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Continuous poly(2-oxazoline) triblock copolymer synthesis in a microfluidic reactor cascade

(2015) CHEMICAL COMMUNICATIONS. 51(58). p.11701-11704
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Abstract
Cationic ring-opening polymerizations of 2-oxazolines were investigated in continuous microflow reactors. Fast homopolymerizations of 2-ethyl-2-oxazoline (EtOx) and 2-n-propyl-2-oxazoline (nPropOx) were carried out up to 180 degrees C, yielding well-controlled polymers. Also well-defined diblock and triblock copolymers were produced in a microfluidic reactor cascade, demonstrating the high value of microflow synthesis for the built-up of advanced poly(2-oxazoline)-based polymers.
Keywords
MODE, MICROREACTOR, SCALE-UP, 2-ETHYL-2-OXAZOLINE, MICROWAVE-ASSISTED POLYMERIZATIONS, CYCLIC IMINO ETHERS, RING-OPENING POLYMERIZATION, BLOCK-COPOLYMERS, FUNCTIONALIZATION, TECHNOLOGY

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Citation

Please use this url to cite or link to this publication:

Chicago
Baeten, Evelien, Bart Verbraeken, Richard Hoogenboom, and Thomas Junkers. 2015. “Continuous Poly(2-oxazoline) Triblock Copolymer Synthesis in a Microfluidic Reactor Cascade.” Chemical Communications 51 (58): 11701–11704.
APA
Baeten, E., Verbraeken, B., Hoogenboom, R., & Junkers, T. (2015). Continuous poly(2-oxazoline) triblock copolymer synthesis in a microfluidic reactor cascade. CHEMICAL COMMUNICATIONS, 51(58), 11701–11704.
Vancouver
1.
Baeten E, Verbraeken B, Hoogenboom R, Junkers T. Continuous poly(2-oxazoline) triblock copolymer synthesis in a microfluidic reactor cascade. CHEMICAL COMMUNICATIONS. 2015;51(58):11701–4.
MLA
Baeten, Evelien, Bart Verbraeken, Richard Hoogenboom, et al. “Continuous Poly(2-oxazoline) Triblock Copolymer Synthesis in a Microfluidic Reactor Cascade.” CHEMICAL COMMUNICATIONS 51.58 (2015): 11701–11704. Print.
@article{6931475,
  abstract     = {Cationic ring-opening polymerizations of 2-oxazolines were investigated in continuous microflow reactors. Fast homopolymerizations of 2-ethyl-2-oxazoline (EtOx) and 2-n-propyl-2-oxazoline (nPropOx) were carried out up to 180 degrees C, yielding well-controlled polymers. Also well-defined diblock and triblock copolymers were produced in a microfluidic reactor cascade, demonstrating the high value of microflow synthesis for the built-up of advanced poly(2-oxazoline)-based polymers.},
  author       = {Baeten, Evelien and Verbraeken, Bart and Hoogenboom, Richard and Junkers, Thomas},
  issn         = {1359-7345},
  journal      = {CHEMICAL COMMUNICATIONS},
  keyword      = {MODE,MICROREACTOR,SCALE-UP,2-ETHYL-2-OXAZOLINE,MICROWAVE-ASSISTED POLYMERIZATIONS,CYCLIC IMINO ETHERS,RING-OPENING POLYMERIZATION,BLOCK-COPOLYMERS,FUNCTIONALIZATION,TECHNOLOGY},
  language     = {eng},
  number       = {58},
  pages        = {11701--11704},
  title        = {Continuous poly(2-oxazoline) triblock copolymer synthesis in a microfluidic reactor cascade},
  url          = {http://dx.doi.org/10.1039/c5cc04319k},
  volume       = {51},
  year         = {2015},
}

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