A family of 3D lanthanide-organic frameworks constructed from parallelogram secondary building units : synthesis, structures and properties
- Author
- Ya-guang Sun, Jian Li, Ke-long Li, Zhen-he Xu, Fu Ding, Bao-yi Ren, Shu-ju Wang, Li-xin You, Gang Xiong and Philippe Smet (UGent)
- Organization
- Project
- Abstract
- A family of lanthanide-organic frameworks, {Ln(2)(pyip)(ox)(2.5)(H2O)(5)}(n) (Ln = La (1), Pr (2), Sm (3), Eu (4), Gd (5), Tb (6), Dy (7)) has been synthesized based on mixed bridging ligands, H(2)pyip and oxalate anion (H(2)pyip = 5-(4-pyridyl)-isophthalic acid, H(2)ox = oxalic acid) and characterized by elemental analysis, Fourier transform infrared spectroscopy, steady state and time-resolved luminescence spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The single-crystal X-ray diffraction analysis results show that complexes 1-7 are isostructural. They crystallize in the same P2(1)/c space group and exhibit a (3,4)-connected {4(2).6.8(2).10}{8(2).10} topology, being a 2-nodal net topology. The luminescence properties of 3, 4, 6, and 7 were investigated and related to the structural properties. The magnetic studies reveal that strong ferromagnetic coupling exists in compound 6.
- Keywords
- COMPLEXES, ADSORPTION, PHOTOLUMINESCENCE, COORDINATION POLYMERS, MAGNETIC-PROPERTIES, LUMINESCENT PROPERTIES, CRYSTAL-STRUCTURES, TETRACARBOXYLATE LIGANDS, ACID LIGAND, SERIES
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-5772223
- MLA
- Sun, Ya-guang, et al. “A Family of 3D Lanthanide-Organic Frameworks Constructed from Parallelogram Secondary Building Units : Synthesis, Structures and Properties.” CRYSTENGCOMM, vol. 16, no. 9, 2014, pp. 1777–85, doi:10.1039/c3ce42197j.
- APA
- Sun, Y., Li, J., Li, K., Xu, Z., Ding, F., Ren, B., … Smet, P. (2014). A family of 3D lanthanide-organic frameworks constructed from parallelogram secondary building units : synthesis, structures and properties. CRYSTENGCOMM, 16(9), 1777–1785. https://doi.org/10.1039/c3ce42197j
- Chicago author-date
- Sun, Ya-guang, Jian Li, Ke-long Li, Zhen-he Xu, Fu Ding, Bao-yi Ren, Shu-ju Wang, Li-xin You, Gang Xiong, and Philippe Smet. 2014. “A Family of 3D Lanthanide-Organic Frameworks Constructed from Parallelogram Secondary Building Units : Synthesis, Structures and Properties.” CRYSTENGCOMM 16 (9): 1777–85. https://doi.org/10.1039/c3ce42197j.
- Chicago author-date (all authors)
- Sun, Ya-guang, Jian Li, Ke-long Li, Zhen-he Xu, Fu Ding, Bao-yi Ren, Shu-ju Wang, Li-xin You, Gang Xiong, and Philippe Smet. 2014. “A Family of 3D Lanthanide-Organic Frameworks Constructed from Parallelogram Secondary Building Units : Synthesis, Structures and Properties.” CRYSTENGCOMM 16 (9): 1777–1785. doi:10.1039/c3ce42197j.
- Vancouver
- 1.Sun Y, Li J, Li K, Xu Z, Ding F, Ren B, et al. A family of 3D lanthanide-organic frameworks constructed from parallelogram secondary building units : synthesis, structures and properties. CRYSTENGCOMM. 2014;16(9):1777–85.
- IEEE
- [1]Y. Sun et al., “A family of 3D lanthanide-organic frameworks constructed from parallelogram secondary building units : synthesis, structures and properties,” CRYSTENGCOMM, vol. 16, no. 9, pp. 1777–1785, 2014.
@article{5772223, abstract = {{A family of lanthanide-organic frameworks, {Ln(2)(pyip)(ox)(2.5)(H2O)(5)}(n) (Ln = La (1), Pr (2), Sm (3), Eu (4), Gd (5), Tb (6), Dy (7)) has been synthesized based on mixed bridging ligands, H(2)pyip and oxalate anion (H(2)pyip = 5-(4-pyridyl)-isophthalic acid, H(2)ox = oxalic acid) and characterized by elemental analysis, Fourier transform infrared spectroscopy, steady state and time-resolved luminescence spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The single-crystal X-ray diffraction analysis results show that complexes 1-7 are isostructural. They crystallize in the same P2(1)/c space group and exhibit a (3,4)-connected {4(2).6.8(2).10}{8(2).10} topology, being a 2-nodal net topology. The luminescence properties of 3, 4, 6, and 7 were investigated and related to the structural properties. The magnetic studies reveal that strong ferromagnetic coupling exists in compound 6.}}, author = {{Sun, Ya-guang and Li, Jian and Li, Ke-long and Xu, Zhen-he and Ding, Fu and Ren, Bao-yi and Wang, Shu-ju and You, Li-xin and Xiong, Gang and Smet, Philippe}}, issn = {{1466-8033}}, journal = {{CRYSTENGCOMM}}, keywords = {{COMPLEXES,ADSORPTION,PHOTOLUMINESCENCE,COORDINATION POLYMERS,MAGNETIC-PROPERTIES,LUMINESCENT PROPERTIES,CRYSTAL-STRUCTURES,TETRACARBOXYLATE LIGANDS,ACID LIGAND,SERIES}}, language = {{eng}}, number = {{9}}, pages = {{1777--1785}}, title = {{A family of 3D lanthanide-organic frameworks constructed from parallelogram secondary building units : synthesis, structures and properties}}, url = {{http://doi.org/10.1039/c3ce42197j}}, volume = {{16}}, year = {{2014}}, }
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