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Developing a new and versatile ordered mesoporous organosilica as a pH and temperature stable chromatographic packing material

Matthias Ide (UGent) , Els De Canck (UGent) , Isabel Van Driessche (UGent) , Frederic Lynen (UGent) and Pascal Van Der Voort (UGent)
(2015) RSC ADVANCES. 5(8). p.5546-5552
Author
Organization
Abstract
Periodic Mesoporous Organosilicas (PMOs) have been successfully spray dried for the first time using a novel cyclic multifunctional organosilane molecule. By reducing the siloxane bridge formation both in the polymerisation and in the anchoring of the side groups an organic/ inorganic hybrid material was designed, depicting inherently improved chemical stability and much increased organic content. The spherical silica particles were applied as a hydrolytically stable stationary phase in reversed phase HPLC. They proved to be both highly retentive and stable in a pH range from 1.75 to 12 and up to 150 degrees C in 60 v% water. Both the backbone and the functionalities of the material exhibit this high stability.
Keywords
SILICA SPHERES, ORGANIC GROUPS, STATIONARY PHASES, AEROSOL-ASSISTED SYNTHESIS, HYBRID, SIEVES, FRAMEWORKS

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Citation

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MLA
Ide, Matthias, et al. “Developing a New and Versatile Ordered Mesoporous Organosilica as a PH and Temperature Stable Chromatographic Packing Material.” RSC ADVANCES, vol. 5, no. 8, 2015, pp. 5546–52, doi:10.1039/c4ra15837g.
APA
Ide, M., De Canck, E., Van Driessche, I., Lynen, F., & Van Der Voort, P. (2015). Developing a new and versatile ordered mesoporous organosilica as a pH and temperature stable chromatographic packing material. RSC ADVANCES, 5(8), 5546–5552. https://doi.org/10.1039/c4ra15837g
Chicago author-date
Ide, Matthias, Els De Canck, Isabel Van Driessche, Frederic Lynen, and Pascal Van Der Voort. 2015. “Developing a New and Versatile Ordered Mesoporous Organosilica as a PH and Temperature Stable Chromatographic Packing Material.” RSC ADVANCES 5 (8): 5546–52. https://doi.org/10.1039/c4ra15837g.
Chicago author-date (all authors)
Ide, Matthias, Els De Canck, Isabel Van Driessche, Frederic Lynen, and Pascal Van Der Voort. 2015. “Developing a New and Versatile Ordered Mesoporous Organosilica as a PH and Temperature Stable Chromatographic Packing Material.” RSC ADVANCES 5 (8): 5546–5552. doi:10.1039/c4ra15837g.
Vancouver
1.
Ide M, De Canck E, Van Driessche I, Lynen F, Van Der Voort P. Developing a new and versatile ordered mesoporous organosilica as a pH and temperature stable chromatographic packing material. RSC ADVANCES. 2015;5(8):5546–52.
IEEE
[1]
M. Ide, E. De Canck, I. Van Driessche, F. Lynen, and P. Van Der Voort, “Developing a new and versatile ordered mesoporous organosilica as a pH and temperature stable chromatographic packing material,” RSC ADVANCES, vol. 5, no. 8, pp. 5546–5552, 2015.
@article{5838581,
  abstract     = {{Periodic Mesoporous Organosilicas (PMOs) have been successfully spray dried for the first time using a novel cyclic multifunctional organosilane molecule. By reducing the siloxane bridge formation both in the polymerisation and in the anchoring of the side groups an organic/ inorganic hybrid material was designed, depicting inherently improved chemical stability and much increased organic content. The spherical silica particles were applied as a hydrolytically stable stationary phase in reversed phase HPLC. They proved to be both highly retentive and stable in a pH range from 1.75 to 12 and up to 150 degrees C in 60 v% water. Both the backbone and the functionalities of the material exhibit this high stability.}},
  author       = {{Ide, Matthias and De Canck, Els and Van Driessche, Isabel and Lynen, Frederic and Van Der Voort, Pascal}},
  issn         = {{2046-2069}},
  journal      = {{RSC ADVANCES}},
  keywords     = {{SILICA SPHERES,ORGANIC GROUPS,STATIONARY PHASES,AEROSOL-ASSISTED SYNTHESIS,HYBRID,SIEVES,FRAMEWORKS}},
  language     = {{eng}},
  number       = {{8}},
  pages        = {{5546--5552}},
  title        = {{Developing a new and versatile ordered mesoporous organosilica as a pH and temperature stable chromatographic packing material}},
  url          = {{http://doi.org/10.1039/c4ra15837g}},
  volume       = {{5}},
  year         = {{2015}},
}

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