Ghent University Academic Bibliography

Advanced

Ruthenium Complexes Containing Bidentate Schiff Base Ligands as Precursors of Homogeneous and Immobilized Catalysts

Fu Ding UGent, Yaguang Sun, Stijn Monsaert UGent, Renata Drozdzak, Ileana Dragutan, Valerian Dragutan and Francis Verpoort UGent (2008) CURRENT ORGANIC SYNTHESIS. 5(4). p.291-304
abstract
The paper presents recent work conducted in our group on the synthesis of a novel class of homogeneous and immobilized Ru-complexes containing Schiff bases as O, N-bidentate ligands benefiting from a versatile, quite general and thoroughly exemplified two-step procedure. The new Ru-complexes with improved stability incorporate a variety of Schiff bases, associated with traditional inorganic and organic ligands such as chloride, phosphanes, arenes, cyclodienes, NHC etc., and different carbenes (alkylidene, vinylidene, allenylidene and indenylidene). By a proper choice of the Schiff base, useful physical and chemical properties of the derived Ru-complexes could be induced resulting in tunable catalytic activity for metathesis and related processes. A pertinent example is the latency of selected Schiff base Ru catalysts which by becoming active only under specific conditions (heat or acid activation) are ideal for industrial applications, e. g. reaction injection molding processes. The synthetic approaches that are critically discussed in this artcile have led to a diversity of Ru-complexes of which several members have risen to the rank of commercial catalysts.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (review)
publication status
published
subject
keyword
RING-OPENING-METATHESIS, VINYLIDENE COMPLEXES, OLEFIN-METATHESIS CATALYSTS, TRANSFER RADICAL POLYMERIZATION, N-HETEROCYCLIC CARBENES, ENOL-ESTER SYNTHESIS, ETHYL DIAZOACETATE, ORGANIC-SYNTHESIS, CLOSING METATHESIS, IN-SITU
journal title
CURRENT ORGANIC SYNTHESIS
Curr. Org. Synth.
volume
5
issue
4
pages
291 - 304
Web of Science type
Review
Web of Science id
000261893300001
JCR category
CHEMISTRY, ORGANIC
JCR impact factor
2.61 (2008)
JCR rank
20/55 (2008)
JCR quartile
2 (2008)
ISSN
1570-1794
language
English
UGent publication?
yes
classification
A1
id
601429
handle
http://hdl.handle.net/1854/LU-601429
date created
2009-04-27 14:25:11
date last changed
2009-04-27 16:18:44
@article{601429,
  abstract     = {The paper presents recent work conducted in our group on the synthesis of a novel class of homogeneous and immobilized Ru-complexes containing Schiff bases as O, N-bidentate ligands benefiting from a versatile, quite general and thoroughly exemplified two-step procedure. The new Ru-complexes with improved stability incorporate a variety of Schiff bases, associated with traditional inorganic and organic ligands such as chloride, phosphanes, arenes, cyclodienes, NHC etc., and different carbenes (alkylidene, vinylidene, allenylidene and indenylidene). By a proper choice of the Schiff base, useful physical and chemical properties of the derived Ru-complexes could be induced resulting in tunable catalytic activity for metathesis and related processes. A pertinent example is the latency of selected Schiff base Ru catalysts which by becoming active only under specific conditions (heat or acid activation) are ideal for industrial applications, e. g. reaction injection molding processes. The synthetic approaches that are critically discussed in this artcile have led to a diversity of Ru-complexes of which several members have risen to the rank of commercial catalysts.},
  author       = {Ding, Fu and Sun, Yaguang and Monsaert, Stijn and Drozdzak, Renata and Dragutan, Ileana and Dragutan, Valerian and Verpoort, Francis},
  issn         = {1570-1794},
  journal      = {CURRENT ORGANIC SYNTHESIS},
  keyword      = {RING-OPENING-METATHESIS,VINYLIDENE COMPLEXES,OLEFIN-METATHESIS CATALYSTS,TRANSFER RADICAL POLYMERIZATION,N-HETEROCYCLIC CARBENES,ENOL-ESTER SYNTHESIS,ETHYL DIAZOACETATE,ORGANIC-SYNTHESIS,CLOSING METATHESIS,IN-SITU},
  language     = {eng},
  number       = {4},
  pages        = {291--304},
  title        = {Ruthenium Complexes Containing Bidentate Schiff Base Ligands as Precursors of Homogeneous and Immobilized Catalysts},
  volume       = {5},
  year         = {2008},
}

Chicago
Ding, Fu, Yaguang Sun, Stijn Monsaert, Renata Drozdzak, Ileana Dragutan, Valerian Dragutan, and Francis Verpoort. 2008. “Ruthenium Complexes Containing Bidentate Schiff Base Ligands as Precursors of Homogeneous and Immobilized Catalysts.” Current Organic Synthesis 5 (4): 291–304.
APA
Ding, F., Sun, Y., Monsaert, S., Drozdzak, R., Dragutan, I., Dragutan, V., & Verpoort, F. (2008). Ruthenium Complexes Containing Bidentate Schiff Base Ligands as Precursors of Homogeneous and Immobilized Catalysts. CURRENT ORGANIC SYNTHESIS, 5(4), 291–304.
Vancouver
1.
Ding F, Sun Y, Monsaert S, Drozdzak R, Dragutan I, Dragutan V, et al. Ruthenium Complexes Containing Bidentate Schiff Base Ligands as Precursors of Homogeneous and Immobilized Catalysts. CURRENT ORGANIC SYNTHESIS. 2008;5(4):291–304.
MLA
Ding, Fu, Yaguang Sun, Stijn Monsaert, et al. “Ruthenium Complexes Containing Bidentate Schiff Base Ligands as Precursors of Homogeneous and Immobilized Catalysts.” CURRENT ORGANIC SYNTHESIS 5.4 (2008): 291–304. Print.