In-situ spectroelectrochemical studies of the removal of chlorides from copper
- Author
- Mieke Adriaens (UGent) and Mark Dowsett
- Organization
- Abstract
- This paper describes corrosion potential measurements of corroded copper samples taken whilst acquiring timeresolved X-ray diffraction or X-ray absorption data in a synchrotron beam line. The surface structure of the samples and its evolution, whilst under simulated conservation treatment in sodium sesquicarbonate, were examined using X-ray diffraction. The fluid chemistry over the sample was monitored during identical experiments using X-ray absorption. All measurements were carried out with the sample immersed (i.e. without the need to expose the sample to air). Processes were followed from initial wetting of the surfaces through to the cessation of measurable change. A webcam was used to make a simultaneous visual record of the sample and its environment. The experiments aim at contributing to the improvement of conservation methods for cupreous artefacts recovered from marine environments.
- Keywords
- spectroelectrochemistry, X-ray absorption spectroscopy, conservation, marine, copper, corrosion, X-ray diffraction
Downloads
-
METAL07 vol3 Adriaens 10-14.pdf
- full text
- |
- open access
- |
- |
- 493.52 KB
Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-696445
- MLA
- Adriaens, Mieke, and Mark Dowsett. “In-Situ Spectroelectrochemical Studies of the Removal of Chlorides from Copper.” METAL 07, Vol. 3, Rijksmuseum Amsterdam, 2007, pp. 10–14.
- APA
- Adriaens, M., & Dowsett, M. (2007). In-situ spectroelectrochemical studies of the removal of chlorides from copper. METAL 07, Vol. 3, 10–14. Amsterdam: Rijksmuseum Amsterdam.
- Chicago author-date
- Adriaens, Mieke, and Mark Dowsett. 2007. “In-Situ Spectroelectrochemical Studies of the Removal of Chlorides from Copper.” In METAL 07, Vol. 3, 10–14. Amsterdam: Rijksmuseum Amsterdam.
- Chicago author-date (all authors)
- Adriaens, Mieke, and Mark Dowsett. 2007. “In-Situ Spectroelectrochemical Studies of the Removal of Chlorides from Copper.” In METAL 07, Vol. 3, 10–14. Amsterdam: Rijksmuseum Amsterdam.
- Vancouver
- 1.Adriaens M, Dowsett M. In-situ spectroelectrochemical studies of the removal of chlorides from copper. In: METAL 07, vol 3. Amsterdam: Rijksmuseum Amsterdam; 2007. p. 10–4.
- IEEE
- [1]M. Adriaens and M. Dowsett, “In-situ spectroelectrochemical studies of the removal of chlorides from copper,” in METAL 07, vol. 3, Amsterdam, 2007, pp. 10–14.
@inproceedings{696445, abstract = {{This paper describes corrosion potential measurements of corroded copper samples taken whilst acquiring timeresolved X-ray diffraction or X-ray absorption data in a synchrotron beam line. The surface structure of the samples and its evolution, whilst under simulated conservation treatment in sodium sesquicarbonate, were examined using X-ray diffraction. The fluid chemistry over the sample was monitored during identical experiments using X-ray absorption. All measurements were carried out with the sample immersed (i.e. without the need to expose the sample to air). Processes were followed from initial wetting of the surfaces through to the cessation of measurable change. A webcam was used to make a simultaneous visual record of the sample and its environment. The experiments aim at contributing to the improvement of conservation methods for cupreous artefacts recovered from marine environments.}}, author = {{Adriaens, Mieke and Dowsett, Mark}}, booktitle = {{METAL 07, vol. 3}}, keywords = {{spectroelectrochemistry,X-ray absorption spectroscopy,conservation,marine,copper,corrosion,X-ray diffraction}}, language = {{eng}}, location = {{Amsterdam}}, pages = {{10--14}}, publisher = {{Rijksmuseum Amsterdam}}, title = {{In-situ spectroelectrochemical studies of the removal of chlorides from copper}}, year = {{2007}}, }