA, USA},
  pages        = {63--77},
  publisher    = {American Chemical Society (ACS)},
  title        = {High-throughput synthesis of thermoresponsive poly(oligoethylene glycol acrylate) copolymers by RAFT polymerization},
  url          = {http://dx.doi.org/10.1021/bk-2015-1188.ch005},
  volume       = {1188},
  year         = {2015},
}

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