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Synthesis, crystal structure and catalytic properties of a 2D cobalt(II) coordination polymer based on mixed ligands

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Abstract
A new Co(II) metal-organic coordination polymer based on flexible bis(imidazole) and aromatic dicarboxylate co-ligands, namely [Co(bix)(nph)](n)(H(2)nph = 3-nitrophthalic acid, bix = 1,4-bis(imidazole-1-ylmethyl)benzene), has been hydrothermally synthesized and characterized by elemental analyses, TG, IR spectroscopy and single-crystal X-ray diffraction. It crystallizes in the triclinic space group P (1) over bar with a = 9.3767(14), b = 10.1451(15), c = 12.1488(17) angstrom, alpha = 102.6450(10), beta = 108.856(2), gamma = 98.807(2)degrees, V = 1035.3(3) angstrom(3), Z = 2, C22H17CoN5O6, M-r= 506.34, D-c = 1.624 g/cm(3), mu = 0.882 mm(-1) and F(000) = 518. In the complex, the nph(2-) ligands connect neighbouring cobalt atoms to form binuclear [Co(nph)](2) subunits, which are linked by pairs of bix ligands to form a 2D honeycomb-like (6,3) network. In addition, the compound is further extended into a 3D supramolecular architecture by pi center dot center dot center dot pi stacking interactions. Moreover, the luminescence and catalytic properties of the complex are investigated.
Keywords
crystal structure, Co(II) complex, luminescence, catalytic property, DEGRADATION, FRAMEWORKS, ACID

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MLA
Zhang, Xu, et al. “Synthesis, Crystal Structure and Catalytic Properties of a 2D Cobalt(II) Coordination Polymer Based on Mixed Ligands.” CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, vol. 34, no. 4, 2015, pp. 599–605.
APA
Zhang, X., Ge, M., Van Hecke, K., & Cui, G.-H. (2015). Synthesis, crystal structure and catalytic properties of a 2D cobalt(II) coordination polymer based on mixed ligands. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 34(4), 599–605.
Chicago author-date
Zhang, Xu, Ming Ge, Kristof Van Hecke, and Guang-Hua Cui. 2015. “Synthesis, Crystal Structure and Catalytic Properties of a 2D Cobalt(II) Coordination Polymer Based on Mixed Ligands.” CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 34 (4): 599–605.
Chicago author-date (all authors)
Zhang, Xu, Ming Ge, Kristof Van Hecke, and Guang-Hua Cui. 2015. “Synthesis, Crystal Structure and Catalytic Properties of a 2D Cobalt(II) Coordination Polymer Based on Mixed Ligands.” CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 34 (4): 599–605.
Vancouver
1.
Zhang X, Ge M, Van Hecke K, Cui G-H. Synthesis, crystal structure and catalytic properties of a 2D cobalt(II) coordination polymer based on mixed ligands. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY. 2015;34(4):599–605.
IEEE
[1]
X. Zhang, M. Ge, K. Van Hecke, and G.-H. Cui, “Synthesis, crystal structure and catalytic properties of a 2D cobalt(II) coordination polymer based on mixed ligands,” CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, vol. 34, no. 4, pp. 599–605, 2015.
@article{5956224,
  abstract     = {A new Co(II) metal-organic coordination polymer based on flexible bis(imidazole) and aromatic dicarboxylate co-ligands, namely [Co(bix)(nph)](n)(H(2)nph = 3-nitrophthalic acid, bix = 1,4-bis(imidazole-1-ylmethyl)benzene), has been hydrothermally synthesized and characterized by elemental analyses, TG, IR spectroscopy and single-crystal X-ray diffraction. It crystallizes in the triclinic space group P (1) over bar with a = 9.3767(14), b = 10.1451(15), c = 12.1488(17) angstrom, alpha = 102.6450(10), beta = 108.856(2), gamma = 98.807(2)degrees, V = 1035.3(3) angstrom(3), Z = 2, C22H17CoN5O6, M-r= 506.34, D-c = 1.624 g/cm(3), mu = 0.882 mm(-1) and F(000) = 518. In the complex, the nph(2-) ligands connect neighbouring cobalt atoms to form binuclear [Co(nph)](2) subunits, which are linked by pairs of bix ligands to form a 2D honeycomb-like (6,3) network. In addition, the compound is further extended into a 3D supramolecular architecture by pi center dot center dot center dot pi stacking interactions. Moreover, the luminescence and catalytic properties of the complex are investigated.},
  author       = {Zhang, Xu and Ge, Ming and Van Hecke, Kristof and Cui, Guang-Hua},
  issn         = {0254-5861},
  journal      = {CHINESE JOURNAL OF STRUCTURAL CHEMISTRY},
  keywords     = {crystal structure,Co(II) complex,luminescence,catalytic property,DEGRADATION,FRAMEWORKS,ACID},
  language     = {eng},
  number       = {4},
  pages        = {599--605},
  title        = {Synthesis, crystal structure and catalytic properties of a 2D cobalt(II) coordination polymer based on mixed ligands},
  volume       = {34},
  year         = {2015},
}

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