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A comparative study of sulphite oxidation under alkaline conditions by use of wall-jet flow cell and rotating disc electrode

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Abstract
The oxidation of sulphite under alkaline conditions has been studied in a diffusion-controlled region in order to find the relationship between the limiting current and the concentration of sulphite in a solution. Cyclic voltammetric experiments with a rotating disc electrode were used to define the potential region where the oxidation current was diffusion controlled. Chronoamperometric experiments with a "wall-jet" flow cell gave a linear relationship between the limiting oxidation current and (C(SO32-))(3/2). This electrochemical method can therefore be used to monitor changes in the sulphite concentration in real time.
Keywords
Wall-jet flow cell, Analytic method, Alkaline, Sulphite

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Citation

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Chicago
Skavas, Erling, Mieke Adriaens, and Tor Hemmingsen. 2006. “A Comparative Study of Sulphite Oxidation Under Alkaline Conditions by Use of Wall-jet Flow Cell and Rotating Disc Electrode.” International Journal of Electrochemical Science 1 (8): 414–424.
APA
Skavas, E., Adriaens, M., & Hemmingsen, T. (2006). A comparative study of sulphite oxidation under alkaline conditions by use of wall-jet flow cell and rotating disc electrode. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 1(8), 414–424.
Vancouver
1.
Skavas E, Adriaens M, Hemmingsen T. A comparative study of sulphite oxidation under alkaline conditions by use of wall-jet flow cell and rotating disc electrode. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE. 2006;1(8):414–24.
MLA
Skavas, Erling, Mieke Adriaens, and Tor Hemmingsen. “A Comparative Study of Sulphite Oxidation Under Alkaline Conditions by Use of Wall-jet Flow Cell and Rotating Disc Electrode.” INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 1.8 (2006): 414–424. Print.
@article{696571,
  abstract     = {The oxidation of sulphite under alkaline conditions has been studied in a diffusion-controlled region in order to find the relationship between the limiting current and the concentration of sulphite in a solution. Cyclic voltammetric experiments with a rotating disc electrode were used to define the potential region where the oxidation current was diffusion controlled. Chronoamperometric experiments with a {\textacutedbl}wall-jet{\textacutedbl} flow cell gave a linear relationship between the limiting oxidation current and (C(SO32-))(3/2). This electrochemical method can therefore be used to monitor changes in the sulphite concentration in real time.},
  author       = {Skavas, Erling and Adriaens, Mieke and Hemmingsen, Tor},
  issn         = {1452-3981},
  journal      = {INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE},
  language     = {eng},
  number       = {8},
  pages        = {414--424},
  title        = {A comparative study of sulphite oxidation under alkaline conditions by use of wall-jet flow cell and rotating disc electrode},
  url          = {http://www.electrochemsci.org/papers/1080414.pdf},
  volume       = {1},
  year         = {2006},
}

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