Developing a new and versatile ordered mesoporous organosilica as a pH and temperature stable chromatographic packing material
- Author
- Matthias Ide (UGent) , Els De Canck (UGent) , Isabel Van Driessche (UGent) , Frederic Lynen (UGent) and Pascal Van Der Voort (UGent)
- Organization
- Abstract
- Periodic Mesoporous Organosilicas (PMOs) have been successfully spray dried for the first time using a novel cyclic multifunctional organosilane molecule. By reducing the siloxane bridge formation both in the polymerisation and in the anchoring of the side groups an organic/ inorganic hybrid material was designed, depicting inherently improved chemical stability and much increased organic content. The spherical silica particles were applied as a hydrolytically stable stationary phase in reversed phase HPLC. They proved to be both highly retentive and stable in a pH range from 1.75 to 12 and up to 150 degrees C in 60 v% water. Both the backbone and the functionalities of the material exhibit this high stability.
- Keywords
- SILICA SPHERES, ORGANIC GROUPS, STATIONARY PHASES, AEROSOL-ASSISTED SYNTHESIS, HYBRID, SIEVES, FRAMEWORKS
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-5838581
- MLA
- Ide, Matthias, et al. “Developing a New and Versatile Ordered Mesoporous Organosilica as a PH and Temperature Stable Chromatographic Packing Material.” RSC ADVANCES, vol. 5, no. 8, 2015, pp. 5546–52, doi:10.1039/c4ra15837g.
- APA
- Ide, M., De Canck, E., Van Driessche, I., Lynen, F., & Van Der Voort, P. (2015). Developing a new and versatile ordered mesoporous organosilica as a pH and temperature stable chromatographic packing material. RSC ADVANCES, 5(8), 5546–5552. https://doi.org/10.1039/c4ra15837g
- Chicago author-date
- Ide, Matthias, Els De Canck, Isabel Van Driessche, Frederic Lynen, and Pascal Van Der Voort. 2015. “Developing a New and Versatile Ordered Mesoporous Organosilica as a PH and Temperature Stable Chromatographic Packing Material.” RSC ADVANCES 5 (8): 5546–52. https://doi.org/10.1039/c4ra15837g.
- Chicago author-date (all authors)
- Ide, Matthias, Els De Canck, Isabel Van Driessche, Frederic Lynen, and Pascal Van Der Voort. 2015. “Developing a New and Versatile Ordered Mesoporous Organosilica as a PH and Temperature Stable Chromatographic Packing Material.” RSC ADVANCES 5 (8): 5546–5552. doi:10.1039/c4ra15837g.
- Vancouver
- 1.Ide M, De Canck E, Van Driessche I, Lynen F, Van Der Voort P. Developing a new and versatile ordered mesoporous organosilica as a pH and temperature stable chromatographic packing material. RSC ADVANCES. 2015;5(8):5546–52.
- IEEE
- [1]M. Ide, E. De Canck, I. Van Driessche, F. Lynen, and P. Van Der Voort, “Developing a new and versatile ordered mesoporous organosilica as a pH and temperature stable chromatographic packing material,” RSC ADVANCES, vol. 5, no. 8, pp. 5546–5552, 2015.
@article{5838581, abstract = {{Periodic Mesoporous Organosilicas (PMOs) have been successfully spray dried for the first time using a novel cyclic multifunctional organosilane molecule. By reducing the siloxane bridge formation both in the polymerisation and in the anchoring of the side groups an organic/ inorganic hybrid material was designed, depicting inherently improved chemical stability and much increased organic content. The spherical silica particles were applied as a hydrolytically stable stationary phase in reversed phase HPLC. They proved to be both highly retentive and stable in a pH range from 1.75 to 12 and up to 150 degrees C in 60 v% water. Both the backbone and the functionalities of the material exhibit this high stability.}}, author = {{Ide, Matthias and De Canck, Els and Van Driessche, Isabel and Lynen, Frederic and Van Der Voort, Pascal}}, issn = {{2046-2069}}, journal = {{RSC ADVANCES}}, keywords = {{SILICA SPHERES,ORGANIC GROUPS,STATIONARY PHASES,AEROSOL-ASSISTED SYNTHESIS,HYBRID,SIEVES,FRAMEWORKS}}, language = {{eng}}, number = {{8}}, pages = {{5546--5552}}, title = {{Developing a new and versatile ordered mesoporous organosilica as a pH and temperature stable chromatographic packing material}}, url = {{http://doi.org/10.1039/c4ra15837g}}, volume = {{5}}, year = {{2015}}, }
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