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Singlet-oxygen oxidation of 5-hydroxymethylfurfural in continuous flow

(2015) CHEMSUSCHEM. 8(10). p.1648-1651
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Abstract
Singlet-oxygen oxidation of 5-hydroxymethylfurfural (5-HMF) was performed in continuous flow mode using rose Bengal as photosensitizer. The resulting butenolide ((HMF)-M-2) was formed selectively in high yield. The procedure proved to be scalable and applicable to related bio-based furfurals. Furthermore, preliminary data show that (HMF)-M-2 can be readily isomerized thermally to 5-hydroxy-4-keto-pentenoic acid oligomers.
Keywords
continuous flow, 5-HMF, oxidation, photochemistry, singlet oxygen, PHOTOOXYGENATION, ACID, PHOTOCHEMISTRY, GENERATION, PRODUCTS, FURANS, FUELS

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Citation

Please use this url to cite or link to this publication:

MLA
Heugebaert, Thomas, Christian Stevens, and Oliver Kappe. “Singlet-oxygen Oxidation of 5-hydroxymethylfurfural in Continuous Flow.” CHEMSUSCHEM 8.10 (2015): 1648–1651. Print.
APA
Heugebaert, T., Stevens, C., & Kappe, O. (2015). Singlet-oxygen oxidation of 5-hydroxymethylfurfural in continuous flow. CHEMSUSCHEM, 8(10), 1648–1651.
Chicago author-date
Heugebaert, Thomas, Christian Stevens, and Oliver Kappe. 2015. “Singlet-oxygen Oxidation of 5-hydroxymethylfurfural in Continuous Flow.” Chemsuschem 8 (10): 1648–1651.
Chicago author-date (all authors)
Heugebaert, Thomas, Christian Stevens, and Oliver Kappe. 2015. “Singlet-oxygen Oxidation of 5-hydroxymethylfurfural in Continuous Flow.” Chemsuschem 8 (10): 1648–1651.
Vancouver
1.
Heugebaert T, Stevens C, Kappe O. Singlet-oxygen oxidation of 5-hydroxymethylfurfural in continuous flow. CHEMSUSCHEM. 2015;8(10):1648–51.
IEEE
[1]
T. Heugebaert, C. Stevens, and O. Kappe, “Singlet-oxygen oxidation of 5-hydroxymethylfurfural in continuous flow,” CHEMSUSCHEM, vol. 8, no. 10, pp. 1648–1651, 2015.
@article{6854964,
  abstract     = {Singlet-oxygen oxidation of 5-hydroxymethylfurfural (5-HMF) was performed in continuous flow mode using rose Bengal as photosensitizer. The resulting butenolide ((HMF)-M-2) was formed selectively in high yield. The procedure proved to be scalable and applicable to related bio-based furfurals. Furthermore, preliminary data show that (HMF)-M-2 can be readily isomerized thermally to 5-hydroxy-4-keto-pentenoic acid oligomers.},
  author       = {Heugebaert, Thomas and Stevens, Christian and Kappe, Oliver},
  issn         = {1864-5631},
  journal      = {CHEMSUSCHEM},
  keywords     = {continuous flow,5-HMF,oxidation,photochemistry,singlet oxygen,PHOTOOXYGENATION,ACID,PHOTOCHEMISTRY,GENERATION,PRODUCTS,FURANS,FUELS},
  language     = {eng},
  number       = {10},
  pages        = {1648--1651},
  title        = {Singlet-oxygen oxidation of 5-hydroxymethylfurfural in continuous flow},
  url          = {http://dx.doi.org/10.1002/cssc.201403182},
  volume       = {8},
  year         = {2015},
}

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