
Synthesis, structures, and catalytic properties of three new metal-organic coordination polymers constructed from flexible benzimidazole-based and cis-1,2-cyclohexanedicarboxylate synthons
- Author
- Chun-Lun Ming, Zeng-Chuan Hao, Baoyi Yu (UGent) , Kristof Van Hecke (UGent) and Guang-Hua Cui
- Organization
- Abstract
- Three metal-organic coordination polymers {[Co(pbmb)(chadc)]center dot 2H(2)O} (n) (1), {[Zn(pbmb)(chadc)]center dot 2H(2)O} (n) (2), and [Ag(pbmb)(chadc)] (n) (3) (pbmb = 1,1'-(1,3-propanediyl)bis(2-methylbenzimidazole), chadc = cis-1,2-cyclohexanedicarboxylate anion), have been hydrothermally synthesized by self-assembly of a flexible bis(2-methylbenzimidazole) ligand and one dicarboxylate anion with three kinds of metal salts. All the compounds were characterized by single-crystal X-ray diffraction and physico-chemical spectroscopic methods. Complexes 1 and 2 possess a 1D sequence of fused rings and 3 shows a 1D helical chain structure, which are bridged by pbmb and chadc ligands. Complex 2 and 3 are further packed into 2D and 3D supramolecular architectures by diverse pi-pi interactions, respectively. The investigation as heterogeneous catalyst in a Fenton-like process for 1-3 reveals different performances. In addition, the fluorescence properties of 1-3 have been investigated in the solid state.
- Keywords
- Fluorescence and catalytic properties, Bis(2-methylbenzimidazole) ligand, Supramolecular interactions, CRYSTAL-STRUCTURES, BIS(BENZIMIDAZOLE)-BASED LIGANDS, FRAMEWORKS, COMPLEXES, ACID, 2D, LUMINESCENCE, SILVER(I), DESIGN, 1D
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-5956210
- MLA
- Ming, Chun-Lun, et al. “Synthesis, Structures, and Catalytic Properties of Three New Metal-Organic Coordination Polymers Constructed from Flexible Benzimidazole-Based and Cis-1,2-Cyclohexanedicarboxylate Synthons.” JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, vol. 25, no. 3, 2015, pp. 559–68.
- APA
- Ming, C.-L., Hao, Z.-C., Yu, B., Van Hecke, K., & Cui, G.-H. (2015). Synthesis, structures, and catalytic properties of three new metal-organic coordination polymers constructed from flexible benzimidazole-based and cis-1,2-cyclohexanedicarboxylate synthons. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 25(3), 559–568.
- Chicago author-date
- Ming, Chun-Lun, Zeng-Chuan Hao, Baoyi Yu, Kristof Van Hecke, and Guang-Hua Cui. 2015. “Synthesis, Structures, and Catalytic Properties of Three New Metal-Organic Coordination Polymers Constructed from Flexible Benzimidazole-Based and Cis-1,2-Cyclohexanedicarboxylate Synthons.” JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS 25 (3): 559–68.
- Chicago author-date (all authors)
- Ming, Chun-Lun, Zeng-Chuan Hao, Baoyi Yu, Kristof Van Hecke, and Guang-Hua Cui. 2015. “Synthesis, Structures, and Catalytic Properties of Three New Metal-Organic Coordination Polymers Constructed from Flexible Benzimidazole-Based and Cis-1,2-Cyclohexanedicarboxylate Synthons.” JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS 25 (3): 559–568.
- Vancouver
- 1.Ming C-L, Hao Z-C, Yu B, Van Hecke K, Cui G-H. Synthesis, structures, and catalytic properties of three new metal-organic coordination polymers constructed from flexible benzimidazole-based and cis-1,2-cyclohexanedicarboxylate synthons. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS. 2015;25(3):559–68.
- IEEE
- [1]C.-L. Ming, Z.-C. Hao, B. Yu, K. Van Hecke, and G.-H. Cui, “Synthesis, structures, and catalytic properties of three new metal-organic coordination polymers constructed from flexible benzimidazole-based and cis-1,2-cyclohexanedicarboxylate synthons,” JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, vol. 25, no. 3, pp. 559–568, 2015.
@article{5956210, abstract = {Three metal-organic coordination polymers {[Co(pbmb)(chadc)]center dot 2H(2)O} (n) (1), {[Zn(pbmb)(chadc)]center dot 2H(2)O} (n) (2), and [Ag(pbmb)(chadc)] (n) (3) (pbmb = 1,1'-(1,3-propanediyl)bis(2-methylbenzimidazole), chadc = cis-1,2-cyclohexanedicarboxylate anion), have been hydrothermally synthesized by self-assembly of a flexible bis(2-methylbenzimidazole) ligand and one dicarboxylate anion with three kinds of metal salts. All the compounds were characterized by single-crystal X-ray diffraction and physico-chemical spectroscopic methods. Complexes 1 and 2 possess a 1D sequence of fused rings and 3 shows a 1D helical chain structure, which are bridged by pbmb and chadc ligands. Complex 2 and 3 are further packed into 2D and 3D supramolecular architectures by diverse pi-pi interactions, respectively. The investigation as heterogeneous catalyst in a Fenton-like process for 1-3 reveals different performances. In addition, the fluorescence properties of 1-3 have been investigated in the solid state.}, author = {Ming, Chun-Lun and Hao, Zeng-Chuan and Yu, Baoyi and Van Hecke, Kristof and Cui, Guang-Hua}, issn = {1574-1443}, journal = {JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS}, keywords = {Fluorescence and catalytic properties,Bis(2-methylbenzimidazole) ligand,Supramolecular interactions,CRYSTAL-STRUCTURES,BIS(BENZIMIDAZOLE)-BASED LIGANDS,FRAMEWORKS,COMPLEXES,ACID,2D,LUMINESCENCE,SILVER(I),DESIGN,1D}, language = {eng}, number = {3}, pages = {559--568}, title = {Synthesis, structures, and catalytic properties of three new metal-organic coordination polymers constructed from flexible benzimidazole-based and cis-1,2-cyclohexanedicarboxylate synthons}, url = {http://dx.doi.org/10.1007/s10904-014-0117-x}, volume = {25}, year = {2015}, }
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