Advanced search
1 file | 1.27 MB Add to list

Synthesis and characterization of two cobalt(II) coordination polymers based on 5-tert-butyl isophthalic acid and bis(benzimidazole) ligands

(2015) TRANSITION METAL CHEMISTRY. 40(3). p.333-340
Author
Organization
Abstract
Two cobalt(II) coordination polymers, namely [Co(bbdmbm)(tbi)center dot H2O] (n) (1) and [Co(bmb)(1.5)(tbi)] (n) (2), (bbdmbm = 1,1'-(1,4-butanediyl)bis(5,6-dimethylbenzimidazole), bmb = 1,4-bis(2-methylbenzimidazol-1-ylmethyl) benzene, H(2)tbi = 5-tert-butyl isophthalic acid), have been synthesized and characterized by physico-chemical and spectroscopic methods and also by single-crystal X-ray diffraction. Complex 1 features a 1D ladder-like chain and is further extended into a 3D supramolecular architecture via strong O-H center dot center dot center dot O hydrogen bonds. Complex 2 exhibits a 2D corrugated (4,4) network constructed with bmb and tbi ligands, which is further assembled into a 3D 3,4,4-connected supramolecular framework with 3,4,4T25 topology through weak C-H center dot center dot center dot O hydrogen-bonding interactions. The fluorescence properties and catalytic activities of both complexes for the degradation of Congo red in a Fenton-like process have been investigated.
Keywords
FLEXIBLE BIS(5, METAL-ORGANIC FRAMEWORKS, 6-DIMETHYLBENZIMIDAZOLE), CATALYTIC-PROPERTIES, CRYSTAL-STRUCTURES, CO-LIGANDS, BIS(IMIDAZOLE) LIGANDS, COMPLEXES, DIMENSIONALITY, FLUORESCENCE, TOPOLOGIES

Downloads

  • (...).pdf
    • full text
    • |
    • UGent only
    • |
    • PDF
    • |
    • 1.27 MB

Citation

Please use this url to cite or link to this publication:

MLA
Yang, Rui, et al. “Synthesis and Characterization of Two Cobalt(II) Coordination Polymers Based on 5-Tert-Butyl Isophthalic Acid and Bis(Benzimidazole) Ligands.” TRANSITION METAL CHEMISTRY, vol. 40, no. 3, 2015, pp. 333–40.
APA
Yang, R., Liu, Y. G., Van Hecke, K., & Cui, G. H. (2015). Synthesis and characterization of two cobalt(II) coordination polymers based on 5-tert-butyl isophthalic acid and bis(benzimidazole) ligands. TRANSITION METAL CHEMISTRY, 40(3), 333–340.
Chicago author-date
Yang, Rui, Yong Guang Liu, Kristof Van Hecke, and Guang Hua Cui. 2015. “Synthesis and Characterization of Two Cobalt(II) Coordination Polymers Based on 5-Tert-Butyl Isophthalic Acid and Bis(Benzimidazole) Ligands.” TRANSITION METAL CHEMISTRY 40 (3): 333–40.
Chicago author-date (all authors)
Yang, Rui, Yong Guang Liu, Kristof Van Hecke, and Guang Hua Cui. 2015. “Synthesis and Characterization of Two Cobalt(II) Coordination Polymers Based on 5-Tert-Butyl Isophthalic Acid and Bis(Benzimidazole) Ligands.” TRANSITION METAL CHEMISTRY 40 (3): 333–340.
Vancouver
1.
Yang R, Liu YG, Van Hecke K, Cui GH. Synthesis and characterization of two cobalt(II) coordination polymers based on 5-tert-butyl isophthalic acid and bis(benzimidazole) ligands. TRANSITION METAL CHEMISTRY. 2015;40(3):333–40.
IEEE
[1]
R. Yang, Y. G. Liu, K. Van Hecke, and G. H. Cui, “Synthesis and characterization of two cobalt(II) coordination polymers based on 5-tert-butyl isophthalic acid and bis(benzimidazole) ligands,” TRANSITION METAL CHEMISTRY, vol. 40, no. 3, pp. 333–340, 2015.
@article{5935265,
  abstract     = {Two cobalt(II) coordination polymers, namely [Co(bbdmbm)(tbi)center dot H2O] (n) (1) and [Co(bmb)(1.5)(tbi)] (n) (2), (bbdmbm = 1,1'-(1,4-butanediyl)bis(5,6-dimethylbenzimidazole), bmb = 1,4-bis(2-methylbenzimidazol-1-ylmethyl) benzene, H(2)tbi = 5-tert-butyl isophthalic acid), have been synthesized and characterized by physico-chemical and spectroscopic methods and also by single-crystal X-ray diffraction. Complex 1 features a 1D ladder-like chain and is further extended into a 3D supramolecular architecture via strong O-H center dot center dot center dot O hydrogen bonds. Complex 2 exhibits a 2D corrugated (4,4) network constructed with bmb and tbi ligands, which is further assembled into a 3D 3,4,4-connected supramolecular framework with 3,4,4T25 topology through weak C-H center dot center dot center dot O hydrogen-bonding interactions. The fluorescence properties and catalytic activities of both complexes for the degradation of Congo red in a Fenton-like process have been investigated.},
  author       = {Yang, Rui and Liu, Yong Guang and Van Hecke, Kristof and Cui, Guang Hua},
  issn         = {0340-4285},
  journal      = {TRANSITION METAL CHEMISTRY},
  keywords     = {FLEXIBLE BIS(5,METAL-ORGANIC FRAMEWORKS,6-DIMETHYLBENZIMIDAZOLE),CATALYTIC-PROPERTIES,CRYSTAL-STRUCTURES,CO-LIGANDS,BIS(IMIDAZOLE) LIGANDS,COMPLEXES,DIMENSIONALITY,FLUORESCENCE,TOPOLOGIES},
  language     = {eng},
  number       = {3},
  pages        = {333--340},
  title        = {Synthesis and characterization of two cobalt(II) coordination polymers based on 5-tert-butyl isophthalic acid and bis(benzimidazole) ligands},
  url          = {http://dx.doi.org/10.1007/s11243-015-9921-6},
  volume       = {40},
  year         = {2015},
}

Altmetric
View in Altmetric
Web of Science
Times cited: