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Functions incorporating a halogen and another group other than a halogen or a chalcogen

Bart Roman (UGent) , Thomas Heugebaert (UGent) and Christian Stevens (UGent)
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Abstract
An overview is presented of the hitherto reported entries to alkenes, geminally substituted with both a halogen and a heteroatom other than a halogen or a chalcogen. The covered methodologies have been categorized according to the chemical class of the precursor molecule and the nature of the transformation yielding the gem-difunctionalized alkene. This work discusses primary literature reports up to the end of 2012.
Keywords
Phosphonylations, Rearrangement, Silylation, Reduction, Amination, Addition cyclisation, Eliminations, Gem-halo-enamine, Gem-halo-vinylmetallate, Gem-halo-vinylphosphonate, Olefinations, Gem-halo-vinylsilane, Halogenations (nucleophilic and electrophilic), Metallation, Isomerisation

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Citation

Please use this url to cite or link to this publication:

Chicago
Roman, Bart, Thomas Heugebaert, and Christian Stevens. 2014. “Functions Incorporating a Halogen and Another Group Other Than a Halogen or a Chalcogen.” In Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, ed. Jan Reedijk. Waltham, MA, USA: Elsevier.
APA
Roman, B., Heugebaert, T., & Stevens, C. (2014). Functions incorporating a halogen and another group other than a halogen or a chalcogen. In J. Reedijk (Ed.), Reference module in chemistry, molecular sciences and chemical engineering. Waltham, MA, USA: Elsevier.
Vancouver
1.
Roman B, Heugebaert T, Stevens C. Functions incorporating a halogen and another group other than a halogen or a chalcogen. In: Reedijk J, editor. Reference module in chemistry, molecular sciences and chemical engineering. Waltham, MA, USA: Elsevier; 2014.
MLA
Roman, Bart, Thomas Heugebaert, and Christian Stevens. “Functions Incorporating a Halogen and Another Group Other Than a Halogen or a Chalcogen.” Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Ed. Jan Reedijk. Waltham, MA, USA: Elsevier, 2014. Print.
@incollection{4249142,
  abstract     = {An overview is presented of the hitherto reported entries to alkenes, geminally substituted with both a halogen and a heteroatom other than a halogen or a chalcogen. The covered methodologies have been categorized according to the chemical class of the precursor molecule and the nature of the transformation yielding the gem-difunctionalized alkene. This work discusses primary literature reports up to the end of 2012.},
  author       = {Roman, Bart and Heugebaert, Thomas and Stevens, Christian},
  booktitle    = {Reference module in chemistry, molecular sciences and chemical engineering},
  editor       = {Reedijk, Jan},
  isbn         = {9780124095472},
  language     = {eng},
  pages        = {88},
  publisher    = {Elsevier},
  title        = {Functions incorporating a halogen and another group other than a halogen or a chalcogen},
  url          = {http://dx.doi.org/10.1016/B978-0-12-409547-2.10980-1},
  year         = {2014},
}

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