Cobalt(II) and silver(I) coordination polymers constructed from flexible bis(5,6-dimethylbenzimidazole) and substituted isophthalate co-ligands
- Author
- Rui Yang, Kristof Van Hecke (UGent) , Baoyi Yu (UGent) , Guang Yue Li and Guang Hua Cui
- Organization
- Abstract
- Two coordination polymers, [Co(L1)(IPA] (n) (1) and {[Ag(L2)(HMIPA)]center dot H2O} (n) (2) (H(2)IPA = isophthalic acid, L1 = 1,2-bis(5,6-dimethylbenzimidazol-1-ylmethyl)benzene, H(2)MIPA = 5-methylisophthalic acid, L2 = 1,6-bis(5,6-dimethylbenzimidazol-1-yl)hexane, have been synthesized and characterized by physicochemical and spectroscopic methods, as well as single-crystal X-ray diffraction. In 1, six-coordinated cobalt centers are bridged by L1 and IPA(2-) ligands to generate a (4,4) two-dimensional layer. However, complex 2 features a 1D chain structure, which is further extended by O-H center dot center dot center dot O hydrogen bonding interactions into a 2D supramolecular layer with (6(3)) topology. The fluorescence and thermal gravimetric analysis of both complexes were also explored. Furthermore, the complexes 1 and 2 exhibit remarkable catalytic properties for the degradation of methyl orange dyes in a Fenton-like process.
- Keywords
- CRYSTAL-STRUCTURES, METAL-ORGANIC FRAMEWORKS, CATALYTIC-PROPERTIES, BIS(BENZIMIDAZOLE)-BASED LIGANDS, PHOTOLUMINESCENT PROPERTIES, LUMINESCENT PROPERTIES, COMPLEXES, ARCHITECTURES, SERIES, 2D
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-5770662
- MLA
- Yang, Rui, et al. “Cobalt(II) and Silver(I) Coordination Polymers Constructed from Flexible Bis(5,6-Dimethylbenzimidazole) and Substituted Isophthalate Co-Ligands.” TRANSITION METAL CHEMISTRY, vol. 39, no. 5, 2014, pp. 535–41, doi:10.1007/s11243-014-9829-6.
- APA
- Yang, R., Van Hecke, K., Yu, B., Li, G. Y., & Cui, G. H. (2014). Cobalt(II) and silver(I) coordination polymers constructed from flexible bis(5,6-dimethylbenzimidazole) and substituted isophthalate co-ligands. TRANSITION METAL CHEMISTRY, 39(5), 535–541. https://doi.org/10.1007/s11243-014-9829-6
- Chicago author-date
- Yang, Rui, Kristof Van Hecke, Baoyi Yu, Guang Yue Li, and Guang Hua Cui. 2014. “Cobalt(II) and Silver(I) Coordination Polymers Constructed from Flexible Bis(5,6-Dimethylbenzimidazole) and Substituted Isophthalate Co-Ligands.” TRANSITION METAL CHEMISTRY 39 (5): 535–41. https://doi.org/10.1007/s11243-014-9829-6.
- Chicago author-date (all authors)
- Yang, Rui, Kristof Van Hecke, Baoyi Yu, Guang Yue Li, and Guang Hua Cui. 2014. “Cobalt(II) and Silver(I) Coordination Polymers Constructed from Flexible Bis(5,6-Dimethylbenzimidazole) and Substituted Isophthalate Co-Ligands.” TRANSITION METAL CHEMISTRY 39 (5): 535–541. doi:10.1007/s11243-014-9829-6.
- Vancouver
- 1.Yang R, Van Hecke K, Yu B, Li GY, Cui GH. Cobalt(II) and silver(I) coordination polymers constructed from flexible bis(5,6-dimethylbenzimidazole) and substituted isophthalate co-ligands. TRANSITION METAL CHEMISTRY. 2014;39(5):535–41.
- IEEE
- [1]R. Yang, K. Van Hecke, B. Yu, G. Y. Li, and G. H. Cui, “Cobalt(II) and silver(I) coordination polymers constructed from flexible bis(5,6-dimethylbenzimidazole) and substituted isophthalate co-ligands,” TRANSITION METAL CHEMISTRY, vol. 39, no. 5, pp. 535–541, 2014.
@article{5770662, abstract = {{Two coordination polymers, [Co(L1)(IPA] (n) (1) and {[Ag(L2)(HMIPA)]center dot H2O} (n) (2) (H(2)IPA = isophthalic acid, L1 = 1,2-bis(5,6-dimethylbenzimidazol-1-ylmethyl)benzene, H(2)MIPA = 5-methylisophthalic acid, L2 = 1,6-bis(5,6-dimethylbenzimidazol-1-yl)hexane, have been synthesized and characterized by physicochemical and spectroscopic methods, as well as single-crystal X-ray diffraction. In 1, six-coordinated cobalt centers are bridged by L1 and IPA(2-) ligands to generate a (4,4) two-dimensional layer. However, complex 2 features a 1D chain structure, which is further extended by O-H center dot center dot center dot O hydrogen bonding interactions into a 2D supramolecular layer with (6(3)) topology. The fluorescence and thermal gravimetric analysis of both complexes were also explored. Furthermore, the complexes 1 and 2 exhibit remarkable catalytic properties for the degradation of methyl orange dyes in a Fenton-like process.}}, author = {{Yang, Rui and Van Hecke, Kristof and Yu, Baoyi and Li, Guang Yue and Cui, Guang Hua}}, issn = {{0340-4285}}, journal = {{TRANSITION METAL CHEMISTRY}}, keywords = {{CRYSTAL-STRUCTURES,METAL-ORGANIC FRAMEWORKS,CATALYTIC-PROPERTIES,BIS(BENZIMIDAZOLE)-BASED LIGANDS,PHOTOLUMINESCENT PROPERTIES,LUMINESCENT PROPERTIES,COMPLEXES,ARCHITECTURES,SERIES,2D}}, language = {{eng}}, number = {{5}}, pages = {{535--541}}, title = {{Cobalt(II) and silver(I) coordination polymers constructed from flexible bis(5,6-dimethylbenzimidazole) and substituted isophthalate co-ligands}}, url = {{http://doi.org/10.1007/s11243-014-9829-6}}, volume = {{39}}, year = {{2014}}, }
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