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One-pot double modification of p(NIPAAm): a tool for designing tailor-made multiresponsive polymers

Stefan Reinicke UGent, Pieter Espeel, Milan M. Stamenović UGent and Filip Du Prez UGent (2013) ACS MACRO LETTERS. 2(6). p.539-543
abstract
A quantitative, additive-free, and one-pot reaction cascade involving the ring-opening of a thiolactone by primary amine treatment and subsequent conversion of the released thiol groups via Michael addition to an acrylate has been utilized for the double modification/functionalization of poly(N-isopropyl acrylamide), yielding tailor-made thermoresponsive polymers. After proving a quantitative double functionalization, different amine/acrylate combinations were employed in order to demonstrate the general applicability of the concept. Cloud points can be tuned by adjusting the amount of ring-opening amine in the reaction mixture, which enables to control the degree of modification.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
CLICK REACTION, CONJUGATION, HOMOCYSTEINE-THIOLACTONE, TEMPERATURE, POST-POLYMERIZATION MODIFICATION, N-ISOPROPYLACRYLAMIDE, ROUTE, TRANSFER RADICAL POLYMERIZATION
journal title
ACS MACRO LETTERS
ACS Macro Lett.
volume
2
issue
6
pages
539 - 543
Web of Science type
Article
Web of Science id
000323362900018
JCR category
POLYMER SCIENCE
JCR impact factor
5.242 (2013)
JCR rank
6/82 (2013)
JCR quartile
1 (2013)
ISSN
2161-1653
DOI
10.1021/mz4002222
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
4179995
handle
http://hdl.handle.net/1854/LU-4179995
date created
2013-11-06 14:24:16
date last changed
2016-12-19 15:43:33
@article{4179995,
  abstract     = {A quantitative, additive-free, and one-pot reaction cascade involving the ring-opening of a thiolactone by primary amine treatment and subsequent conversion of the released thiol groups via Michael addition to an acrylate has been utilized for the double modification/functionalization of poly(N-isopropyl acrylamide), yielding tailor-made thermoresponsive polymers. After proving a quantitative double functionalization, different amine/acrylate combinations were employed in order to demonstrate the general applicability of the concept. Cloud points can be tuned by adjusting the amount of ring-opening amine in the reaction mixture, which enables to control the degree of modification.},
  author       = {Reinicke, Stefan and Espeel, Pieter and Stamenovi\'{c}, Milan M. and Du Prez, Filip},
  issn         = {2161-1653},
  journal      = {ACS MACRO LETTERS},
  keyword      = {CLICK REACTION,CONJUGATION,HOMOCYSTEINE-THIOLACTONE,TEMPERATURE,POST-POLYMERIZATION MODIFICATION,N-ISOPROPYLACRYLAMIDE,ROUTE,TRANSFER RADICAL POLYMERIZATION},
  language     = {eng},
  number       = {6},
  pages        = {539--543},
  title        = {One-pot double modification of p(NIPAAm): a tool for designing tailor-made multiresponsive polymers},
  url          = {http://dx.doi.org/10.1021/mz4002222},
  volume       = {2},
  year         = {2013},
}

Chicago
Reinicke, Stefan, Pieter Espeel, Milan M. Stamenović, and Filip Du Prez. 2013. “One-pot Double Modification of p(NIPAAm): a Tool for Designing Tailor-made Multiresponsive Polymers.” Acs Macro Letters 2 (6): 539–543.
APA
Reinicke, S., Espeel, P., Stamenović, M. M., & Du Prez, F. (2013). One-pot double modification of p(NIPAAm): a tool for designing tailor-made multiresponsive polymers. ACS MACRO LETTERS, 2(6), 539–543.
Vancouver
1.
Reinicke S, Espeel P, Stamenović MM, Du Prez F. One-pot double modification of p(NIPAAm): a tool for designing tailor-made multiresponsive polymers. ACS MACRO LETTERS. 2013;2(6):539–43.
MLA
Reinicke, Stefan, Pieter Espeel, Milan M. Stamenović, et al. “One-pot Double Modification of p(NIPAAm): a Tool for Designing Tailor-made Multiresponsive Polymers.” ACS MACRO LETTERS 2.6 (2013): 539–543. Print.