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Broadband luminescence in rare earth doped Sr2SiS4 : relating energy levels of Ce3+ and Eu2+

Anthony Parmentier (UGent) , Philippe Smet (UGent) and Dirk Poelman (UGent)
(2013) MATERIALS. 6(8). p.3663-3675
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Organization
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Center for nano- and biophotonics (NB-Photonics)
Abstract
Sr2SiS4:Ce3+ is an efficient blue-emitting (460 nm) phosphor, excitable with light of wavelengths up to 420 nm. From the excitation spectrum, we construct the energy level scheme and use it to check the predictive power of the Dorenbos model, relating the positions of the Ce3+ energy levels with those of Eu2+ in the same host. For strontium thiosilicate, this method gives excellent results and allows us to determine which of two available crystallographic sites is occupied by cerium. We use the Dorenbos method for extracting information on the coordination of Ce3+ from the observed crystal field splitting.
Keywords
INORGANIC-COMPOUNDS, XRD, cerium, luminescence, phosphor, thiosilicate, europium, Dorenbos, sulfide, LEDS, THIOSILICATE PHOSPHORS, CAS, PHOTOLUMINESCENCE

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Citation

Please use this url to cite or link to this publication:

Chicago
Parmentier, Anthony, Philippe Smet, and Dirk Poelman. 2013. “Broadband Luminescence in Rare Earth Doped Sr2SiS4 : Relating Energy Levels of Ce3+ and Eu2+.” Materials 6 (8): 3663–3675.
APA
Parmentier, Anthony, Smet, P., & Poelman, D. (2013). Broadband luminescence in rare earth doped Sr2SiS4 : relating energy levels of Ce3+ and Eu2+. MATERIALS, 6(8), 3663–3675.
Vancouver
1.
Parmentier A, Smet P, Poelman D. Broadband luminescence in rare earth doped Sr2SiS4 : relating energy levels of Ce3+ and Eu2+. MATERIALS. 2013;6(8):3663–75.
MLA
Parmentier, Anthony, Philippe Smet, and Dirk Poelman. “Broadband Luminescence in Rare Earth Doped Sr2SiS4 : Relating Energy Levels of Ce3+ and Eu2+.” MATERIALS 6.8 (2013): 3663–3675. Print.
@article{4299592,
  abstract     = {Sr2SiS4:Ce3+ is an efficient blue-emitting (460 nm) phosphor, excitable with light of wavelengths up to 420 nm. From the excitation spectrum, we construct the energy level scheme and use it to check the predictive power of the Dorenbos model, relating the positions of the Ce3+ energy levels with those of Eu2+ in the same host. For strontium thiosilicate, this method gives excellent results and allows us to determine which of two available crystallographic sites is occupied by cerium. We use the Dorenbos method for extracting information on the coordination of Ce3+ from the observed crystal field splitting.},
  author       = {Parmentier, Anthony and Smet, Philippe and Poelman, Dirk},
  issn         = {1996-1944},
  journal      = {MATERIALS},
  keywords     = {INORGANIC-COMPOUNDS,XRD,cerium,luminescence,phosphor,thiosilicate,europium,Dorenbos,sulfide,LEDS,THIOSILICATE PHOSPHORS,CAS,PHOTOLUMINESCENCE},
  language     = {eng},
  number       = {8},
  pages        = {3663--3675},
  title        = {Broadband luminescence in rare earth doped Sr2SiS4 : relating energy levels of Ce3+ and Eu2+},
  url          = {http://dx.doi.org/10.3390/ma6083663},
  volume       = {6},
  year         = {2013},
}

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