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Synthesis, structure and luminescent properties of Cd(II) and Zn(II) complexes constructed from 3,5-dimethyl-2, 6-pyrazinedicarboxylic acid

(2008) JOURNAL OF COORDINATION CHEMISTRY. 61(12). p.1839-1848
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Abstract
[Cd-2(phen)(2)(DPZDA)(2)(H2O)(2)] center dot 8H(2)O (1) and [Zn(phen)(DPZDA)(H2O)] center dot 2H(2)O (2) have been synthesized by reaction of Cd(NO3)(2)/Zn(NO3)(2) with phen and DPZDA (where phen = 1,10-phenanthroline, H(2)DPZDA = 3,5-dimethyl-2,6-pyrazinedicarboxylic acid) in aqueous ethanol solution. Elemental analysis, IR spectra, thermal analyses and X-ray single crystal diffraction were carried out to determine the composition and crystal structure of 1 and 2. In 1, a 2D supramolecular network containing a novel metal-water decamer were formed by hydrogen bonds. In 2, a 2D supramolecular structure was constructed from hydrogen bonds and pi...pi interactions. Moreover, 1 and 2 displayed photoluminescent properties in the blue range at room temperature.
Keywords
LIQUID WATER, CRYSTAL HOST, (H2O)(10) CLUSTER, COORDINATION POLYMERS, ORGANIC SUPRAMOLECULAR COMPLEX, WATER CLUSTERS, SOLID-STATE, ICE, MOLECULES, HEXAMER

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Citation

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MLA
Sun, Ya-Guang, et al. “Synthesis, Structure and Luminescent Properties of Cd(II) and Zn(II) Complexes Constructed from 3,5-Dimethyl-2, 6-Pyrazinedicarboxylic Acid.” JOURNAL OF COORDINATION CHEMISTRY, vol. 61, no. 12, TAYLOR & FRANCIS LTD, 2008, pp. 1839–48.
APA
Sun, Y.-G., Gu, X.-F., Drozdzak, R., Ding, F., Gao, E.-J., Yan, X.-M., & Verpoort, F. (2008). Synthesis, structure and luminescent properties of Cd(II) and Zn(II) complexes constructed from 3,5-dimethyl-2, 6-pyrazinedicarboxylic acid. JOURNAL OF COORDINATION CHEMISTRY, 61(12), 1839–1848.
Chicago author-date
Sun, Ya-Guang, Xiao-Fu Gu, Renata Drozdzak, Fu Ding, En-Jun Gao, Xiao-Mei Yan, and Francis Verpoort. 2008. “Synthesis, Structure and Luminescent Properties of Cd(II) and Zn(II) Complexes Constructed from 3,5-Dimethyl-2, 6-Pyrazinedicarboxylic Acid.” JOURNAL OF COORDINATION CHEMISTRY 61 (12): 1839–48.
Chicago author-date (all authors)
Sun, Ya-Guang, Xiao-Fu Gu, Renata Drozdzak, Fu Ding, En-Jun Gao, Xiao-Mei Yan, and Francis Verpoort. 2008. “Synthesis, Structure and Luminescent Properties of Cd(II) and Zn(II) Complexes Constructed from 3,5-Dimethyl-2, 6-Pyrazinedicarboxylic Acid.” JOURNAL OF COORDINATION CHEMISTRY 61 (12): 1839–1848.
Vancouver
1.
Sun Y-G, Gu X-F, Drozdzak R, Ding F, Gao E-J, Yan X-M, et al. Synthesis, structure and luminescent properties of Cd(II) and Zn(II) complexes constructed from 3,5-dimethyl-2, 6-pyrazinedicarboxylic acid. JOURNAL OF COORDINATION CHEMISTRY. 2008;61(12):1839–48.
IEEE
[1]
Y.-G. Sun et al., “Synthesis, structure and luminescent properties of Cd(II) and Zn(II) complexes constructed from 3,5-dimethyl-2, 6-pyrazinedicarboxylic acid,” JOURNAL OF COORDINATION CHEMISTRY, vol. 61, no. 12, pp. 1839–1848, 2008.
@article{601659,
  abstract     = {[Cd-2(phen)(2)(DPZDA)(2)(H2O)(2)] center dot 8H(2)O (1) and [Zn(phen)(DPZDA)(H2O)] center dot 2H(2)O (2) have been synthesized by reaction of Cd(NO3)(2)/Zn(NO3)(2) with phen and DPZDA (where phen = 1,10-phenanthroline, H(2)DPZDA = 3,5-dimethyl-2,6-pyrazinedicarboxylic acid) in aqueous ethanol solution. Elemental analysis, IR spectra, thermal analyses and X-ray single crystal diffraction were carried out to determine the composition and crystal structure of 1 and 2. In 1, a 2D supramolecular network containing a novel metal-water decamer were formed by hydrogen bonds. In 2, a 2D supramolecular structure was constructed from hydrogen bonds and pi...pi interactions. Moreover, 1 and 2 displayed photoluminescent properties in the blue range at room temperature.},
  author       = {Sun, Ya-Guang and Gu, Xiao-Fu and Drozdzak, Renata and Ding, Fu and Gao, En-Jun and Yan, Xiao-Mei and Verpoort, Francis},
  issn         = {0095-8972},
  journal      = {JOURNAL OF COORDINATION CHEMISTRY},
  keywords     = {LIQUID WATER,CRYSTAL HOST,(H2O)(10) CLUSTER,COORDINATION POLYMERS,ORGANIC SUPRAMOLECULAR COMPLEX,WATER CLUSTERS,SOLID-STATE,ICE,MOLECULES,HEXAMER},
  language     = {eng},
  number       = {12},
  pages        = {1839--1848},
  publisher    = {TAYLOR & FRANCIS LTD},
  title        = {Synthesis, structure and luminescent properties of Cd(II) and Zn(II) complexes constructed from 3,5-dimethyl-2, 6-pyrazinedicarboxylic acid},
  url          = {http://dx.doi.org/10.1080/00958970701793610},
  volume       = {61},
  year         = {2008},
}

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